• 제목/요약/키워드: wax

검색결과 855건 처리시간 0.028초

왁스(wax) 함침형 나일론 6의 합성과 그의 기계적 성질에 관한 연구 (A Study on Synthesis and Mechanical Properties of Wax-Impregnated Nylon 6)

  • 강석춘;정대원
    • 한국자동차공학회논문집
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    • 제7권7호
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    • pp.268-277
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    • 1999
  • In order to make an advanced dry-friction engineering material, wax-impregnated nylons were synthesized by anionic polymerization of $\varepsilon$-caprolactam in the presence of apraffin wax. DNX-125S, which has lowest melting point among four different kinds of waxs investigated, showed excellent miscibiility with $\varepsilon$-carprolactam and no effect on the polymerization reaction. Five different kinds of wax-impregnated nylons from of DNW-125S content 0% to 8% were synthesized and tested. Among the samples, wax-free nylon has the highest yield and tensile strength and hardness, while the specimen with2% wax has the largest elongationi and energy absorption to break. The wax-impregnated nylon with a wax content 6% showdd the smallest friction coefficient under slow sliding speed and low load. Bus as the sliding speeds were increased to high, thespcieimen with 8% wax has better friction property.

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CONTROL OF HARDNESS OF OIL-WAX GELS BY A NOVEL BRANCHED WAX AND APPLICATION TO LIPSTICKS

  • Yoshida, K.;Shibata, M.;Ito, Y.;Nakamura, G.;Hosokawa, H.
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book I
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    • pp.469-479
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    • 2003
  • A novel branched wax has been developed for the control of the hardness of oil-wax gels. Using this wax, glossier application and smoother texture but tough lipstick can be obtained. Oil-wax gels are oily solids composed of liquid and crystalline solid oils (waxes). They are widely used in various cosmetic products, especially lipsticks. The control of gel hardness is one of the most important techniques in improvement of the lipstick quality. Addition of small amounts of commercial branched paraffin wax (e.g. microcrystalline wax, b-PW) to n-paraffin wax (n-PW) has been commonly used to increase gel hardness. However, gel hardness is very sensitive to the quantity of b-PW and the gel obtained is not always hard enough for practical use. In this study we examined the relationship between the gel hardness and the properties of the wax crystal in the gel. We have found that, when b-PW is added to n-PW, the wax crystal size becomes smaller (hardening the gels) and its crystallinity is decreased (softening the gels) simultaneously. Considering this result, we have developed a novel branched wax, Bis(polyethylenyl)- tetramethyldisiloxane (named ESE). ESE molecules are composed of a central tetramethyldisiloxane unit (branch unit) with polyethylene units at both ends. The central unit may suppress crystal growth while the ends are expected to prevent a decrease in wax crystallinity during crystallization. When ESE is added to n-PW, the wax crystal obtained becomes smaller without decreasing in crystallinity; consequently, the gel hardness is dramatically increased. By using ESE, the total amount of wax in a lipstick can be decreased by 30% without spoiling the stick toughness, thereby achieving glossy application and smooth texture.

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Inlay wax의 열팽창에 관한 연구 (A study on Thermal expansion of Inlay waxes)

  • 남상용;곽동주;차성수
    • 대한치과기공학회지
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    • 제30권2호
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    • pp.17-22
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    • 2008
  • The purpose of this study was to observe the thermal expansion of the inlay waxes at temperature. Inlay pattern wax shows not only a high coefficient of expansion but also a tendency to warp or distort when allowed to stand unrestrained. The thermal expansion of inlay waxes was tested according to the treatment conditions for 10 minutes at $40^{\circ}C$ The thermal expansion of inlay waxes at various temperatures was measured with an electro dial gauge. The results were as fellows: 1. It is shown that the rate of thermal expansion of wax A is 0.2%, wax B is 0.29%, wax C is 0.38%, and wax D is 0.22% at $40^{\circ}C$ 2. It is shown that the coefficient of thermal expansion of wax A is $106{\times}10^{-6}/^{\circ}C$, wax B is $152{\times}10^{-6}/^{\circ}C$, wax C is $199{\times}10^{-6}/^{\circ}C$, and wax D is $116{\times}10^{-6}/^{\circ}C$ at $40^{\circ}C$ 3. The thermal expansion of the inlay waxes at $40^{\circ}C$ was shown to increase in the order of wax C, B, D, A.

