Synthesis of $SrTiO_3$ from the Mixtures of $SrCO_3$ and $TiO_2$

$SrCO_3$$TiO_2$를 사용한 $SrTiO_3$의 합성반응에 관한 연구

  • Published : 1983.01.01

Abstract

The formation of strontium titanate from several molar $SrCO_3$ and $TiO_2$ mixtures was studied in air and $CO_2$ gas Mixtures of $SrCO_3$ and $TiO_2$ were heated in air at 400-$600^{\circ}C$ DTA-TG was used to obtain thermal histories of simples heated in air and $CO_2$ gas. X-ray diffraction analysis was used to determine both the phase composition and the amounts of each phase present. The phase relationship of various compounds $SrTiO_3$, $Sr_2TiO_4$, $Sr_2Ti_3O_7$ and $Sr_4Ti_3O_{10}$ formed by the sintering in each composition was shown by the calibration curves. High temperature X-ray analysis was used to determine both the formation process and deformation process of each products. Small amount of SrTiO3 is formed first at the surface af contact SrTiO3 reacts with $SrCO_3$ to form Sr2TiO4 this is affected on the $CO_2$ pressure.

Keywords

References

  1. Phys. Re. Le. v.12 no.17 Superconductivity in Semiconducting SrTiO₃ J. F. Schooley;W. R. Hosler
  2. Phys. Re. v.134 no.2A Electronic Transport in Strontium Titanate H. P. R. Frederikes;W. R. Thurber;W. R. Hosler
  3. J. El. Soc. v.129 no.5 Electrical Conductivity in Lanthanum Doped Strontium Titanate U. Balachandran;N. G. Eror
  4. Neorg. Mater. v.12 no.4 Composition of Coprecipitated compounds of Sr and Ti and Their Behavior heated T. F. Limar;I. F. Cherednichenko;N. G. Kisel
  5. J. Phys. Chem. v.72 no.9 Solid-State Reactions of SrCO₃+TiO₂ N. H. Harris;R. I. Cook
  6. Instituti di chim. Appl. v.16 no.1 X-ray studies of several Strontium Titanates Antonio Cocco;Franco Massazza
  7. Am. Chim (Rome) v.53 no.7 Microscopic study of the System SrO-TiO₂ Antonio Cocco;Franco Massazza