• 제목/요약/키워드: wetting effect

검색결과 223건 처리시간 0.025초

비이온계 계면활성제 수용액이 면직물의 습윤특성에 미치는 영향 (Effect on Nonionic Surfactant Solutions on Wetting and Absorbancy of Cotton Fabrics)

  • 김천희
    • 한국의류학회지
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    • 제25권8호
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    • pp.1444-1452
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    • 2001
  • Textile materials are frequently in contact with surfactant solutions during their manufacturing or finishing processes as well as cleaning processes in use. Liquid wetting, wicking and absorbency of textile materials, and the liquid properties, surface characteristics and pore geometry of textile materials, and the liquie-solid interactions, In this paper, 10 different nonionic surfactants, including Span 20, Twen 20, 40, 60, 80, 21, 61, 81, 65, 85, were used. The surfactants were characterized by their hydrophile-lipophile-balance (HLB) values, structures, and surface tensions. The 0.1g/dL and 1.0g/dL surfactant solutions, which were both above critical micelle concentration (CMC), were used to see the concentration effects on the wetting and absorbency of cotton fabrics. The wetting behavior and liquid retention properties of hydrophobic cotton fabrics with different nonionic surfactant solutions are reported. The contact angles are greatly decreased and the water retention values are greatly increased by adding most of the surfactants studied into the system. The extents of this effects are influenced by the characteristics of surfactants and its solutions. Hydrophilic surfactants which have low number of carbon atoms or unsaturated hydrophobe structures are more effective in improving the wetting and absorbancy of hydrophobic cotton fabrics. The water retention of hydrophobic cotton fabrics has positive relations with $cos{\theta}$, adhesion tension and work of adhesion. The 1.0g/dL surfactant solutions show similar, but slightly improved wetting and absorbency characteristics of hydrophobic cotton fabrics compared to the 0.1g/dL surfactant solutions.

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A hysteresis model for soil-water characteristic curve based on dynamic contact angle theory

  • Liu, Yan;Li, Xu
    • Geomechanics and Engineering
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    • 제28권2호
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    • pp.107-116
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    • 2022
  • The steady state of unsaturated soil takes a long time to achieve. The soil seepage behaviours and hydraulic properties depend highly on the wetting/drying rate. It is observed that the soil-water characteristic curve (SWCC) is dependent on the wetting/drying rate, which is known as the dynamic effect. The dynamic effect apparently influences the scanning curves and will substantially affect the seepage behavior. However, the previous models commonly ignore the dynamic effect and cannot quantitatively describe the hysteresis scanning loops under dynamic conditions. In this study, a dynamic hysteresis model for SWCC is proposed considering the dynamic change of contact angle and the moving of the contact line. The drying contact angle under dynamic condition is smaller than that under static condition, while the wetting contact angle under dynamic condition is larger than that under static condition. The dynamic contact angle is expressed as a function of the saturation rate according to the Laplace equation. The model is given by a differential equation, in which the slope of the scanning curve is related to the slope of the boundary curve by means of contact angle. Empirical models can simulate the boundary curves. Given the two boundary curves, the scanning curve can be well predicted. In this model, only two parameters are introduced to describe the dynamic effect. They can be easily obtained from the experiment, which facilitates the calibration of the model. The proposed model is verified by the experimental data recorded in the literature and is proved to be more convenient and effective.

Effect of Improved Surface Wetability and Adhesion of Undulated Diamond-like Carbon Structure with r.f. PE-CVD

  • Jang, Young-Jun;Kim, Seock-Sam
    • KSTLE International Journal
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    • 제9권1_2호
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    • pp.22-25
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    • 2008
  • This paper investigated the wetting and adhesion property of undulated DLC film with surface morphology controlled for a reduced real area of contact. The undulated DLC Films were prepared by 13.56 MHZ radio frequency plasma enhanced chemical vapor deposition (r.f. PECVD) by using nanoscale Cu dots surface on a Si (100) substrate. FE-SEM, AFM analysis showed that the after repeated deposition and plasma induced damage with Ar ions, the surface was nanoscale undulated. This phenomenon changed the surface morphology of DLC surface. Raman spectra of film with changed morphology revealed that the plasma induced damage with Ar ions significantly suppressed the graphitization of DLC structure. Also, it was observed that while the untreated flat DLC surfaces had wetting angle starting ranged from $72^{\circ}$ and adhesion force of 333ni. Had wetting angle the undulated DLC surfaces, which resemble the surface morphology of a cylindrical shape, increased up to $104^{\circ}$ and adhesion force decreased down to 11 nN. The measurements agree with Hertz and JKR models. The surface undulation was affected mainly by several factors: the surface morphology affinity to cylindrical shape, reduction of the real area of contact and air pockets trapped in cylindrical asperities of the surface.

