• Journal of the Korea Furniture Society
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• v.15 no.2
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• pp.19-27
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• 2004

As glulam is a woody material, it is necessary to be more careful in a gluing process. It takes 6-7 hours at $40-60^{\circ}C$ to harden PRF resin used in making structural glulam, and about 24 hours at room temperature. In the present process which can not use a press continuously, reducing the hardening time is necessary to increase production. The experiment was done to compare the adhesive properties of PRF resin and MUF resin through bending test, block shear strength test and water soaking test. In comparing the bending strength of prediction MOE is 1.2 times higher that actual MOE. PRF and MUF do not show significant difference in MOE and MOR, and in block shear strength test, such as shear strength and wood failure rate. However, in water soaking and boiling water soaking tests PRF and MUF show the significant difference in delamination rate.

• Journal of the Korean Wood Science and Technology
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• v.19 no.4
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• pp.18-26
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• 1991

This study was carried out to examine not only the effect and the process of activation of aluminum sulfate for the manufacture of PB and MDF, but also application of the activation treatment to PB and MOF made with MDI adhesive. The results were as follows: 1. For the manufacture of PB, activating effect did not take place Because the low moisture content of 30% in the process of activation treatment made probably insufficient activation. It needs to examine higher moisture content for the uniform and enough activation same as that of MOF. 2. In the case of MOF, Activating effect was excellent, it showed not only better results of MOR 48%, MOE 29%, IB 60% than those of the control but also better dimensional stability. 3. Application of alum activation to the PB and MDF made with MDI adhesive yielded no effects. Maybe it was the reson that the curing mechanism of MDI is different. 4. Modifing the wood surface was the oxidation and wettability was not the variable limiting glueline performance. It is necessary to make a more study about activating reaction.

• Structural Engineering and Mechanics
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• v.78 no.3
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• pp.319-332
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• 2021

The wood-concrete composite is an interesting solution in the field of Civil Engineering to create high performance bending elements for bridges, as well as in the building construction for the design of wood concrete floor systems. The authors of this paper has been working for the past few years on the development of the bonding process as applied to wood-concrete composite structures. Contrary to conventional joining connectors, this assembling technique does ensure an almost perfect connection between wood and concrete. This paper presents a careful theoretical investigation into interfacial stresses at the level of the two interfaces in composite wooden beam- reinforced concrete slab strengthened by external bonding of prestressed composite plate under a uniformly distributed load. The model is based on equilibrium and deformations compatibility requirements in all parts of the strengthened composite beam, i.e., the wooden beam, RC slab, the CFRP plate and the adhesive layer. The theoretical predictions are compared with other existing solutions. This research is helpful for the understanding on mechanical behaviour of the interface and design of the CFRP- wooden-concrete hybrid structures.

• Journal of the Korean Wood Science and Technology
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• v.33 no.2 s.130
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• pp.29-39
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• 2005

Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

• Computers and Concrete
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• v.24 no.2
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• pp.103-115
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• 2019

In this study, the strength and stiffness (EI) of wood-concrete composite beams for bridges with T-shaped cross section were evaluated. Two types of connectors were used: connectors bonded with epoxy adhesive and connectors attached to the wood just by pre-drilling (without adhesive). The connectors consisted of common steel bars with a diameter of 12.5 mm. Initially, the strength and stiffness (EI) of the beams were analyzed by bending tests with the load applied at the third point of the beam. Subsequently, the composite beams were evaluated by numerical simulation using ANSYS software with focus on the connection system. To make the composite beams, Eucalyptus citriodora wood and medium strength concrete were used. The slip modulus K and the ultimate strength values of each type of connector were obtained by direct shear tests performed on composite specimens. The results showed that the connector glued with epoxy adhesive resulted in better strength and stiffness (EI) for the composite beams when compared to the connector fixed by pre-drilling. The differences observed were up to 10%. The strength and stiffness (EI) values obtained analytically by $M{\ddot{o}}hler^{\prime}$ model were lower than the values obtained experimentally from the bending tests, and the differences were up to 25%. The numerical simulations allowed, with reasonable approximation, the evaluation of stress distributions in the composite beams tested experimentally.

• Journal of the Korean Wood Science and Technology
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• v.36 no.3
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• pp.30-38
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• 2008

Petroleum-based resin adhesives have extensively been used for the production of wood panels. However, with the increase of manufacturing cost and the environmental issue, such as the emission of volatile organic compounds, of the adhesive resins, it is necessary to be developed new adhesive systems. In this study, the potential of okara, which is a residue wasted from the production of tofu, for the development of bio-based adhesives was investigated. At first, the physical and chemical properties of okara were examined. After okara was hydrolyzed in acidic and/or alkaline solutions, okara-based adhesive resins were formulated with the mixtures of the okara hydrolyzates and phenol formaldehyde (PF) prepolymer. The adhesive resins were used for the fabrication of plywood panels, and then the adhesive strength and formaldehyde emission of the plywood panels were measured to examine the applicability of the resin adhesives for the production of plywood panels. The solids content and pH of the okara used in this study were around 20% and weak acidic state, respectively. In the analysis of its chemical composition, the content of carbohydrate was the highest, and followed by protein. The shear strengths of plywood fabricated with okara-based resin adhesives exceeded a minimum requirement of KS standard for ordinary plywood, but its wood failure did not reach the minimum requirement. In addition, the formaldehyde emissions of all plywood panels were higher than that of E1 specified in the KS standard. Based on these results, okara has the potential to be used as a raw material of environmentally friendly adhesive resin systems for the production of wood panels, but further researches - biological hydrolysis of okara and various formulations of PF prepolymer - are required to improve the adhesive strength and formaldehyde emission of okara-based resin adhesives.

