리튬고분자 이차전지의 전기적 전기화학적 특성

  • 박수길 (충북대학교 공업화학과·충남대학교 고분자공학과) ;
  • 박종은 (충북대학교 공업화학과·충남대학교 고분자공학과) ;
  • 손원근 (충북대학교 공업화학과·충남대학교 고분자공학과) ;
  • 류부형 (동국대 산업안전공학과) ;
  • 이주성 (한양대학교 공업화학과)
  • 발행 : 1998.06.01

초록

The new type polymer electrolyte composed of polyacrylonitrile(PAN) baed polymer electrolyte contain LiClO$_4$-EC/PC and LiPF$\sub$6/-EC/PC were developed for the weightless and long or life time of lithium polymer battery system with using polyaniline electrode. The gel type electrolytes were prepared by PAN at different lithium salts in the glove box. We prepared for polymer electrolyte with knife casting method. The minimum thickness of PAN gel electrolyte for the slim type is about <400∼500$\mu\textrm{m}$. These gel electrolytes showed good compatibility with lithium electrode. The test cell of Li/polymer electrolyte/Lithium cobalt oxide solid state cell which was prepared by different lithium salt was researched by electrochemical technique. Resistance of polymer electrolyte which consist of LiClO$_4$ is more less than that of LiPF$\sub$6/ and cycle life is more longer than that of LiPF$\sub$6/.

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