• Korean Journal of Heritage: History & Science
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• v.55 no.2
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• pp.200-211
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• 2022

The celadon stools with an openwork ring design which consist of four items as one collection were excavated from Gaeseong, Gyeonggi-do Province. The celadon stools were designated and managed as treasures due to their high arthistorical value in the form of demonstrating the excellence of celadon manufacturing techniques and the fanciful lifestyles during the Goryeo Dynasty. However, one of the items, which appeared to have been repaired and restored in the past, suffered a decline in aesthetic value due to the aging of the treatment materials and the lack of skill on the part of the conservator, raising the need for re-treatment as a result of structural instability. An examination of the conservation condition prior to conservation treatment found structural vulnerabilities because physical damage had been artificially inflicted throughout the area that was rendered defective at the time of manufacturing. The bonded surfaces for the cracked areas and detached fragments did not fit, and these areas and fragments had deteriorated because the adhesive trickled down onto the celadon surface or secondary contaminants, such as dust, were on the adhesive surface. The study identified the position, scope, and conditions of the bonded areas at the cracks UV rays and microscopy in order to investigate the condition of repair and restoration. By conducting Fourier-transform infrared spectroscopy(FT-IR) and portable x-ray fluorescence spectroscopy on the materials used for the former conservation treatment, the study confirmed the use of cellulose resins and epoxy resins as adhesives. Furthermore, the analysis revealed the addition of gypsum(CaSO₄·2H₂O) and bone meal(Ca₁₀ (PO₄)₆(OH)₂) to the adhesive to increase the bonding strength of some of the bonded areas that sustained force. Based on the results of the investigation, the conservation treatment for the artifact would focus on completely dismantling the existing bonded areas and then consolidating vulnerable areas through bonding and restoration. After removing and dismantling the prior adhesive used, the celadon stool was separated into 6 large fragments including the top and bottom, the curved legs, and some of the ring design. After dismantling, the remaining adhesive and contaminants were chemically and physically removed, and a steam cleaner was used to clean the fractured surfaces to increase the bonding efficacy of the re-bonding. The bonding of the artifact involved applying the adhesive differently depending on the bonding area and size. The cyanoacrylate resin Loctite 401 was used on the bonding area that held the positions of the fragments, while the acrylic resin Paraloid B-72 20%(in xylene) was treated on cross sections for reversibility in the areas that provided structural stability before bonding the fragments using the epoxy resin Epo-tek 301-2. For areas that would sustain force, as in the top and bottom, kaolin was added to Epo-tek 301-2 in order to reinforce the bonding strength. For the missing parts of the ring design where a continuous pattern could be assumed, a frame was made using SN-sheets, and the ring design was then modeled and restored by connecting the damaged cross section with Wood epos. Other restoration areas that occurred during bonding were treated by being filled with Wood epos for aesthetic and structural stabilization. Restored and filled areas were color-matched to avoid the feeling of disharmony from differences of texture in case of exhibitions in the future. The investigation and treatment process involving a variety of scientific technology was systematically documented so as to be utilized as basic data for the conservation and maintenance.

• Fire Science and Engineering
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• v.29 no.1
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• pp.12-18
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• 2015

This study has conducted an experiment of comparing the flame resistant performance and combustion characteristics according to flame resistant treatment using the Cypress Luba and particle board that is commonly used for interior decoration and furniture. As a result of testing the flame resistant performance of Cypress Luba, the Cypress Luba injected with flame resistant resin using the vacuum pressure treatment has shown to have better performances (carbonized area 9.55% and carbonized length 22.91%) than the Cypress Luba treated with flame resistant coating having rubberized plastic components on its surface. For particle board, the specimen attached with fireproof film was identified to be better (carbonized area 40.10% and carbonized length 43.40%) than the specimen with non-fireproof film. For the results of combustion characteristics using the Cone Calorimeter, the specimen treated with flame resistant coating on the surface had faster ignition than the Cypress Luba injected with fire resistant resin using vacuum pressure treatment, and in the total release of calories, the Cypress Luba injected with fire resistant resin using vacuum pressure had $68.2MJ/m^2$, and the specimen treated with fire resistant coating on the surface had $111.52MJ/m^2$. For the particle board, the ignition time had a little difference but in the total release of calories, the specimen attached with fireproof film had $90.1MJ/m^2$ and the specimen with non-fireproof film had $107.6MJ/m^2$.

• 보존과학연구
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• s.35
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• pp.121-127
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• 2014

The Vietnam homecoming box that has been collected in National Museum of Korean The Vietnam homecoming box that has been collected in National Museum of Korean Contemporary History got severely damaged such as rot, attached foreign substance, fading, color, wood decay. In particular, the bottom of the box was unstable state that deteriorated by pests and the left strut was severely damaged by some deep cracks and pests. The metal bands were remained on the side and bottom of the box, and all the bands were seriously corroded. On the bottom-right of the lid, black foreign matter was adhered to the surface. In the process of conservation treatments, the cleaning, filling cracks, reinforcing the bottom of the box, attaching the metal bands were proceed in order after the investigation of the state.

