Electrode Surface Analysis of Delithiated $LiCoO_2$ using Ion Chromatograph

이온 크로마토그래피를 이용한 충전전압에 따른 $LiCoO_2$ 전극의 표면 특성

  • Published : 2007.11.01

Abstract

In this paper, we report on a study of the electrode/electrolyte interfaces of MCMB/$LiCoO_2$ cell using Ion-chromatography. The cells for the experiments were preconditioned by cycling three times and stabilized at OCV of 3.0V 4.35V and 4.5V. The stabilized cathode electrode was used for surface characterization investigations. Concerning the $LiCoO_2$/electrolyte interfaces, the result obtained have shown the presence of $F^-\;and\;CO_3^{2-}$ on the surface of cathode electrode as well as increasing the concentration of ions as cell voltage increase.

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