• Title/Summary/Keyword: zinc acetate

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Effects of Zinc Containing Solution on Oral Microorganisms (Zinc 수용액이 구강 미생물에 미치는 영향)

  • 이상구;김은숙;이승우
    • Journal of Oral Medicine and Pain
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    • v.23 no.4
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    • pp.343-352
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    • 1998
  • This experiment was performed to investigate effects of zinc containing solution on the major normal flora Staphylococccus aureus, Streptococus mutans and Candida albicans and to observe the variation according to anionic change and concentration difference. Zinc chloride, zinc iodide and zinc acetate solution were added to werially diluted broth culture so that each final concentration might be 0.25%, 0.5%. 1%. After that, 100ul of each aliquot was spreaded on each selective media plate( Mannitol Salts Agar plate for Staphylococcus aureus, Mitis Salivarius Agar plate for Streptococcus mutans and Sabouraud Destrose Agar plate for Candida albicans). The % killing was calculated bu CFU count after incubation under the appropriate condition. 1. zinc iodide, zinc chloride, and zinc acetate solutions showed inhibitory effects on Staphylococcus aureus, Streptococcus mutans and Candida albicans. 2. The inhibitory effects on Staphylococcus aureus were ranked in order of ainc iodide, zinc chloride and zinc actate. 3. The inhibitory effects on Streptococcus mutans were ranked in orfer of zinc iodide, zinc chloride and zinc acetate. 4. the inhibitory effects on Candida albicans showed no difference among zinc iodide, zinc chloride and zinc acetate. 5. The inhibitory effects of zinc chloride and zinc acetate on Staphylococcus aureus and Streptococcus mutnas showed increasing pattern as the concentration increase. But the inhibitory effects of zinc iodide on Staphylococcus aureus and Streptococcus mutans showed no apparent difference according to concentrations and it was the case with the inhibitory effects of zinc iodide, zinc chloride and zinc acetate on Candida albicans.

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Preparation of Zinc Oxide by Hydrothermal Precipitation and Degradation of Tartrazine (수열 합성법에 의한 Zinc Oxide의 제조 및 Tartrazine 분해 특성)

  • Na, Seok-Eun;Jeong, Sang-Gu;Jeong, Ga-Seop;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.752-757
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    • 2011
  • The effects of reaction temperature, reactant concentration, pH of solution and mixing order of reactants on the particle shape and size distribution of zinc oxide were investigated in the preparation of zinc oxide from ammonium hydroxide and zinc acetate by the method of aqueous hydrothermal precipitation method, and the photocatalytic ability of zinc oxide synthesized was measured from the degradation of tartrazine under UV irradiation. The average particle size was increased with pH of solution but decreased with zinc acetate concentration and reaction temperature. The optimum condition for the synthesis of minimum sized zinc oxide was pH 11.2, concentration of zinc acetate 0.6 M and reaction temperature $90^{\circ}C$, and its average particle size was 3.133 ${\mu}$m. 97% of tartrazine was degraded by zinc oxide in sixty minutes.

Fabrication of ZnO films from directly heated Zinc-Acetate and oxygen effects on the deposition (Zinc-acetate 직접 가열에 의한 ZnO막의 제조 및 산소분위기 영향)

  • 마대영;이수철;김상현;박기철;김기완
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.400-405
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    • 1995
  • ZnO films have been grown easily with the conventional thermal evaporation method on SiO$\_$2/ coated Si wafers. Anhydrous zinc acetate has been used as evaporation source. Zinc-acetate was directly heated in the laboratory-made brass boat. Zinc-acetate was sublimed at the boat temperature of about 220.deg. C. The substrates were heated to 600.deg. C with home made tantalium heater. Oxygen has been flowed into the deposition chamber to change the partial pressure of oxygen. X-ray diffraction patterns showed all the films to be amorphous. The films deposited at high oxygen pressure exhibit higher resistivity than films at low pressure. Energy dispersive spectroscopy(EDS) and rutherford backscattering spectrometry(RBS) were conducted on the films to reveal the composition of the ZnO films.

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Preparation of Zinc Oxide by Hydrothermal Precipitation Method and their Photocatalytic Characterization (수열합성법에 의한 산화아연의 제조와 광분해 특성)

  • Jeong, Sang-Gu;Na, Seok-Eun;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.808-814
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    • 2012
  • Photocatalytic zinc oxide powders were prepared from precursor zinc acetate and ammonia solution at elevated temperature, $80^{\circ}C$, by hydrothermal precipitation method. The effect of operating parameters, pH of ammonia solution and concentration of zinc acetate solution, on the characteristics of zinc oxide powders were experimentally examined. Zinc oxide powders prepared at the conditions of pH 11, zinc acetate concentration of 1.0 M, precipitation temperature of $80^{\circ}C$, showed smallest average particle diameter of $3{\mu}m$. SEM and XRD analysis confirmed that prepared zinc oxide has hexagonal rods structure, and Anatase type crystallinity. In addition, DRS and PL analysis showed that the zinc oxide has activity at the range of 200~400 nm of UV light. And the zinc oxide decomposed 57% of a food-color stamp Brilliant blue FCF for 3 hours under the UV radiation.

Characteristics of $ZnO_{x}$ films deposited by using zinc acetate as precursor (Zinc acetate를 precursor로 하여 증착한 $ZnO_{x}$막의 특성)

  • 마대영;김상현;이수철;김영진;김기완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.129-133
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    • 1994
  • $ZnO_{x}$ films were deposited by conventional thermal evaporation method. Zinc acetate was used as precursor. XRD and SEM results shows films as mixed stats of ZnO and zinc acetate. And EDX measurements reseal composition of films as $ZnO_{x}$.

