• Title/Summary/Keyword: water-soluble dye

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폐 선박의 FRP를 재활용 과정에서 용이한 기계적 조작을 위한 화학적 처리 방법에 관한 연구 (A Study on the Chemical Treatments Suitable for the Simple Mechanical Manipulation During the Recycling Process of FRP Waste from Ships)

  • 이승희;김용섭;윤구영
    • 한국해양환경ㆍ에너지학회지
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    • 제12권1호
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    • pp.55-59
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    • 2009
  • 중소형 폐 선박으로부터 생성되는 FRP를 재활용하기 위한 방법으로 층상으로 배열된 로빙층과 매트층을 분리하는 것은 에너지 면에서나 환경적인 면에서 많은 장점을 가지고 있다. 비록 로빙층과 매트층은 그 비율은 다르나 모두 수지와 유리를 포함한다는 유사성과 로빙층은 매트층에 비해 얇은 두께로 존재한다는 이유로 인해 로빙층을 매트층과 분리할 때 기계가 자동적으로 충간의 차이를 인식하기는 어렵다. 본 연구에서는 유리의 구성비가 다른 두 층의 화학적 성질의 차를 이용하여 광학적으로 층간 인식이 가능한 방법을 모색하였다. FRP에 대해 (1) FRP의 층 사이에 존재하는 수지를 녹이는 진한 황산, 또는 (2) 유리를 녹이는 염기성 용액(KOH의 메탄올과 아이소프로판올 용액), (3) 유리의 $SiO_2$와 반응하는 플루오르산(HF)용액, (4) HF 용액으로 처리한 후 수용성 염료를 도포한 경우, 각각 두 층간의 차별화가 일어났다. 이 결과를 이용하여 폐 FRP의 분리 공정이 단순화될 수 있을 것이다.

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Ferric Oxinate를 標職物質로 사용한 人工汚染布의 洗滌特性 (Characteristics of Artificially Soiled Fabrics Containing Ferric Oxinate as a Tracer)

  • Ahn, Kyung Cho;Kim, Sung Reon
    • 한국염색가공학회지
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    • 제8권1호
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    • pp.83-89
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    • 1996
  • Carbon black has been used as a particulate soil to prepare artificial soiled fabrics for detergent study but it has two major defects. The one is the difficulty of quantitative analysis of carbon black for evaluate the detergency, the other is that there is no reliable correlation between the removal of carbon black and oily soil which is the major component of natural soil. In this study ferric oxinate was used as a particulate soil since it is in black color and can be soiled on fabric by suspension in water or by solution in chloroform and it is easily analysed quantitatively by extracting it from soiled fabric with chloroform to get correct value of soil removal. The characteristics of soil removal of ferric oxinate were compared with that of carbon black and Sudan black, an oil soluble dye, which had been proved that it's detergency correlated with that of oily soil The soil removal of ferric oxinate and Sudan black estimated from quantitative analysis and from K/S value were in good agreement whereas the result calculated by simple reflectance was consistently low. The soil removal of ferric oxinate was exceeded from that of carbon black without regard to surfactants, Triton and Las, but the effect of washing conditions such as temperature and washing time on soil removal of both soils with different suffactants showed no considerable difference. Though the soil removal of Sudan black was little effected by the conditions, the soil removal in Triton exceeded considerably that of in Las, which is the characteristic of oily soil. Thus the soil removal of Sudan black was in good agreement with ferric oxinate in Triton, a non-ionic surfactant, and with carbon black in Las, an artionic surfactant. We concluded that ferric oxinate is a more realistic model particulate soil for artificial soiled cotton fabric washed with non-ionic surfactant than carbon black.

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발아 녹두 추출물의 항염증 효능 및 염모제 응용 (Anti-Inflammatory Effect of Germinated Mung Bean and Hairdye Applications)

  • 김은석;정노희
    • 한국응용과학기술학회지
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    • 제31권1호
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    • pp.23-30
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    • 2014
  • 본 연구에서는 발아된 녹두 추출물의 항염증 효능 및 화장품 응용에 관한 연구이다. 동일 농도인 $250{\mu}g/m{\ell}$에서 산화질소 생성 억제 비교시 발아 녹두 추출물이 가장 높은 억제 효과를 보였다. 또한 수용성 용매에 따른 결과를 비교하였을 때 1,3-부틸렌글라이콜을 사용하고, 5일간 발아시킨 녹두를 추출한 것이 가장 높은 산화질소 억제 효과를 나타내었다. 염증 반응이 많이 일어나는 염모제에 발아 녹두 추출물을 적용한 결과 발아 녹두 추출물을 포함한 염모제가 포함하지 않은 것 보다 높은 산화질소 억제 효과를 보였다. 따라서 발아 녹두 추출물은 화장품에 자극 완화제와 항염증 소재로 응용이 기대된다.

