연속식 MMA/MA 공중합 반응기의 정상상태 및 동특성 해석

Analysis of steady-states and dynamic characteristics of a continuous MMA/MA copolymerization reactor

The dynamic characteristics of a continuous MMA/MA free-radical solution copolymerization reactor were studied. A mathematical model was developed and kinetic parameters which had been estimated in the previous work were used. With this model, bifurcation diagrams were constructed with various parameters as the bifurcation parameter to predict the region of stable operating conditions and to enhance the controller performance. It was shown that the steady-state multiplicity existed over wide ranges of residence time and jacket inlet temperature. Periodic solution branches were found to emanated from Hopf bifurcation points. Under certain conditions isola was also observed, which would result in poor performance of feedback controllers.