• Journal of the Korean Wood Science and Technology
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• v.25 no.4
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• pp.17-21
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• 1997

This study was carried out to develop the manufacturing technique of Korean paper(Hanji) and find out new uses of machine-made Hanji produced on a a large scale by paper machine. Six kinds of Hanji were made and laminated with backpaper by acryl-based or vinyl acetate ethylene-based adhesive. Six kinds of wallpapers were made such as WH 1, WH 2-1, WH 2-2, WH 3-1, WH 3-2 and WH 4. Physical properties and quality test on the wallpapers were examined. Physical strength of the wallpapers was better than each strength of the Hanji and backpaper. It might be a roll of adhesive. And so, Production cost of the Hanji could be brought down if the Hanji was made thin to get strength not enough to cut during lamination of two papers(Hanji and backpaper). Hanji wallpapers of WH 3-1 and WH 4 are lower than a standard in sunlight resistance and WH 1 is in properties of opacity. WH 2-1, WH 2-2 and WH 3-2 were better than Korean standard in some quality tests. WH 2-2 and WH 3-2 were superior to other wallpapers as a whole. About, twenty kinds of wallpapers with surface treatment, are now being produced on the basis of these two types of wallpapers.

• Journal of Conservation Science
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• v.35 no.3
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• pp.245-251
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• 2019

In this paper, conservation treatment processes for the wooden furniture in the Presidential Archives are introduced. Conservation treatment strategies for modern wooden cultural heritage have been increasingly studied. The current study uses materials similar to those used by the existing conservation treatment method. Material analysis showed that the chair(Lee136-2) and desk(Yun37) in the Presidential Archives are made of Dipterocarpaceae, and both are coated with two layers of varnishing. FT-IR analysis showed that the varnish has a similar spectrum to that of a nitrocellulose-based lacquer(Lee136-2) and top coat(Yun37) and confirmed that a synthetic material was used. Pollutants had adhered to the surface of the wooden furniture and it was also in structurally unstable condition because of cracks and damage to the varnish and wood. Therefore, a conservation treatment was carried out to restore the damaged areas to their original appearance using similar kinds of materials, based on data obtained by materials analysis.

• Journal of the Korean Wood Science and Technology
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• v.10 no.3
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• pp.180-188
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• 1982

This study was carried out to make hardboard fire retardants and to examine the properties of the hard-board treated with them. The fire retardant treatment was achieved by surface impregnation of water soluble retardant chemicals into the forming mat with 55 percent of moisture content. followed by the hot pressing process. Ammonium monophosphate, ammonium diphosphate, sodium borate, and boric acid were used as the fire retardants. Fire retardant test was carried out by using the differential thermal analysis thermogram. The results are summarized as follows: 1. Fire retardant-treated hardboard showed higher values of the specific gravity. water absoption, and flexural strength than those of untreated hardboard. Especially, the treatment of ammonium monophosphate gave the best results in the flexural strength, and a 10 gr/$ft^2$ loading of the fire retardant compound of ammonium monophoshate, ammonium diphosphate, and sodium borate drew the best flexural strength value among the three different experimental loadings of 10, 20 and 30 gr/$ft^2$. 2. There were no definite differences in moisture content between the fire retardant-treated hardboard and the untreated hardboard. 3. The fire retardant compound of ammonium monophosphate, ammonium diphosphate, and sodium borate resulted in the best fire retardancy, and its fire retardancy was increased in proportion to the increase of loading.

• Journal of the Korean Home Economics Association
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• v.29 no.2
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• pp.87-120
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• 1991

The purpose of this study was to identify the design characteristics of the multi-leveled chest(jang) which was the main furniture of the master bedrom(anbang) in the Chosun Dynasty. The major findings and conclusions were: 1. The front view of the multi-leveled chest were composed of a protruded top panel(kaepan), drawers, folded doors, sectional panels(chwibyok kan and morum kan) and base stand(madae) in general. Variety in the front view found more frequently in single level chests than bi- or tir-level chests. 2. The overall dimensions of each type of chest increased with increase in number of levels, but the height of the sectional parts decreased. That is, the overall proportion of the single level chests were 10 : 9, bi-level chests were 5 : 6, and tri-level chests were 2 : 3. The proportion of 1 : 1, 4 : 5, 1 : 3, 1 : 4, 1 : 5 were found often in the sectional parts such as drawers, doors, chwibyok kans and morum kans. 3. In general, the surface treatments were subtle. Carved or inlayed ornamentation were seldom seen, and most chess were finished with clear lacquer to show the natural wood grain. There were no distinctive characteristics of surface ornamentation characteristic of any one type of chest. 4. The general patterns of the metal ornaments were spade(yowidu), round, bow, rectangular(yakgua), bat and flower shapes. The multi-level chests were decorated with more metal ornament types compared with the single-level chests. 5. In conclusion, there was more variety in all the design elements in the single level chests compared with the other types of chests. The bi-and tri-level chests were quite stylized in composition, size, proportion, surface treatment, and metal ornamentation.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.271-278
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• 2006