폐 FRP선박의 재활용공정에서 용이한 면포추출공정을 위한 화학적 처리 방법에 관한 연구 (A Study For The Simple Method In Dividing The Layers of Fiber-reinforced Plastic)

  • 이승희;김용섭;윤구영
    • 한국해양환경ㆍ에너지학회지
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    • 제13권1호
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    • pp.43-46
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    • 2010
  • 중소형 폐 선박으로부터 배출되는 FRP를 재활용하기 위한 방법으로 층상으로 배열된 로빙층과 매트층을 분리하는 것은 에너지 면에서나 환경적인 면에서 많은 장점을 가지고 있다. 비록 로빙층과 매트층은 모두 유리섬유로 이루어져있으나 수지함유량의 차이와 유리섬유의 조직형태의 차이로 인하여 재활용 용도는 매우 달라지고 있다. 그러나 로빙층은 매트층에 비해 얇은 두께로 존재한다는 이유로 인해 로빙층을 FRP에서 분리할 때 기계가 자동적으로 층간의 차이를 인식하기는 매우 어렵다. 따라서 이 추출과정에서 많은 로빙층의 손실과 공정의 난이도에 의한 처리시간 지연 등의 문제가 발생한다. 본 연구에서는 유리의 구성비가 다른 두 층의 화학적 성질의 차를 이용하여 광학적으로 층간 인식이 가능한 방법을 모색하였다. FRP에 대해 유리의 $SiO_2$와 반응하는 플루오르산(HF) 용액으로 처리한 후 수용성 염료를 도포한 경우 두 층간의 차별화가 확연하게 일어났다. 본 연구는 이 결과를 이용하여 폐 FRP의 면포분리 공정의 효율성을 극대화 할 수 있는 시스템을 개발 하였다.

수술중 시행한 척수 조영술의 유용성 (The Usefulness of Intraoperative Myelography during Spinal Surgery)

  • 윤성훈;이진석;장하성;이형진;양지호;이일우;강준기
    • Journal of Korean Neurosurgical Society
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    • 제30권sup2호
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    • pp.322-327
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    • 2001
  • Objectives : There are many kinds of method to evaluate neural decompression during operation. They are direct visual and manual inspection, intraoperative ultrasound, endoscope, intraoperative computed tomography and intraoperative myelography. We used intraoperative myelography to evaluate the proper decompression of neural elements during the decompressive surgery. Methods : We injected 10-20cc of nonionic water-soluble contrast materials through direct puncture site of exposed dura during operation or lower lumbar level or lumbar drain inserted preoperatively. 12 patients were included in this study. They were 7 patients of centrally herniated lumbar disc disease, 1 patient of multiple lumbar spinal stenosis, 2 patients of thoracic extradural tumor and 2 cervical fracture & dislocations. Results : 5 of 12 patients showed remained neural compression through intraoperative myelography, so they were operated further through other approach. Myelographic dye is heavier than CSF, so the dependent side of subarachnoid space was visualized only. In one case, CSF leakage through hemovac was detected, but it was treated only bed rest for 5 days after hemovac removal. Conclusion :Intraoperative myelography is an effective method to evaluate neural decompression during spinal surgery. This technique is easy and familiar to us, neurosurgeons.