Growth and Properties of $Cd_{1-x}$$Zn_x$/S Films Prepared by Chemical Bath Deposition for Photovoltaic Devices (Chemical Bath Depsoition법에 의한 $Cd_{1-x}$$Zn_x$/S 박막의 제조 및 특성에 관한 연구)

  • 송우창;이재형;김정호;박용관;양계준;유영식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.104-110
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    • 2001
  • Structural, optical and electrical properties of Cd$_{1-x}$ Zn$_{x}$S films deposited by chemical bath deposition(CBD), which is a very attractive method for low-cost and large-area solar cells, are presented. Especially, in order to control more effectively the zinc component of the films, zinc acetate, which was used as the zinc source, was added in the reaction solution after preheating the reaction solution and the pH of the reaction solution decreased with increasing the concentration of zinc acetate. The films prepared after preheating and pH control had larger zinc component and higher optical band gap. The crystal structures of Cd$_{1-x}$ Zn$_{x}$S films was a wurtzite type with a preferential orientation of the (002) plane and the lattice constants of the films changed from the value for CdS to those for ZnS with increasing the mole ratio of the zinc acetate. The minimum lattice mismatch between Cd$_{1-x}$ Zn$_{x}$S and CdTe were 2.7% at the mole ratio of (ZnAc$_2$)/(CdAc$_2$+ZnAc$_2$)=0.4. As the more zinc substituted for Cd in the films, the optical transmittance improved, while the absorption edge shifted toward a shorterwavelength. the photoconductivity of the films was higher than the dark conductivity, while the ratio of those increased with increasing the mole ratio of zinc acetate. acetate.

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Size Control and Optical Properties of ZnO nanoparticles by Zinc-Lithium-Acetate System (Zinc-Lithium-Acetate System을 통한 ZnO 분말 크기제어 및 광학 특성 연구)

  • Yu, Ri;Kim, YooJin
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.371-375
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    • 2013
  • ZnO nanoparticles in the size range from 5 to 15 nm were prepared by zinc-lithium-acetate system. The morphologies and structures of ZnO were characterized by TEM, XRD and FT-IR spectra. UV-visible results shows that the absorption of ZnO nanoparticles is blue shifted with decrease in particles size. Furthermore, photoluminescence spectra of the ZnO nanoparticles were also investigated. The ZnO nanoparticles have strong visible-emission intensity and their intensities depend upon size of ZnO nanoparticles.

The analysis on the optical properties of $Cd_1-_xZn_xS$ films deposited by CBD method (CBD법을 이용한 Cd1-xZnxS 박막의 광학적 특성분석)

  • Son, W.C.;Lee, J.H.;Kim, J.H.;Moon, J.S.;Park, Y.K.;Yang, K.J.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1649-1651
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    • 2000
  • Optical properties of $Cd_{1-x}Zn_{x}S$ films deposited by :chemical bath deposition(CBD), which is a very attractive method for low-cost and large-area solar cells, are presented, Especially, in order to control more effectively the zinc component of the films, zinc acetate, which used as the zinc source, mixed in reaction solution after preheating and the pH of the reaction solution decreased with increasing the concentration of zinc acetate. The films prepared after preheating and pH control had larger zinc component and higher optical band gap. As the more zinc substituted for Cd in the films, the optical transmittance improved, while the absorption edge shifts to a shorter wavelength and the optical band gap increased. The photo conductivity of the films was larger than the dark conductivity, while the ratio of those increased with increasing the mole ratio of zinc acetate.

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Electrochemical Properties of Gel Polymer Electrolyte including Zinc Acetate Dihydrate for Zinc-Air Batteries (아연-공기 전지용 아세트산 아연 이수화물을 첨가한 고분자 전해질의 전기화학적 특성)

  • Hui Seo Kim;Dong Yun Lee;Yong Nam Jo
    • Korean Journal of Materials Research
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    • v.33 no.12
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    • pp.550-557
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    • 2023
  • In zinc-air batteries, the gel polymer electrolyte (GPE) is an important factor for improving performance. The rigid physical properties of polyvinyl alcohol reduce ionic conductivity, which degrades the performance of the batteries. Zinc acetate is an effective additive that can increase ionic conductivity by weakening the bonding structure of polyvinyl alcohol. In this study, polymer electrolytes were prepared by mixing polyvinyl alcohol and zinc acetate dihydride. The material properties of the prepared polymer electrolytes were analyzed by Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). Also, Electrochemical impedance spectroscopy was used to calculate ionic conductivity. The electrolyte resistances of GPE, 0.2 GPE, 0.4 GPE, and 0.6 GPE were 0.394, 0.338, 0.290, and 0.213 Ω, respectively. In addition, 0.6 GPE delivered 0.023 S/cm high ionic conductivity. Among all of the polymer electrolytes tested, 0.6 GPE showed enhanced cycle life performance and the highest specific discharge capacity of 11.73 mAh/cm2 at 10 mA. These results verified that 0.6 GPE improves the performance of zinc-air batteries.

Etching of Zinc Oxide(ZnO) Using Isomer of Butyl Acetate (부틸아세트산 메틸 이성체에 의한 산화아연(ZnO)의 식각)

  • Lee, Bong-Ju;Jeong, Heon-Sang;Lee, Gyeong-Seop
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.3
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    • pp.111-114
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    • 2002
  • Using the plasma that we developed to generate a low-temperature plasma at atmospheric pressure, we have investigated the etching possibility of an air-exposed zinc oxide(ZnO) thin films. Hydrogen and methane radicals generated from the plasma were observed and their intensity was found to be dependent on the isomer of butyl acetate by an analysis with optical emission spectrosxopy. The etching ability of this plasma was evaluated by an emission intensity, etching time, rf power.