Preparation of Ba2Ti9O20 by Coprecipitation Method

공침법에 의한 Ba2Ti9O20의 합성

  • 이경희 (명지대학교 공과대학 무기재료공학과) ;
  • 이병하 (명지대학교 공과대학 무기재료공학과) ;
  • 오권오 (명지대학교 공과대학 무기재료공학과)
  • Published : 1988.06.01

Abstract

Preparation of high purity ultrafine Ba2Ti9O20 powder was investigated by coprecipitation method. Formation of Ba2Ti9O20 powder from precipitate of coprecipitation takes place at 120$0^{\circ}C$, which is 20$0^{\circ}C$ lower than that from mechanical mixtures of BaCO3 and TiO2. This is apparently due to the nature of the compounds formed by the reaction of mixtures of aqueous solutions of BaCl2 and TiCl4 with an ammoniacal solution of ammonium carbonate and ammouium hydroxide. In this method, the Ba2Ti9O20 powders show low callcining and sintering temperature and it has good sintering and dielectric constant at room temperature.

Keywords

References

  1. Chem. Weekblad v.49 no.49 Keramische Materialen Voor de Electrotechinck G. H. Jonker
  2. J. Am. Ceram. Soc. v.51 no.10 A New BaOTiO₂ Compound with Temperature Stable High Permitivity and Low Microwave Loss H.M.O. Bryan;J. Thomson
  3. J. Am. Ceram. Soc. v.58 no.910 Ba₂$Ti_{9}O_{20}$as Microwave Dielectric Resonator J.K. Ploured;D.F. Linn;H.M. O'Bryan;J. Thomson
  4. Hermsdorfer Technishe Mitteilungen v.Heft 30 no.947-950 Dielektrische Eigenschaften Van Zusammensetzungen in System BaO-TiO₂ Naumann;J.Plotner;W. Stellenberger, K.
  5. INT. J Electronics v.51 no.3 A stabilised X-band MIC Gunn Oscillator Using a Dielectric Resonator Deepak. Singh;D. K. Chatteriee;E. Bhagiratha RaO.
  6. Japanese. J. Appl. Physics v.22 no.7 Effect of Mn Doping on the Dielectric Properties of Ba₂$Ti_{9}O_{20}$Ceramics at Microwave Frequency Schoichiro Normura;Keilchiro Tomaya;Kumiko Kaneta
  7. Electronics Letters 22nd January v.17 no.2 MIC Impatt Diode Oscillator Stabilised by Temperature Compensated Dielectric Resonater G. B. Morgan;G. O. Obe
  8. J. Am. Ceram. Soc. v.57 no.12 Phase Equilibria in the TiO₂ Rich Region of the System BaO-TiO₂ H.M. O Bryan;J Thomson
  9. J. Am. Ceram. Soc. v.66 no.1 Ba₂$Ti_{9}O_{20}$Phase Equilibria H.M.O Bryan;J. Thomson
  10. Preparation and Properties of Ba₂$Ti_{9}O_{20}$Microwave Dielectrics by Hydrolysis of Metal Alkoxides ShinKhi Hirano;Keiichi Yokouchi
  11. J. Am. Ceram. Soc. v.41 no.10 The ternary System BaO-TiO₂-SnO₂and BaO-TiO₂-ZrO₂ G.H. Jonker;W. Kwestroo
  12. J. Am. Ceram. Soc. v.69 no.2 Alkoxide Precursor Synthesis and Characterization of Phases in the Barium-Titanium Oxide System J.J. Ritter;R.S. Roth;J.E. Blendell
  13. Titanium, it's Occurrence Chemistry and Technology(2nd ed.) J. Barksodole
  14. J. Am. Ceram. Soc. v.65 no.12 Secondphase Development in Ba Doped Rutile H.M.O Bryan;M.F. Yan