强酸性 溶液中에서의 $\beta$-4-Nitroazoxybenzene의 轉位反應에 關한 反應速度論的 硏究

Kinetics of the Rearrangement of $\beta$-4-Nitroazoxybenzene in Strongly Acidic Solution

  • 발행 : 19671200

초록

强酸性溶液 中에서 ${\beta}$-4-Nitroazoxybenzene이 4-Hydroxy-4'-Nitroazobenzene으로 轉位하는 反應을 UV 分光光度法에 의하여 確認하였다. 20Vol%의 알코올과 80Vol.%의 여러가지 농도의 황산수용액에서의 이 轉位反應 反應速度을 究明하였으며, 그 結果 이 反應이 酸觸媒에 의한 擬1次反應임을 알았으며, 또한 이 轉位反應의 機構도 考察하였다.

The rearrangement of ${\beta}$-4-nitroazoxybenzene into 4-hydroxy-4'-nitroazobenzene in strongly acidic solutions has been as certained by UV spectrophotometry. The kinetics of the rearrangement in 20 vol. % ethanol and 80 vol. % of aqueous sulfuric acid-water solutions has been studied, and the rearrangement was found to be acid catalyzed pseudo-frst-order reaction. The mechanism of the rearrangement is also discussed.

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참고문헌

  1. Atti. Accad. Lincei. v.21 A. Angelli;B. Valori
  2. Chem. Abst. v.6 A. Angelli;B. Valori
  3. Chem. Ind. (London) P.H. Gore
  4. Chem. Ind. (London) M.M. Shemyakin;V.J. Maimind;Ts. E. Ahadzhanyan
  5. J. Am. Chem. Soc. v.89 C.S. Hahn;K.W. Lee;H.H. Jaff'e
  6. J. Mol. Spectroscopy v.2 H.H. Jaff'e;S.J. Yeh;R. W. Gardner
  7. J. Korean Chem. Soc. v.6 C.S. Hahn
  8. Theory and Applications of Ultraviolet Spectroscopy H.H. Jaff'e;M. Orchin
  9. J. Am. Chem. Soc. v.84 C. S. Hahn;H. H. Jaff'e
  10. Chem. Ind. E. Buncel;B.T. Lawton
  11. Canad J. Chem. v.43 E. Buncel;B.T. Lawton
  12. Advances in Physical Organic Chemistry v.1 L.L. Schalegar;F.A. Long
  13. Chem. and Ind. M.M. Shemyakin;V. I. Maimind;B. V. Vaichunaite
  14. Zhur. Obshchei Khim. v.28 M.M. Shemyakin;V. I. Maimind;B. V. Vaichunaite
  15. Izvest. Aked. Nank. USSR, Ser. Khim. M.M. Shemyakin;Ts E. Agadzhanyan;V.I. Maimind;R.V. Kudryaotseo
  16. Org. Synt. v.33 C. Kaslow;R. Summer