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Protective Effects of Ursolic Acid on Osteoblastic Differentiation via Activation of IER3/Nrf2

  • Lee, Sang-im
    • 치위생과학회지
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    • 제19권3호
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    • pp.198-204
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    • 2019
  • Background: Oxidative stress is a known to be associated with in the pathogenesis of many inflammatory diseases, including periodontitis. Ursolic acid is a pentacyclic triterpenoid with has antimicrobial, antioxidative, and anticancer properties. However, the role of ursolic acid in the regulating of osteogenesis remains undetermined. This study was aimed to elucidate the crucial osteogenic effects of ursolic acid and its ability to inhibit oxidative stress by targeting the immediate early response 3 (IER3)/nuclear factor erythroid 2-related factor 2 (Nrf2) pathway. Methods: Cell proliferation was determined using water-soluble tetrazolium salt assay, cell differentiation was evaluated by alkaline phosphatase (ALP) activity, and formation of calcium nodules was detected using alizarin red S stain. Generation of reactive oxygen species (ROS) was determined using by DCFH-DA fluorescence dye in hydrogen peroxide ($H_2O_2$)-treated MG-63 cells. Expression levels of IER3, Nrf2, and heme oxygenase-1 (HO-1) were analyzed using western blot analysis. Results: Our results showed that ursolic acid up-regulated the proliferation of osteoblasts without any cytotoxic effects, and promoted ALP activity and mineralization. $H_2O_2$-induced ROS generation was found to be significantly inhibited on treatment with ursolic acid. Furthermore, in $H_2O_2$-treated cells, the expression of the early response genes: IER3, Nrf2, and Nrf2-related phase II enzyme (HO-1) was enhanced in the presence of ursolic acid. Conclusion: The key findings of the present study elucidate the protective effects of ursolic acid against oxidative stress conditions in osteoblasts via the IER3/Nrf2 pathway. Thus, ursolic acid may be developed as a preventative and therapeutic agent for mineral homeostasis and inflammatory diseases caused due to oxidative injury.

옻칠한지의 제조 및 특성 (The Characteristics of Hanji Prepared with Lacquer)

  • 조현진;이상극;노정관
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2007년도 춘계학술대회논문집
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    • pp.380-390
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    • 2007
  • The purpose of this study is to make a functional Hanji treated with an oriental lacquer which has various functionalities. The raw oriental lacquer produced in China was used in this study This lacquer was diluted with ethanol and terpene in different solvent ratios. The diluted lacquer in the solvents had two layers. The upper layer was solvent soluble and the lower contained precipitates. Hanji was treated with the solvent solubles and the mixture containing precipitates, and then properties of the Hanji were evaluated. The oriental lacquer consisted of 25.04% of water, 60% of urushiol, 3.13% of nitrogen-containing compounds, and 5.66% of gum. The pH of oriental lacquer was 5.3 and the viscosity was 1680 cP. The average weight, thickness, and density of Hanji treated with oriental lacquer tended to gradually decreased as the lower concentration of lacquer was used and as the solvent soluble was treated. Tensile strength of the treated Hanji decreased when the diluted lacquer was used and Hanji treated with terpene dilutes at the ratio of lacquer to solvent of 1:5 (v/v) showed higher tensile strength than ones treated with ethanol dilutes. The folding endurance decreased as the less concentrated lacquer was used and the highest value was obtained when 1:40 (v/v) of lacquer to solvent ratio in both ethanol and terpene mixture. Absorption ratio was higher in the Hanji treated with ethanol mixture, treated with the lacquer in higher concentration, and treated with ethanol mixture. Hanji treated with ethanol dilutes at 1:20 (v/v) and the lower ratio of lacquer to solvent showed a hydrophobic property. Amount of the bound dye materials tended to be decreasing as the concentration of lacquer becomes lower and it was higher in Hanji treated with ethanol mixture than with terpene mixture. Color of Hanji treated with the solvent diluted mixture was Y to YR-type, whereas that of Hanji treated with raw oriental lacquer was Y-type, terpene

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FRP선박의 일괄 재처리 방법의 개선 (Developing Advanced Total Recycling Method of FRP Boats)

  • 이승희;윤구영
    • 한국해양환경ㆍ에너지학회지
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    • 제16권1호
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    • pp.53-59
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    • 2013
  • 1990년대 이후, 중소형 폐 선박으로부터 생성되는 FRP를 재활용하기 위한 방법으로 층상으로 배열된 로빙층과 매트층을 분리하는 것은 친 환경적이면서도 경제적 재활용의 장점을 가지고 있다. 그러나 효율적으로 로빙층과 매트층을 분리하는 기술과 로빙층은 매트층에 비해 얇은 두께로 존재한다는 이유로 인해 로빙층을 매트층과 분리할 때 기계가 자동적으로 층간의 차이를 인식하는 방법은 아직 개발이 이루지지 않고 있다. 본 연구에서는 유리의 구성비가 다른 두 층의 화학적 성질의 차를 이용하여 광학적으로 층간 인식이 가능한 방법을 모색하였다. 또한 다양한 로빙층의 구성에도 자동적으로 절단위치를 분석하는 절단시스템과 최종생산물의 유용성을 확보할 수있는 다양한 크기의 유리섬유를 생산할 수있는 세단기를 개발하였다. 본 연구 결과로 광학적 인식기술과 유연한 절단기술 그리고 다양한 세단기술이 융합된 폐 FRP의 분리 공정의 단순화와 자동화를 달성하게 되었다.