We used polymers of alternating cationic and anionic nature to build up shells on fiber surfaces, strengthen the worn-out fibers and improve paper properties made from such fibers. OCC and ONP pulps were either dipped or salted out in the cationic polyallylamine, polyacrylamide and starch solutions. After centrifugal drying, these were followed by treatments in anionic polyacrylic acid, poly-acrylamide, and starch solutions, respectively. The shell-enhanced fibers were formed into handsheets and their physical properties evaluated. The results show that building multiple shells on worn-out fiber surfaces can strengthen the fibers and paper. The simpler and more practical impregnation-centrifuging treatment provided the desired effects, whereas salting out the polymers produced somewhat superior fibers. The latter process, were impractical, however. The first pair of polymeric shells imparted marked strength improvement, whereas later layers had diminishing efficacies. Overall, the methods can improve fiber quality, attaining paper strength requirements without resorting to expensive measures. Alternate cationic polymer and filler powders were also deposited on fiber surface based on the micriparticle system in an anticipation of stiffness gains. Platy minerals, such as montmorillonite, bentonite, sericite, clay and talc were added following cationic PAM. After dewatering of polymer-pigment shelled fiber of one to 3 pairs of layers, handsheets either calendered or uncalendered were evaluated. The results indicate that regardless of calendaring, stiffness of the handsheets did not improve appreciably while certain other strength properties showed gains. We also attempted the novel starch gel filler addition method wherein tapioca starch and filers (PCC, sericite or clay) were mixed at high solids content of 50% and cooked until gelatinized. The filled handsheets were dried under various conditions and then tested for their properties. Improvements in strengths of modified filled paper were observed.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.12
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• pp.1280-1286
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• 2006

Three different virgin activated carbons made of each coal(Calgon), coconut(Samchully) and wood(Picabiol) based activated carbon(AC) were tested for an adsorption performance of 1,4-dioxane in a continuous adsorption column. Breakthrough behavior was Investigated that the breakthrough points of coal, coconut and wood based AC were observed as 3600 bed volumn(BV), 1440 BV and 144 BV respectively. Adsorption capacity(X/M) of coal, coconut and wood based AC was observed. The reported results of adsorption capacity showed that coal based AC was highest(578.9 ${\mu}g/g$), coconut based AC was intermediate(142.3 ${\mu}g/g$) and wood based AC was lowest(7.4 ${\mu}g/g$) due to increasing specific surface area. Moreover, carbon usage rates(CURs) for coal, coconut and wood based AC had been shown as 0.48 g/day, 1.41 g/day and 6.9 g/day respectively. The constant characteristic of the system, k of coal based AC was found to be 91.5 and k of coconut based AC was found to be 17.9. Removal efficiencies of 1,4-dioxane with different ozonation dosages(2 and 5 mg/L) for 20 min ozonation had been shown 38% and 87% respectively. There was no observation for biological removal of 1.4-dioxane by attached micro-organisms when used(3.1 years and over 5 years) biological activated carbon(BAC) without pretreatment of oxidation were employed. When a combination of ozonation(2 mg/L and 5 mg/L) and BAC process for $10{\sim}30$ min was applied, removal efficiency for 1,4-dioxine increased only $2{\sim}6%$ compared to only applying ozonation. Therefore removal efficiency of BAC process prior to using oxidation was proven to negligible. Consequently, the results presented in this paper provide a better insight into the adsorption performance of 1,4-dioxane. This observation suggests that using virgin activated carbon made of coal is the best selection for removal of 1,4-dioxane in the water treatment for an advanced treatment. It is clear from this research that longer EBCT for ozonation or higher ozone concentration are more effective operation methods for removal of 1,4-dioxane than longer EBCT in the BAC process.

• Journal of Environmental Science International
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• v.19 no.3
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• pp.379-387
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• 2010

Sediments of Little Scioto (LS) River in Ohio was contaminated by poor disposal of creosote from Baker Wood Creosoting Facility. Among the primary compounds of creosote, Polycyclic Aromatic Hydrocarbons (PAHs) are the most common ingredient PAHs are known for toxic, carcinogenic and mutagenic compounds. There are many difficulties to remove the PAHs in nature environment because their characteristics are having a less water-solubility, volatile and low mobility properties as increasing the molecular weight. The generation of hydroxyl radicals (${\cdot}OH$) and hydrogen peroxide ($H_2O_2$) forms as well as high temperature (5000 K) and pressure (1000 atm) by a physico-chemical effects of ultrasound during a cavitation collapse can promote the degradation and desorption of PAHs in sediment And it can also produces shock wave and microjets which are able to change the size and surface of particle in solid-liquid system as one of physical effects. Therefore, we explored to understand the role of particle size, the effect of elimination for PAHs concentration by ultrasound and optimize the conditions for ultrasonic treatment. The condition of various size of particles (> $150{\mu}m$, < $150{\mu}m$) and solid-liquid ratio (12.5g/L, 25g/L) for the treatment was considered and ultrasonic power (430 W/L) with liquid - hexane extraction and microwave extraction method were applied after ultrasound treatment.