비이온계 계면활성제 수용액이 PET직물의 습윤특성에 미치는 영향 제1보 : Span 20과 Tween 20의 혼합계와 희석계 (Effect of Nonionic Surfactant Solutions on Wetting and Absorbancy of PET Fabric 1. Mixtures and Dilutions of Span 20 and Tween 20)

  • 김천희
    • 한국의류학회지
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    • 제27권9_10호
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    • pp.1153-1159
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    • 2003
  • The effects of changing aqueous solution properties by nonionic surfactants on wetting behavior and water retention properies of hydrophobic PET (polyethylene terephthalate) fabric were reported. The aqueous solution properties were diversified by mixing and diluting two nonionic surfactants, i.e., sorbitan monolaurate (Span 20) and polyoxyethylene(20) sorbitan monolaurate (Tween 20). The surface wetting properties ($cos{\theta}$) of PET fabric were greatly improved by adding $10^{-1}g/dl$ Tween 20 and further improved by mixing Span 20 to the system. The water retention properties (W) of PET fabric were also greatly increased by addition of $10^{-1}g/dl$ Tween 20. In diluted surfactant systems, the $cos{\theta}'s$ were increased with decreasing surface tension of aqueous liquids. The ratios of aqueous liquid retained in the pore structure to liquid retention capacity (W/H) were also increased with decreasing surface tension, however, W/H values were dramatically increased right after critical micelle concentration (cmc). The existence of micelles was important for the retention of aqueous liquids in the fabric. The critical surface tension of PET fabric used was found to be 28.7dyne/cm.

건습반복을 받는 콘크리트의 염소이온 침투에 관한 실험적 연구 (An Experimental Study on the Penetration of Chloride Ions to Concrete Subjected to Wetting and Drying Conditions)

  • 김은겸;최영규;김승진
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.838-841
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    • 2004
  • This paper presents the experimental results on the penetration of chloride. ions to ordinary portland cement concrete which is subjected to 2 different artificial environments; consecutive digestion, wetting at $3\%$ NaCl for 1 day and then drying at $40^{\circ}C$ oven for 4 days. The water-cement ratio was $35\%,\;45\%,\;55\%$. Test results showed that the intrusion depth and concentration of chloride ions penetrated into concrete in repeated wetting-drying environments were respectively deeper and higher than those of consecutive digestion environment. The penetration of chloride ions deeply depend on the effect of water to cement ratio.

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풍화계열 사면의 불포화 함수특성곡선 이력이 강우 침투에 미치는 영향 (Effect of Hysteresis on Soil-Water Characteristic Curve in Weathered Granite and Gneiss Soil Slopes during Rainfall Infiltration)

  • 신길호;박성완
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2006년도 춘계 학술발표회 논문집
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    • pp.28-33
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    • 2006
  • Shallow failures of slopes in weathered soils are caused by infiltration due to prolonged rainfall. These failures are mainly triggered by the deepening of the wetting band accompanied by a decrease in suction induced by the water infiltration. In this paper, hysteresis on soil-water characteristic curve(SWCC) of granite and gneiss weathered soils are investigated using transient flow analysis respectively. Each case was subjected to artificial rainfall intensities and time duration depending on the laboratory-based drying and wetting processes. The results show that the unsaturated seepage on weathered slopes are very much affected by the initial suction of soils and unsaturated permeability of the soils. In addition, a granite weathered soil has a lower air-entry value, residual matric suction, and wetting front suction and less hysteresis loop than a gneiss weathered soil.

