• 한국세라믹학회지
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• 제29권10호
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• pp.757-764
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• 1992

The platelet reinforced mullite-zirconia composites were prepared by pressurelss sintering with addition of Al2O3 or SiC platelets. The sintered density of 10 vol% Al2O3 platelet reinforced mullite-zirconia composite was 98.3% at 1700$^{\circ}C$. The fracture strength (290 MPa) and fracture toughness (4.9 MPa$.${{{{ SQRT { m} }}) in the Al2O3 platelet reinforced mullite-zirconia composite were enhanced compared with those of mullite-zirconia due to the crack deflection and load transfer effect of platelets. Whereas, the SiC platelet reinforced mullite-zirconia composite sintered at 1650$^{\circ}C$ showed relatively lower density (95.7%), fracture strength (170 MPa), and fracture toughness (3.9 MPa$.${{{{ SQRT { m} }} than the Al2O3 platelet reinforced mullite-zirconia composite.

• 한국세라믹학회지
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• 제49권6호
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• pp.566-574
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• 2012

Porous zirconia ceramics are widely considered to be important due to their unique properties and potential applications. In this paper, we propose a novel approach to produce porous zirconia ceramics. The linear shrinkage of the prepared porous zirconia ceramics could be controlled to 4% by incorporating pre-sintered zirconia granules and hollow polymeric spheres. We also investigated the effect of pre-sintered zirconia granules on the microstructure and the properties, such as the porosity, pore distribution, and bending strength of the porous zirconia ceramics.

• 대한심미치과학회지
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• 제32권2호
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• pp.46-53
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• 2023

도자기 파절은 금속도재, 전부도재, 지르코니아 수복물의 흔한 문제점이다. 이와 관련되 여러가지 요소들이 제시되는데, 금속의 물성, 금속도재의 금속 코핑의 형태, 가공 방법, 지지형태, 교하벽, 비기능적 습관들이 포함된다. 이 논문에서는 이런 요소들을 조금더 구체적으로 살펴보고자 한다.

• 한국자동차공학회논문집
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• 제1권2호
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• pp.89-102
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• 1993

In this experimental investigation, various plasma-sprayed zirconia contained coatings and a kind of alumina-zirconia coating were studied to gain a better understanding of their tribological behaviour under dry contact condition in a reciprocating motion at temperature of 200℃. Particular attention was made for finding appropriate coatings in cylinder liner/piston ring application with an emphasis on the antiwear property. In order to identify the wear mechanism, SEM(Scanning Electron Microscope), optical micrograph, and roughness tester were used. Alumina-zirconia and 8% yttria-zirconia were found to be most appropriate for the application to the cylinder liner/piston ring and, especially, alumina-zirconia exhibited highest wear-resistance and also showed good friction characteristics. Wear mechanisms of ceramic coatings identified.

• 한국정밀공학회지
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• 제28권7호
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• pp.783-788
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• 2011

The recent development of bio-ceramic material is being studied in various bio-material engineering field. There are lots of technical difficulties because manufacturing or bonding technique are required bio-friendliness, cleanliness and persistence. Zirconia ceramic powder is cladded on Ti-6AI-4V metallurgically by laser cladding processing. Laser cladding system with powder feeding delivery is designed and manufactured for optimum processing condition. Increasing of manufacturing speed and good quality of clad layer are achieved by application of preheating of substrate before laser cladding. The thin dilution and good clad layer on the substrate are obtained for applications of bio-materials such as the dental materials and the articulated joints of human body.