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조선왕조실록 밀랍본 복원기술연구(제1보) - 재현밀랍지의 열화거동평가 - (The Study of Restoration Technique of Wax-treated Volume for the Annals of the Joseon Dynasty(I) - Evaluation of degradation behavior of reproduced waxy paper -)

  • 정선화;정소영;서진호;이혜윤
    • 펄프종이기술
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    • 제39권1호
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    • pp.56-63
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    • 2007
  • The purpose of this research was to identify causes of damage of wax-treated volume of "The Annals of the Joseon Dynasty". As one of the efficient restoration methods, analyses of damaged state of reproduced wax-treated paper through tests of degradation of wax-treated paper under an artificial setting were performed, and in particular, differences between lightness and acidity were observed. On the whole, it was confirmed that yellow wax-treated papers were more stable than white wax-treated papers against artificial aging treatment, which is thought to be because the white wax-treated paper was more affected by a variety of substances interacting with paper than yellow wax-treated paper under artificially aged conditions, which were added in the course of refinement and processing operation such as decolorization and deodorization.

PE Wax를 첨가한 아스팔트 바인더의 물리적 특성 (Evaluation of the Effect of PE Wax on Asphalt Binder Properties)

  • 김부일;전성일;이문섭;조윤호
    • 한국도로학회논문집
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    • 제8권4호
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    • pp.101-113
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    • 2006
  • 일반적으로 아스팔트 개질재의 경우 아스팔트 바인더의 고온 점성을 증가시킬 뿐만 아니라 믹싱 및 포설온도에서의 점도 또한 증가시켜 높은 생산온도 및 시공온도를 요구하게 된다. 이와 달리 Wax의 경우 아스팔트 바인더의 강성을 증가시키기도 하지만 일정 온도가 넘으면 물처럼 유동성을 확보해 믹싱 및 포설온도에서의 점도를 낮추어 작업성을 높이는 효과가 있다. 본 연구에서는 실내실험을 통해 PE Wax가 아스팔트 바인더에 첨가되었을 경우 그 특성을 분석하였다. 이를 위해 SBS, 폐타이어 고무분말 개질 아스팔트 바인더와 비교 분석하였다. 또한 Wax가 기존 개질재인 SBS, 폐타이어 고무분말과 함께 사용되었을 경우 그 효과를 분석하였다. 실험 결과, Wax type I은 내유동성 강화에 큰 효과가 있으며 작업성 개선에 약간의 효과가 있는 것으로 나타났다. Wax type II는 아스팔트 바인더의 작업성 개선에 크게 기여하고, 상온에서 부드러운 특성으로 균열에 대한 저항성을 증진시키는 것으로 나타났다.

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들기름 기반 야외 금속 조형물 보존용 혼합 Wax의 개발 및 적용성에 관한 연구: 철제 조형물 중심으로 (A Study on the Development and Application of Perilla Oil Based Compound Wax Agent for Preserving Outdoor Metal Sculpture: A Case Study on Iron Sculptures)

