• Title/Summary/Keyword: zirconium silicate (ZrSiO$_4$)

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A Study on Stabilized CdS-CdSe Red Stain A Study on Zircon Cadmium Sulphoselenide Stain (안정화 CdS-CdSe계 채료에 관한 연구 제2보$ ZrSiO_4-Cd(S_xS_{1-x})$ 의 합성)

  • 이종근;김종옥
    • Journal of the Korean Ceramic Society
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    • v.23 no.4
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    • pp.23-26
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    • 1986
  • The synthetic conditions of $ ZrSiO_4-Cd(S_xS_{1-x})$ stains from CdS, Se, $SiO_2$ , 4ZrO_2$ and Lif were investigated and the colors were examined. Colors of the stains prepared were yellow orange red pink ruby and violet in relation to both the content of CdS-Se in $ZrSiO_4$ and firing temperature. Colors of these series stains were thermally stabilized probably by the structural stability of zirconium silicate. Furthermore by the result of X-ray diffraction analysis it is assumed that color of the zircon cadmium sulphoselenide $ ZrSiO_4-Cd(S_xS_{1-x})$ stain is developed by neither the coloring ions in $ZrSiO_4$ lattice nor the solid solution of $ZrSiO_4$ and $Cd(S_xS_{1-x})$ but by the small crystals of $Cd(S_xS_{1-x})$ being occluded by the zirconium silicate during sintering process.

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High temperature Friction and Wear of Friction Material; The Effect of the Relative Amount of Graphite and Zirconium Silicate (ZrSiO$_4$) (흑연과 지르콘의 상대적 함량에 따른 마찰재의 고온 마찰 및 마모특성)

  • Kim, Seong-Jin;Jang, Ho
    • Tribology and Lubricants
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    • v.16 no.5
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    • pp.365-372
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    • 2000
  • Tribological behavior of novolac resin-based friction materials with three different relative amounts of graphite and zirconium silicate was investigated by using a pad-on-disk type friction tester. The goal of this paper is to examine the effects of the relative amount of a lubricant and an abrasive in the automotive friction material on friction and wear characteristics at elevated temperature. Friction and wear of friction materials were affected by the existence of transfer film(3$\^$rd/ body layer) at friction interface and the composition of friction material, especially lubricant amount. The friction material with higher content of graphite indicated homogenized and durable transfer film, and resulted in stable friction coefficient regardless of the increase in friction heat. The experimental result also showed that the higher concentration of ZrSiO$_4$ in friction material aggravated friction stability and wear resistance due to the higher friction heat generated at fiction interface during high temperature friction test.

Influence of the Relative Amount of Graphite and Zirconium Silicate on Friction Characteristics (흑연과 지르콘의 상대적인 함량에 따른 마찰특성에 관한 연구)

  • Kim, Seong-Jin;Jang, Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.06a
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    • pp.166-172
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    • 2000
  • Friction characteristics of phenolic resin-based friction composites containing threedifferent relative amounts of graphite and zirconium silicate were investigated by using a pad-on-disk type friction tester. Constant temperature test and constant interval test at three different initial temperatures(100. 200, 300$^{\circ}C$) were performed to examine the effects of friction heat on friction characteristics at elevated temperature. The friction composite(FMO.7) with higher content of ZrSiO$_4$showed unstable friction force at higher temperature and resulted in larger fluctuations of vibration during friction test. The abrasive action of ZrSiO$_4$in friction composite impeded stable transfer film and induced higher friction heat at friction interface. Friction oscillations according to the temperature were associated with the formation of transfer film(i'd body layer) on the friction composite and the counter part.

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A Study on Coagulation Process using Zirconium Silicate as a Coagulation-aid (지르코늄 실리케이트를 응집보조제로 이용한 응집공정에 관한 연구)

  • Cho, Jae-Seung;Yoon, Tai-Il;Jeon, Yu-Jae;Cho, Kyung-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.3
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    • pp.203-207
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    • 2009
  • The concern of seriousness and harmful effects of environmental pollution is rising by the various water pollutions, appearances of new micro-noxious substances and increase of sustainable pollutants. The method is suggested that can effectively increase the removal of organic substances and several pollutants using a coagulation process. The experiment for characteristics of $ZrSiO_4$ (zirconium silicate) as a coagulation-aid was carried out for application to coagulation process with domestic wastewater and lake water, and the removal rate of the organic substances depending on a dosage was evaluated by PDA (Photometric Dispersion Analyzer) in this study. Zeta-potential of zirconium silicate solution was -32.22 mv at pH 7 and the lower negative(-) charge was detected in the more acidic conditions. Absorbance on $UV_{254}$ presented higher when zirconium silicate was added than in a domestic wastewater itself. Besides, the results by PDA experiment represented that injection of zirconium silicate could promote growing of floc. Tests for coagulation process were conducted by three ways which are pre-injection, co-injection and post-injection of zirconium silicate with alum. Accordingly, removal efficiency of organic substances increased over 15% in co-injection than in using of alum as a sole reagent. When a 20 mg/L of alum was used with a 10 mg/L of zirconium silicate, the removal efficiency was high up to 90%. Removal efficiency of $COD_{Cr}$ was improved more than 15% in case of dosage of coagulant either PAC (Poly aluminium chloride) or PACS (Poly aluminium chloride Silicate) together with zirconium silicate. As a result, the removal efficiency of $COD_{Cr}$ were 5~10% higher in a co-injection of zirconium silicate with a coagulant than a pre-injection and a post-injection but it of soluble substances was lower in a co-injection.

Effect of the Amount of a Lubricant and an Abrasive in the Friction Material on Friction Characteristics (자동차 제동시 나타나는 마찰특성에 관한 연구(I. 고체 윤활제($Sb_2S_3$)와 연마제($ZrSiO_4$)의 함량에 따른 영향)

  • Jang, Ho
    • Tribology and Lubricants
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    • v.13 no.1
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    • pp.34-41
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    • 1997
  • Frictional behavior of three automotive friction materials (brake pads) containing different amounts of antimony trisulfide ($Sb_2S_3$) and zirconium silicate ($ZRSiO_4$) were investigated using a front brake system. The friction materials were tested on a brake dynamometer (dyno) with gray cast iron rotors. The dynamometer(dyno) test simulated the dragging of a ehicle maintaining 70 km/h and vehicle stops from 100 km/h using 20 different combinations of initial brake temperature (IBT) and input pressure (IP). The results showed a strong influence of the relative amount of $Sb_2S_3$ and $ZrSiO_4$ in friction materials on friction characteristics. Friction stability was improved with the higher concentration of $Sb_2S_3$ in the friction material. Torque variation during drag cycle was increased with an increase of the $ZrSiO_4$ concentration in the friction material. Average friction coefficient and the wear rate of the friction material increased by using more aggressive friction materials containing more $ZrSiO_4$ and less $Sb_2S_3$. Generation of the disk thickness variation (DTV) increased when friction materials with higher concentration of $ZrSiO_4$ were used Careful examination of DTV change showed that aggressiveness of the friction material played an important role in determining torque variation.