• Journal of the Korean Wood Science and Technology
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• v.20 no.1
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• pp.79-85
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• 1992

아까시나무로부터 두종류의 flavanone인 7, 3', 4' - trihydroxy flavanone과 3, 7, 3', 4', 5' - pentahydroxy flavanonol이 단리되어 $^{13}C$ NMR에 의해 구조가 규명되었다. flavanone은 resorcinol A-ring과 Catechol B-ring으로, flavanonol은 resorcinol A-ring 및 pyrogallol B-ring으로 구성되고 있다.

• Journal of Forest and Environmental Science
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• v.36 no.3
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• pp.219-224
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• 2020

Urea formaldehyde resins are widely used in the manufacturing of wood composite and their usage is always combined with release of formaldehyde characterized to be hazardous to health during and after the manufacturing of the products. This study investigates the effectiveness of wood-based adhesive from oil of pyrolysed Triplochiton scleroxylon sawdust for the production of composite board. The wood-derived Pyrolytic Oil (PyO) was blended with Urea Formaldehyde (UF) resin to formed Pyrolytic Oil-Urea Formaldehyde (PyOUF). The obtained PyOUF called Wood-Based Adhesives at four blends and control (UF) viz; 1:1, 1:2, 1:3, 2:1, 1:3 were further employed to prepare the composite board and test for their bonding strength by physical (water absorption-WA and thickness swelling-Th.S) and mechanical properties (modulus of elasticity-MOE, modulus of rupture-MOR, and impact bending-IB). Data obtained was analysed using analysis of variance at α 0.05. The result of analysis of variance conducted on physical properties show significant difference (p≤0.05) between the WA values obtained when testing the different blending proportion of PyOUF and likewise between 2 and 24 h of immersion. PyOUF had significant effect (p≤0.05) on Th. S for 24 h but no significant different (p>0.05) for the 2 h period of soaking. The analysis of variance on mechanical properties of the composite board (MOE, MOR, and IB) show significance differences (p≤0.05) between the strength values obtained when testing the different ratios of PyO with UF. PyO content influenced the properties of the boards and it is evident that PyO can be used in the manufacture of composite board.

• Journal of the Korean Wood Science and Technology
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• v.31 no.2
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• pp.84-91
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• 2003

In this study, the three species (Populus euramericana, Pinus densiflora and Quercus variabilis) were cut to difference (0, 0.15, 0.3, 0.45 mm) between the size of tip and that of root of the finger (DSTR) and jointed with poly vinyl acetate (PVA) and resorcinol-phenol resin (RPR). We described the relationship between the bending strength properties of finger DSTR and the acoustic emission (AE) generated during the bending test. The results were as follows: The AE generation time of finger-jointed specimens with RPR adhesive was earlier than that with PVA adhesive. The AE cumulative event count of finger-jointed specimens with RPR adhesive continuously increased with increasing load and the event count was much more than that with PVA adhesive. Also, the AE cumulative event count for resorcinol-phenol resin adhesive obtained from low load level was abundant. The AE wave in finger-jointed specimens with RPR adhesive could be detected in the below proportional limit load. Therefore, AE signals from bending test are useful for the estimation of strength in finger DSTR specimens.

• Journal of Conservation Science
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• v.35 no.6
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• pp.681-688
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• 2019

In this study, the characteristics of natural and synthetic adhesives used in woodcraft were evaluated. The pattern of deterioration of wood and adhesives according to changes in temperature and humidity were compared. For materials, one type of anlmal glue, three kinds of polyvinyl acetate adhesives, one type of epoxy adhesive and one type of zelkova wood were selected. Characteristics of physical and chemical characteristics, weather resistance and drying speed assessment were carried out. The adhesion characteristic evaluation showed that the adhesion strength of anlmal glue and one type of polyvinyl acetate adhesive were 6.54 N/㎟ and 7.01 N/㎟, pH meter of anlmal glue and polyvinyl acetate adhesives was pH 7.03 and pH 3.32-3.59 which were range of available as an adhesive. According to the test results of weather resistance, epoxy adhesives had the highest decreasing value in adhesion strength after deterioration. In the reversible test of the adhesive, it was found to be highly reversible in NaOH, a soluble solvent excluding epoxy, but attention is required when using the wood since it may show discoloration during processing.