  • 오승준;위광철
    • 보존과학회지
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    • 제33권2호
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    • pp.121-130
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    • 2017
  • 현재 야외 철제 조형물 보존용 코팅제로 사용되고 있는 wax는 장점도 있지만 낮은 내구성 및 안정성 등의 단점으로 인한 사용상의 문제점이 노출되고 있다. 손상원인으로는 대기오염에 의한 대기가스와 산성비, 공기 중의 수분, 미세먼지, 황사 등에 의해 wax가 노화되어 코팅력이 저하되고, 이로 인해 보존처리 후 짧은 시간 내에 재 부식이 발생한다. 또한 wax의 노화로 색상변화 및 광택변화가 일어나 표면 이질감을 주기도 한다. 이러한 문제점들은 장기간 지속되어 왔으며 이를 개선하기 위한 재료의 개발이 필요한 실정이다. 이에 본 연구에서는 기존에 사용되어지고 있는 wax 코팅제들을 분석하여 각각의 특성과 용도별로 부족한 점들을 파악하여 보다 개선된 wax 코팅제를 개발하였으며, 야외 폭로실험과 인공 산성비 실험을 통해 환경 변화에 따른 표면 코팅 변화양상을 확인해본 결과 기존 재료들 보다 야외 폭로실험결과 약 4배, 인공 산성비 실험 결과 약 1.5배 이상의 우수한 부식방지 및 차단 효과를 나타내었다. 또한 색도 및 광택도, 접촉각, 박막두께 등의 물성 측정을 통해 기존에 사용되어온 wax보다 박막두께는 약 1.3 ~ 1.8배 두껍지만 고른 피막을 형성해 외부 환경으로 부터의 차단성 및 내구성이 우수하고 색도 및 광택도도 기존의 재료와 유사한 물성을 보여주어 기존에 사용되어온 wax 코팅제를 대체할 수 있는 재료로 판단된다.

왁스를 함유한 자외선 경화형 코팅제의 경화 및 표면 물성 (Curing and Surface Properties of UV-curable Coating Containing Wax)

  • 한아람;김종구;홍진후;김현경
    • 접착 및 계면
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    • 제13권1호
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    • pp.38-44
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    • 2012
  • 본 연구는 왁스를 함유한 자외선 경화형 코팅제의 경화 물성, 표면 모폴로지, 코팅 표면 물성을 Photo-DSC, SEM, 진자경도, 연필경도 및 광택도를 이용하여 평가하였으며, 특히 왁스의 종류(파라핀 왁스, PE 왁스)에 따른 제반 코팅 물성을 조사하였다. 그 결과 왁스의 종류는 코팅 도막의 광택도와 표면 경도에 큰 영향을 주는 것으로 나타났으며, 유동성이 우수하며 부드러운 고체상의 파라핀 왁스를 사용한 경우에는 저광택의 소광성을 보여주었다. Photo-DSC의 ${\Delta}H$는 왁스를 함유한 코팅 시스템이 함유하지 않은 시스템 보다 높게 나타났는데, 특히 파라핀 왁스를 사용한 경우의 ${\Delta}H$가 PE 왁스를 사용한 경우에 비해 높게 나타났다. 이는 파라핀 왁스가 PE 왁스에 비해 더 효과적으로 공기 중의 산소를 차단하여 경화성이 높아진 것임을 의미한다. 또한 왁스의 산소 차단 효과는 경화속도와 밀접한 관계가 있는 것으로 확인되었다.

Wax-up으로 조각한 치관과 CAD로 설계한 치관의 형태 비교 (Shape comparison of Wax-up carved crown and CAD-designed crown)

  • 김갑진
    • 대한치과기공학회지
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    • 제39권2호
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    • pp.93-99
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    • 2017
  • Purpose: With the development of digital dental technology, we are manufacturing prosthetic crown in various ways. However, the wax-up method that makes existing prosthetic crown is also used steadily. Thus, we will compare the shape of the crown designed with wax-up and the crown designed with CAD. Methods: Sculpt the crown with wax-up on the model to 10 dental technicians. The same model was used to design the crown CAD. Measure the size of the sculpted crown. The shapes were compared in three dimensions. Results: As a result, we could observe a difference in size and shape in crown designed with wax - up crown and crown. Conclusion: These results suggest that there are differences according to the method of carving crown and the method of processing.

