• Journal of the Korean GEO-environmental Society
• /
• v.2 no.1
• /
• pp.103-114
• /
• 2001

Sorption studies were conducted to determine if slow sorption fraction is observed in recent1y deposited organic matter by studying wetland soils explicitly. Sorption characteristics of hydrophobic organic compounds (chlorobenzene and phenanthrene) in recently deposited freshwater marsh soils were determined using a batch sorption procedure. Relative indicators of organic matter age were assessed using several techniques including the ratio of elemental oxygen to carbon in the organic matter. Slow sorption characteristics for both surface marsh soil (top 0-2 cm, <5 years old) and deeper marsh soil (below 10-cm, >20 years old) were compared against relatively older PPI (Petro Processors, Inc. Superfund site) and BM (Bayou Manchac) soils to investigate whether soil age can cause differences in sorption of organic compounds in wetland soils. Increases in sorption non-linearity of slow sorption model parameters (increase in KF and decrease in N) explain the existence of slow sorption fraction. The results of slow sorption model indicates the presence of a sizable slow sorption fraction; 25.4 - 26.3% (chlorobenzene) and 1.4 - 1.9% (phenanthrene) of the sorbed mass in wetland soils and 40.0 - 55.93% (chlorobenzene) and 2.9 - 3.19% (phenanthrene) of the sorbed mass in PPI and BM soils, respectively. The slow sorption fraction increased in the order of surface < deeper < PPI < BM soil indicating that size of the slow sorption fraction increases with soil organic matter age.

• Korean Journal of Ecology and Environment
• /
• v.36 no.3 s.104
• /
• pp.295-303
• /
• 2003

Sorption kinetics of hydrophobic organic compounds (chlorobenzene and phenanthrene) in natural wetland soils was investigated using laboratory batch adsorbers. One -site mass transfer model (OSMTM) and two compartment first-order kinetic model (TCFOKM) were used to analyze sorption kinetics. Analysis of OSMTM reveals that apparent sorption equilibria were obtained within 10 to 75 hours for chlorobenzene and 2 hours for phenanthrene, respectively. For chlorobenzene, the sorption equilibrium time for surface soil was longer than that of deeper soil presumably due to physico-chemical differences between the soils. For phenanthrene, however, no difference in sorption equilibrium time was observed between the soils. As expected from the number of model parameters involved, the three-parameter TCFOKM was better than the two-parameter OSMTM in describing sorption kinetics, The fraction of fast sorption ($f_1$) and the first-order sorption rate constants for fast ($k_1$)and slow ($k_2$) compartments were determined by fitting experimental data to the TCFOKM. The results of TCFOKM analysis indicate that the sorption rate constant in the fast compartment($k_1$) was much greater than that of slow fraction($k_2$) . The fraction of the fast sorption ($f_1$) and the sorption rate constant in the fast compartment($k_1$) were increasing in the order of increasing $k_{ow}$, phenanthrene > chlorobenzene. The first-order sorption rate constants in the fast ($k_1$) and slow ($k_2$) compartments were found to vary from $10^{-0.1}\;to\;-10^{1.0}$ and from $10^{-4}\;to-10^{-2}$, respectively.

• Environmental Engineering Research
• /
• v.13 no.4
• /
• pp.165-168
• /
• 2008

Measurements of phosphatase activity in peatlands are made difficult by the low levels of activity and the characteristically high concentrations of dissolved organic matter within the sediments. These materials may cause high background absorbances in colorimetric assays, and quenching interference in fluorimetric assays. This review describes the development of a new approach which allows such problems to be overcome by using HPLC to separate the interferences from the products of enzymic hydrolysis. This approach is applicable to various environmental samples such as peat, wetland sediment, and sludge which may contain a large amount of interfering organic matters.

• Journal of the Korean Society of Environmental Restoration Technology
• /
• v.13 no.3
• /
• pp.46-62
• /
• 2010

This study was conducted to understand the water and soil properties to propose the promotion of vegetation environment at farm pond depression. We selected 8 palustrine wetlands from agricultural area after consideration of human interference, surround land use, and size of area. Water quality analysis showed that the average SS, T-N, T-P were over the limit of agricultural water quality standard level at some sites. The cause for deterioration of water quality is supposed by the long-term stagnation of water in palustrine wetland. The recommended measures to improve water quality are as follows; improving water circulation by connecting with nearby natural water, preventing oxygen depletion by dredging deposit, lowering down T-N and T-P by removing autumn plants, preventing inflow of phosphorus in fertilizer ingredients which is the main cause for high T-P. The soil contamination of the surveyed area was about the same level of average heavy metal contents in soils from 2,010 paddy fields in Korea, which was much lower than soil contamination standards. As for soil texture, sand content was 40~90% and clay content was less than 20%. The content of silt and clay in soil from community of floating-leaved:submerged hydrophytes and community of emergent hydrophytes was higher that of soil from community of hygrophytes, and the content of sand in soil from community of hygrophytes was 10% higher than underwater soil. In terms of bulk density, the average was 0.24~0.96g/$cm^3$, which was quite low, because of high content of peat and organic matter in soil of the surveyed area. As for the average content of organic matter, community of floating-leaved:submerged hydrophytes was 18.25g/kg, community of emergent hydrophytes was 16.88g/kg, and community of hydrophytes was 25.63g/kg. The range of content of T-N in soil of community of floating-leaved；submerged hydrophytes was 0.022~0.307%, and that of community of emergent hydrophytes was 0.029~0.681% and that of community of hydrophytes was 0.088~0.325%. Apart from three sites in the surveyed area, most parts were over the standards or below the standard. After this study, we will conduct and discuss the relationship between vegetation characteristics and environments, which will be used of the best practical management and restoration of wetland.