• Bulletin of the Korean Chemical Society
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• 제23권8호
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• pp.1127-1134
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• 2002

Fine ceramic particles of zirconia toughened alumina (ZTA), titania toughened alumina (TTA), and zirconia-titania toughened alumina (ZTTA) have been synthesized by ultrasonic spray pyrolysis (USP) at various temperatures from starting salt solutio ns of various compositions aiming for the development of catalytic material. These particles were characterized for properties such as shape, size and size distribution, diffraction pattern, and chemical and phase composition of elements by scanning electron microscopy (SEM), particle size analyzer (PSA), x-ray diffraction (XRD), and inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Chemical compositions and sizes of ceramic composites have been controled by the stoichiometry of salt solutions and the flow rate of spraying solutions. The optimum experimental conditions for the various composite particle syntheses have been proposed.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2007년도 춘계학술대회 논문집
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• pp.7-8
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• 2007

• 한국세라믹학회지
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• 제31권9호
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• pp.1060-1068
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• 1994

Stable zirconia sol was prepared from zirconium butoxide Zr(OC4O9)4 as a precursor and ethylacetoacetate(EAcAc) or diethylene glycol(DEG) as a chelating agent under ambient agent under ambient atmosphere by Sol-Gel process. The sythesized sol was coated on 304 stainless steel substrate by dip coating, thereafter zirconia film could be obtained by heat-treatment at $600^{\circ}C$. The characteristics of coating film were determined by FT-IR, XRD, and ellipsometion peak represented Zr-O-Zr bonding of tetragonal phase was shown at 470cm-1. Crystallization of zirconia gel and film from amorphous state to tetragonal phase started at 40$0^{\circ}C$, and then transformed into monoclinic phase around $700^{\circ}C$. Zirconia film coated on 304 stainless steel substrate showed relatively low porosity of 16% when it was coated with 0.4M zirconia sol and thereafter heat-treated at 80$0^{\circ}C$ and the film was densified continuously up to 90$0^{\circ}C$. The zirconia film of 10 nm thick acted as a protective layer against oxidation up to $700^{\circ}C$.

• 대한치과기공학회지
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• 제31권2호
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• pp.39-44
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• 2009

In the orthopedic field which firstly used zirconia as artificial joints, researchers had studied the reasons for collapsing zirconia used as restorative material by accumulated inner cracks in several years and they found out Low Temperature Degradation is one of the reasons. In the dentistry field, it has not been too long since they used zirconia as the cores of all-ceramic restoration; however, the study is needed as prophylactic measure against Low Temperature Degradation which can be caused by saliva wetting the mouth all the time and frictional forces such as bite pressure and masticatory pressure. Artificial aging by autoclaving is used because there are difficulties of testing in the patient's mouth. To study the changes in the material properties, the flexural strength of dental zirconia ceramic is measured before and after the test. The following are the result of the test. 1) The zirconia blocks in the autoclaves at $130^{\circ}C$ and $200^{\circ}C$ are phase-shifted tetragonal to monoclinic by Low Temperature Degradation. 2)The non-autoclaved specimens have the average fractural strength of 1346.4MPa, the specimens autoclaved at $130^{\circ}C$ have 1226.4Mpa and the specimens autoclaved at $200^{\circ}C$ have 1024.1MPa. The tests show that as the temperature increases, the flexural strength tend to decrease and the differences are noticeable(p<0.001). 3)Through the Duncan's post-hoc test, the differences in flexural strength of the 3 groups were listed in order of strength like normal temperature>at $130^{\circ}C$ autoclave low temperature degradation> at $200^{\circ}C$ autoclave low temperature degradation.

• 한국세라믹학회지
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• 제29권3호
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• pp.167-176
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• 1992

Zirconia-toughnened alumina(ZTA) powders that were uniformly coated with zirconia and yttria on the surface of alumina particles were prepared in order to inhibit the grain growth of alumina. Alumina particles were ultrasonically dispersed in the ethanol solution of Zr-n-propoxide, and then the Zr-alkoxide was hydrolyzed. Hydrated zironia as thin film was stabilized to tetragonal crystalline form by doping yttria as a stabilizer. The prepared ZTA powders had the good sinterability even at the lower temperature. As a result, the sintered bodies showed the enhanced fracture toughness compared with pure alumina. The relative density and fracture toughness(KIC) of the ZTA bodies sintered at 1550$^{\circ}C$ were 98% and 5 MPa$.$m1/2 respectively.