• Title/Summary/Keyword: wetting angle

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Fabrication of Stable Water/Oil Separation Filter Using Effect of Surface Wettability (표면 젖음성을 이용한 물/오일 분리막 제작)

  • Kim, Dohyeong;An, Taechang
    • Journal of Sensor Science and Technology
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    • v.25 no.3
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    • pp.213-217
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    • 2016
  • The superhydrophobic and superoleophobic meshes surfaces have been used in various applications such as self-cleaning, anti-icing, gas exchange, oil-water separation, sound-wave penetrable anti-wetting structures, etc. In particular, there are many studies for oil-water separation with environmental issues. Because of high pressure and dynamic environment, oil-water separation filters must have stable surface properties as super-hydrophobicity and superoleophobicity. The oleophobicity of surface depends on the surface chemistry and roughness of the surface. The roughness of oleophobic surface enhances its static contact angle and stability. The multi-scale hierarchical structure provides a stable superhydrophobic state by maintaining a Cassie state. In this research, we fabricated a superoleophobic mesh with a multi-scale hierarchical structure to increase the pressure resistance and adjusted a size of the mesh hole.

Joining Behavior of Ceramics to Metal by Using Lead-bismate Heavy Metal Glass Frit (중금속 창연산화납계 저온유리 분말을 이용한 세라믹스/금속의 접합거동)

  • Choi, Jin Sam
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.312-316
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    • 2014
  • The joining behavior of forsterite ceramics to SUS304 alloy using $8PbO-78Bi_2O_3-8B_2O_3-4ZnO-2SiO_2$ (wt%) system glass frit was investigated. The contact angle was smaller than $90^{\circ}$ at a temperature of $460^{\circ}C$. Redox reaction at the interface between forsterite and SUS304 was found to appear when the electrons in the metal part moved toward the glass part and the oxygen ions in glass moved to the metal side. The decrease of the surface tension due to the PbO solubility on the forsterite side contributed to the better wetting behavior at low temperature.

Effects of Substrate and Surface Energy on Ink-jet Printing

  • Lee, Jin-Ho;Kim, Hong-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1457-1458
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    • 2009
  • The fundamental parameters controlling ink-jet printing liquids are the viscosity and surface energy. The wetting contact angle determines the spread of a liquid drop on the surface and depends on the relative surface energy. The characteristics of silver ink-jet printing were studied with control of surface energy and head temperature. Polyethylene terephthalate(PET) film and Si-wafer(ptype) were used as substrates and atmospheric plasma was treated to control the surface energy. With silver ink, the hydrophilic surface treatment could reduce the radius of droplets due to the hydrophobic nature of silver ink.

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Roll-to-Roll (R2R) Fabrication of Micro Pillar Array for Biomimetic Functionalization of Surface

  • Jeon, Deok-Jin;Lee, Jun-Young;Yeo, Jong-Souk
    • Applied Science and Convergence Technology
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    • v.23 no.1
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    • pp.54-59
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    • 2014
  • The roll-to-roll (R2R) fabrication method to make micro-scale pillar arrays for biomimetic functionalization of surfaces is presented. Inspired by the micro-structure of plants in nature, a surface with a synthetic micro-scale pillar array is fabricated via maskless photolithography. After the surface is SAM (self-assembled monolayer) coated with trichlorosilane in a vacuum desiccator, it displays a hydrophobic property even in R2R replicas of original substrate, whose properties are further characterized using various pitches and diameters. In order to perform a comparison between the original micro-pattern and its replicas, surface morphology was analyzed using scanning electron microscopy and wetting characteristics were measured via a contact angle measurement tool with a $10{\mu}L$ water droplet. Efficient roll-to-roll imprinting for a biomimetic functionalized surface has the potential for use in many fields ranging from water repelling and self-cleaning to microfluidic chips.

Microstructural Changes of $SiO_2-Si$ During Liquid-Phase Sintering (액상소결단계에서 $SiO_2-Si$의 미세조직 변화)

  • 강대갑;정충환
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.443-447
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    • 1994
  • Compacts of mixed SiO2-Si powder were liquid phase sintered at 145$0^{\circ}C$ for up to 60 min in a hydrogen atmosphere. In contrast to the conventional microstructures of liquid phase sintered materials, the specimens showed that the solid phase of SiO2 formed a matrix while the liquid phase of Si was the dispersed in the solid matrix. The dispersion of liquid Si pockets was attributed to the high wetting angle of liquid Si on solid SiO2. Because of relatively high solubility of SiO2 in liquid Si at 145$0^{\circ}C$, SiO2 particles accommodated their shape via a solution-reprecipitation process. The liquid Si pockets grew by coalescing with their neighbour pockets. In the latter stage of the sintering, plate-shape grains appeared in the liquid Si pockets. The grains were SiO2 phase precipitated from the liquid Si which was oversaturated with oxygen during cooling to room temperature. By the formation and subsequent removal of the gaseous SiO phase due to the reaction between SiO2 and Si, the specimens became porous.