입상활성탄에 의한 수용액으로부터 오로라 레드의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구 (Equilibrium, Kinetic and Thermodynamic Parameter Studies on Adsorption of Allura Red from Aqueous Solution by Granular Activated Carbon)

  • 이종집
    • 공업화학
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    • 제25권4호
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    • pp.430-436
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    • 2014
  • 오로라레드(Allura Red, AR)는 수용성의 유해한 타르계 식품착색제(적색 40호)이다. 역청탄계 입상활성탄을 사용한 AR의 회분식 흡착실험은 흡착제의 양, 초기농도, 접촉시간과 흡착온도를 조작변수로 선택하여 수행되었다. 흡착평형자료를 가지고 Langmuir와 Freundlich 및 Temkin 흡착등온식에 대한 적합성을 평가하였다. 흡착평형은 Langmuir 흡착등온식이 더 잘 맞았으며, 계산된 분리계수($R_L$) 값으로부터 입상활성탄이 AR을 효과적으로 처리할 수 있다는 것을 알 수 있었다. Temkin parameter, B의 값은 1.62~3.367 J/mol로 흡착공정이 물리흡착임을 나타내었다. 흡착속도실험으로부터, 입자내확산속도상수($k_m$)는 온도증가와 함께 커졌으며, 흡착공정은 유사이차반응속도식에 잘 맞았음을 알았다. 흡착공정의 특성을 평가하기 위하여 활성화에너지, 엔탈피, 엔트로피 및 Gibbs 자유에너지변화와 같은 열역학 파라미터들을 298~318 K의 온도 범위에서 조사하였다. Gibbs 자유에너지변화값(${\Delta}G$ = -7.02~-8.79 kJ/mol)과 엔탈피변화값(${\Delta}H$ = + 82.2 kJ/mol)으로부터 흡착공정이 자발적이고 흡열과정임을 알았다.

성숙한 3T3-L1 지방세포에서 Akkermansia muciniphila의 지방축적 감소 효과 (Effect of Reduction in the Adipose Accumulation of Akkermansia muciniphila in Mature 3T3-L1 Adipocytes)

  • 심혜윤;임수경;신주현;이도경;서재구;김호준
    • 한방비만학회지
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    • 제19권2호
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    • pp.106-112
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    • 2019
  • Objectives: The aim of this study was to observe the reduction of lipid accumulation by treatment with Akkermansia muciniphila extract on 3T3-L1 adipocytes. Methods: After treating pasteurized Akk. muciniphila strains in HT-29 colorectal cancer cell, the relative expression of interleukin (IL)-8, tumor necrosis factor-α, IL-6, and IL-1β mRNA was analyzed by real time polymerase chain reaction, respectively. 27 strains of Akk. muciniphila which have anti-inflammatory effects were selected. 3T3-L1 pre-adipocytes were treated with Akk. muciniphila for 24 hr and then measured the toxicity using water soluble tetrazolium salt assay. The cells were incubated for 4 days and then differentiated into adipocytes using the medium including adipogenic reagents for 10 days. The Akk. muciniphila was treated when the medium was exchanged for differentiation medium at 4th day and insulin medium at 6th day. To observe the lipid accumulation, the cells were stained with Oil red O dye and were measured using a spectrophotometer. Results: In the cytotoxicity test, the cell viability of 3T3-L1 pre-adipocytes was significantly increased compared to the control group which untreated with Akk. muciniphila, and there was no cytotoxicity of Akk. muciniphila at 1×107 CFU/mL. The results on Oil red O staining and absorbance measurements were showed a significant decrease in lipid accumulation in the group which was treated with Akk. muciniphila compared to the control group. Conclusions: In our results, Akk. muciniphila has the inhibitory effect of lipid accumulation in 3T3-L1 adipocytes. This suggests that Akk. muciniphila could be help to improve obesity.