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Charge Transport at the Interfaces between Carbon Nanotube and Wetting Metal Leads Mediated via Topological Defects

  • Ko, Kwan Ho;Kim, Han Seul;Kim, Hu Sung;Kim, Yong-Hoon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.179.2-179.2
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    • 2014
  • Carbon nanotubes (CNT)-metal contacts play an important role in nanoelectronics applications such as field-effect transistor (FET) devices. Using Al and (10,0) CNT, we have recently showed that the CNT-metal contacts mediated via topological defects within CNT exhibits intrinsically low contact resistance, thanks to the preservation of the sp2 bonding network at the metal-CNT contacts.[1] It is well-established that metals with good wetting property such as Pd consistently yield good contacts to both metallic and semiconducting CNTs. In this work, the electronic and charge transport properties of the interfaces between capped CNT and Pd will be investigated based on first-principles computations and compared with previous results obtained for the Al electrodes.

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표면 젖음성이 스프레드-스플래시 영역 간 천이 조건에 미치는 효과 (Surface Wetting Effect on Spread-Splash Transition Criterion)

  • 류성욱;이상용
    • 한국분무공학회지
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    • 제12권4호
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    • pp.198-203
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    • 2007
  • In the present work, surface wetting effect on spread-splash regime and transition criterion of the water and ethanol droplets impacting an unheated dry wall has been experimentally investigated. The droplet was directed on a polished STS plate and a glass slide, and the impinging behavior was visualized and recorded using a CCD camera. Droplet diameter and velocity approaching the wall were measured as well. The critical Sommerfeld number representing the spread-splash boundary for the ethanol droplet impinging on the substrates turned out to be smaller compared to that for the water droplet impinging on the substrates with the surface roughness condition remained unchanged. The shift of the transition boundary is considered to be due to the effect of the surface wettability represented by static contact angle and surface tension of droplet.

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The Analysis on the Activation Procedure of Polymer Electrolyte Fuel Cells

  • Jang, Jong-Mun;Park, Gu-Gon;Sohn, Young-Jun;Yim, Sung-Dae;Kim, Chang-Soo;Yang, Tae-Hyun
    • Journal of Electrochemical Science and Technology
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    • 제2권3호
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    • pp.131-135
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    • 2011
  • It is, in general, believed that during the activation process, the proton conductivity increases due to wetting effect and the electrochemical resistance reduction, resulting in an increase in the fuel cell performance with time. However, until now, very scant information is available on the understanding of activation processes. In this study, dominant variables that effect on the performance increase of membrane electrode assemblies (MEAs) during the activation process were investigated. Wetting, pore restructuring and active metal utilization were analyzed systematically. Unexpectedly, the changes for both ohmic and reaction resistance characterized by the electrochemical impedance spectroscopy (EIS) after initial wetting process were much smaller when considering the degree of cell performance increases. However, the EIS spectra represents that the pore opening of electrode turns into gas transportable structure more easily. The increase in the performance with activation cycles was also investigated in a view of active metals. Though the particle size was grown, the number of effective active sites might be exposed more. The impurity removal and catalytic activity enhancement measured by cyclic voltammetry (CV) could be a strong evident. The results and analysis revealed that, not merely wetting of membrane but also restructuring of electrodeand catalytic activity increase are important factors for the fast and efficient activation of the polymer electrolyte fuel cells.

저강도 강우시 절토사면의 흡인력 분포와 안정성에 대한 투수계수의 효과 (Effect of Hydraulic Conductivity on Suction Profile and Stability of Cut-Slope during Low Intensity Rainfall)

  • 마무드 칼리드;김진만
    • 한국지반공학회논문집
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    • 제28권6호
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    • pp.63-70
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    • 2012
  • 저강도 강우상태에서 투수계수가 일반적인 절토사면의 흡인력 분포와 안정성에 어떤 영향을 주는지를 평가하였다. 지하수면 위의 불포화 지층의 초기 흡인력을 15 kPa로 가정하였다. 강우 지속시간 증가에 따른 절토사면의 안정성을 평가하기 위해 유한요소법과 한계평형법을 사용하였다. 유한요소 침투해석 결과, 저강도 강우상태에서는 불포화 지층이 계속해서 불포화 상태로 유지되는 현상을 보였다. 또한, 침윤선(wetting front)이 불포화 지층에 남아있는 경우에는 사면의 안정성에 사실상 변화가 없었으나, 침윤선(wetting front)이 지하수면에 도달하는 경우에는 지하수면이 높아짐에 따라 사면안정성이 크게 저하되었다.