A Study on the Extraction of Alumina from Kaolin

카오린으로부터 $Al_2O_3$의 용출에 관한 연구

  • 백용혁 (한양대 무기재료공학과) ;
  • 이종근 (한양대 무기재료공학과)
  • Published : 1982.02.01

Abstract

The possibility of extraction of alumina from domestic Ha-dong kaolin was studied by sulfuric acid treatment. Raw kaolin was calcined at various temperature (500-110$0^{\circ}C$) and calcined kaolin were treated with sulfuric acid. The tendency of extraction yield of alpha alumina have been investigated by relating reaction time, temperature, and acid concentration. After reaction, precipitates were analyzed by DTA, TGA, and identified alpha alumina by X-ray diffractometer with calcined sample at 120$0^{\circ}C$. The results were as follows; 1. The optimum calcination temperature was 800-86$0^{\circ}C$. 2. The most suitable extracting conditions of alpha alumina were 40 wt%-$H_2SO_4$, 2-3 hours acid-treating time and 8$0^{\circ}C$ acid-treating temperature. 3. Precipitates were composed of $(NH_4)_2SO_4$, $Al_2SO_4(OH)_4$ 5-7 $H_2O$ and $Al(OH)_3$.

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References

  1. American Ceramic Society, Special Publication no.4 Alumina as a ceramic material W. H. Gitzen
  2. Raw Materials W. E. Worrall
  3. 技報堂 物工學 吉木文平
  4. 技報堂 物工學 吉木文平
  5. JIS
  6. 分所化學 朱忠烈
  7. 窯業原料學 李鍾根
  8. J. Am. Ceram. Soc. v.52 no.2 Kineties and Mechanism of High-Temperature Reaction of Kaolinite Minerals J. F. Duncan;K. J. D. Mackenzie
  9. J. Am. Ceram. Soc v.60 Structure Analysis of the transition phases in the Kaolinite-Mullite tbermal sequence A. J. Leonard
  10. Physical Chemistry(3rd ed.) Gordon M.Barrow
  11. Octave Levenspiel v.28 Chemical Reaction Engineering 2nd Ed
  12. ?媒硏究所 論文集 v.1 國內産 高嶺土로부터 活性 알루미나의 製适 崔錫尨外