왁스첨가(添加) 순서(順序), 첨가량(添加量), 종류(種類)가 Isocyanate 접착(接着) PB의 성질(性質)에 미치는 영향(影響) (Effect of the Sequence of Wax Addition, Wax Level and Type on Properties of Isocyanate-Bonded Particleboard)

  • 권진헌
    • Journal of the Korean Wood Science and Technology
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    • 제23권2호
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    • pp.70-76
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    • 1995
  • 본 연구는 왁스첨가순서(添加順序), 첨가량(添加量), 왁스종류(種類)가 Isocyanate 접착(接着) PB의 성질(性質)과 내수성(耐水性)에 미치는 영향(影響)을 구명(究明)하기 위해서 실시(實施)되었다. 왁스첨가순서(添加順序)는 PB의 기계적(機械的) 성질(性質) 및 내수성(耐水性)에 유의적(有意的)인 영향(影響)을 미치지는 않았다. 왁스에멀젼 첨가량(添加量)을 증가(增加)시킴으로써 접착력(接着力) 및 휨강도(强度) 내수(耐水) MOR은 감소(減少)되었지만 상태(常態) MOR 및 MOE는 감소(減少)되지 않았다. 상태접착력(常態接着力), 상태(常態) 및 내수(耐水) MOR과 MOE는 솔리드왁스량(量)을 증가(增加)시킴으로써 감소(減少)되지 않았지만 내수접착력(耐水接着力)은 감소(減少)되었다. 1% 및 1.5% 왁스량(量)을 첨가(添加)한 보드는 0.5% 왁스를 첨가(添加)한 보드와 비교(比較)해 보았을 때 내수성(耐水性)이 증가(增加)되지는 않았다. 솔리드왁스를 첨가(添加)한 보드의 접착력(接着力)은 왁스에멀젼을 첨가(添加)한 보드보다 더 좋은 결과(結果)를 나타내었다. 휨강도(强度)의 MOR 및 MOE, 내수성(耐水性)은 솔리드왁스와 왁스에멀젼간에 유의적(有意的)인 차이(差異)를 보이지는 않았다.

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OBSERVATION OF THE SWEATING IN LIPSTICK BY SCANNING ELECTION MICROSCOPY

  • Seo, Su-Youn;Lee, In-Sook;Sin, Hyeon-Jong;Choi, Kyu-Yeol;Kang, She-Hoon;Ahn, Ho-Jeong
    • 대한화장품학회지
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    • 제22권2호
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    • pp.182-192
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    • 1996
  • In this study, the relationship between wax matrix in lipstick and sweating was investigated by observing the change of size and shape of wax matrix with sweating by Scanning Electron Microscopy (SEM). For observation by SEM, a lipstick sample was frozen in liquid nitrogen, then the oil in the lipstick was extracted out in cold isopropanol($-70^{\circ}C$) for 1-3days. After isopropanol was evaporated, the sample was sputtered with gold, and examined by SEM. When examined the sweated sample by SEM, the change of wax matrix underneath the surface from fine, uniform structure to coarse, nonuniform structure was observed, which was resulted from the caking of surrounding wax matrix. That is, the oil underneath the surface was migrated to the surface of lipstick with sweating, consequently the wax matrix at that region was rearranged into the coarse matrix. In case of flamed lipstick, sweating was delayed and the wax matrix was much coarser than that of unflamed one. Its larger wax matrix at surface region was good for including oil. The effect of molding temperature on sweating was also studied. As the molding temperature was increased, sweating was greatly reduced and the size of wax matrix was increased. It was also found that sweating was influenced with the compatinility of wax and oil. A formula consisting of wax and oil which have good compatibility has a tendency of reduced sweating and increased size of wax matrix. When pigment was added to wax and oil. It was also found that sweating was influenced with the passage of time by observing a thick membrane of wax on surface of lipstick after a month from molding. In case of some lipsticks, the size of wax matrix was altered to bigger or smaller. In conclusion, the structure of wax matrix at the surface region of lipstick was changed with the process of foaming, molding temperature, compatibility of wax and oil, addition of pigment, and the passage of time. In most cases, as the size of wax matrix was increased, sweating was reduced and delayed.

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