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Microstructure Observation of the Grain Boundary Phases in ATF UO2 Pellet with Fission Gas Capture-ability (핵분열 기체 포획 기능을 갖는 사고저항성 UO2 펠렛에서 형성되는 입계상의 미세구조 관찰)

  • Jeon, Sang-Chae;Kim, Dong-Joo;Kim, Dong Seok;Kim, Keon Sik;Kim, Jong Hun
    • Journal of Powder Materials
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    • v.27 no.2
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    • pp.119-125
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    • 2020
  • One of the promising candidates for accident-tolerant fuel (ATF), a ceramic microcell fuel, which can be distinguished by an unusual cell-like microstructure (UO2 grain cell surrounded by a doped oxide cell wall), is being developed. This study deals with the microstructural observation of the constituent phases and the wetting behaviors of the cell wall materials in three kinds of ceramic microcell UO2 pellets: Si-Ti-O (STO), Si-Cr-O (SCO), and Al-Si-Ti-O (ASTO). The chemical and physical states of the cell wall materials are estimated by HSC Chemistry and confirmed by experiment to be mixtures of Si-O and Ti-O for the STO; Si-O and Cr-O for SCO; and Si-O, Ti-O, and Al-Si-O for the ASTO. From their morphology at triple junctions, UO2 grains appear to be wet by the Si-O or Al-Si-O rather than other oxides, providing a benefit on the capture-ability of the ceramic microcell cell wall. The wetting behavior can be explained by the relationships between the interface energy and the contact angle.

Evaluation of Material Properties of Acetylated Medium Density Fiberboard (MDF) (아세틸화 처리 중밀도 섬유판(MDF)의 재질 평가)

  • LEE, Jong Shin;KIM, Soung Joon
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.3
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    • pp.393-404
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    • 2020
  • This study examined the material properties of MDF manufactured using acetylated pinus radiata fibers against moisture and compared the properties with the fiberboard quality standards of KS F 3200. Since acetylated MDF shows very low moisture content, water absorption and thickness swelling than the quality standards, it is expected to have an excellent dimensional stability. The bending strength in wetting condition of the acetylated MDF reached approximately 70% of the bending strength in dry condition, making it suitable for the quality standards. The internal bond of the acetylated MDF in the wetting condition was higher than the minimum internal bond of the quality standards in the dry condition, showing a good water resistance. Since the water droplet contact angle of the acetylated MDF is larger than that of untreated MDF, it is determined that it contributes in improving the water resistance due to the low wettability.

Pressureless Infiltration Processing of B4C/Al Composite by Surface Modification (표면 개질에 의한 상압에서의 B4C/Al복합체 제조 방법)

  • 임경란;강덕일;김창삼
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.128-131
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    • 2003
  • Formation of$B_4C/Al$composite by pressureless infiltration was investigated by lowering wetting angle via surface modification of $B_4C$powder with alumina precursor. Surface modification was confirmed by zeta potential analysis. The$B_4C/Al$composite was prepared by placing an Al 6061 disk on the$B_4C$preform and heating at $1030{\circ}C$/20 min under a flowing argon, but no infiltration took place for a bare $B_4C$ preform even at$1250{\circ}C$/30 min. Analysis of XRD and SEM showed the $Al_3BC$phase besides$B_4C$and Al, but no trace of deteriorative$A1_4C_3$.

Wetting Characteristics of Water Droplet on the Solid Surfaces with Variable Pillar-Type Nanostructures (다양한 기둥 타입을 가지는 나노 구조물 고체 표면에서의 물 액적 젖음 특성)

  • Yoo, Min Jung;Kwon, Tae Woo;Ha, Man Yeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.10
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    • pp.659-666
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    • 2016
  • A numerical study, using the molecular dynamics simulation method, was carried out to investigate the wetting characteristics of water droplets on a solid square pillar surface with variable periodic edge length patterns at the nanoscale. In this study, the pillar plane was supposed to be rectangular or square shaped. In addition, the surface area was increased while the shape of the pillar plane was kept fixed. In the case of the square pillar, the edge length increased from $4.24{\AA}$ to $12.72{\AA}$. Also, the rectangular pillar had two types of length edges. In this case, one edge length was fixed at $8.48{\AA}$ and the other edge length was increased from $4.24{\AA}$ to $12.72{\AA}$. Through these length changes, the hydrophobicity and hydrophilicity of a water droplet on the variable pillar surfaces were analyzed.

POLYMER SURFACE MODIFICATION WITH PLASMA SOURCE ION IMPLANTATION TECHNIQUE

  • Han, Seung-Hee;Lee, Yeon-Hee;Lee, Jung-Hye;Yoon, Jung-Hyeon;Kim, Hai-Dong;Kim, Gon-ho;Kim, GunWoo
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.345-349
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    • 1996
  • The wetting property of polymer surfaces is very important for practical applications. Plasma source ion implantation technique was used to improve the wetting properties of polymer surfaces. Poly(ethylene terephtalate) and other polymer sheets were mounted on the target stage and an RF plasma was generated by means of an antenna located inside the vacuum chamber. High voltage pulses of up to -10kV, 10 $\mu$sec, and up to 1 kHz were applied to the stage. The samples were implanted for 5 minutes with using Ar, $N_2,O_2,CH_4,CF_4$ and their mixture as source gases. A contact angle meter was used to measure the water contact angles of the implanted samples and of the samples stored in ambient conditions after implantation. The modified surfaces were analysed with Time-Of-Flight Mass Spectrometer (TOF-SIMS) and Auger Electron Spectroscopy (AES). The oxygen-implanted samples showed extremely low water contact angles of $3^{\circ}C$ compared to $79^{\circ}C$ of unimplanted ones. Furthermore, the modified surfaces were relatively stable with respect to aging in ambient conditions, which is one of the major concerns of the other surface treatment techniques. From TOF-SIMS analysis it was found that oxygen-containing functional groups had been formed on the implanted surfaces. On the other hand, the $CF_4$-implanted samples turned out to be more hydro-phobic than unimplanted ones, giving water contact angles exceeding $100^{\circ}C$ . The experiment showed that plasma source ion implantation is a very promising technique for polymer surface modification especially for large area treatment.

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