• Title/Summary/Keyword: water vapor resistance

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Phase formation and microstructural characteristics of ytterbium silicates coatings fabricated by plasma spraying with Ar/He gas compositions for environmental barrier coating applications (플라즈마용사로 증착된 환경차폐코팅 이터븀 실리케이트의 Ar/He 가스 조성에 따른 상형성 및 미세구조 특성)

  • Choi, Jae-Hyeong;Kim, Seongwon;Kim, Ji-Yoo;Moon, Hung Soo
    • Journal of the Korean institute of surface engineering
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    • v.55 no.6
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    • pp.376-382
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    • 2022
  • Yb2Si2O7 has a coefficient of thermal expansion similar to that of the base material of SiC and has excellent corrosion resistance in a high-temperature oxidizing atmosphere including water vapor, so it is being studied as one of the materials for environmental barrier coatings (EBCs). In this study, Yb2Si2O7 powder granule is deposited using atmospheric plasma spraying (APS) with different Ar/He ratios. Phase formation and microstructural characteristics are investigated with the coated specimens. In the coating layer, the crystallinity decreased, and the amorphous content increased from an increase in the ratio of Ar. In addition, the various types of particles involved by local volatilization of Si according to the Ar/He ratios were identified.

Geotechnical Characteristics of Prefabricated Vertical Drain System for Contaminated Soil Remediation (오염토양 복원을 위한 연직배수시스템의 지반공학적 특성)

  • Shin, Eunchul;Park, Jeongjun
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.5
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    • pp.5-14
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    • 2007
  • The quantity of noxious wastes generated by the growth in industrialization and population in all over the world and its potential hazards in subsurface environments are becoming increasingly significant. The extraction of the contaminant from the soil and movement of the water are restricted due to the low permeability and adsorption characteristics of the reclaimed soils. Incorporated technique with PVDs have been used for dewatering from fine-grained soils for the purpose of ground improvement by means of soil flushing and soil vapor extraction systems. This paper is to evaluate several key parameters that affected to the performance of the PVDs specifically with regard to: well resistance of PVD, zone of influence, and smear effects. In the feasibility of contaminant remediation was evaluated in pilot-scale laboratory experiments. Well resistance is affected on the vertical discharge capacity of the PVDs under the various vacuum pressures. The discharge capacity increases consistently in areal extents with higher applied vacuum up to a limiting vacuum pressure. The head values for each piezometer at different vacuum pressures show that the largest head loss occurs within 14 cm of the PVD. Air flow rates and head losses were measured for the PVD placed in the model test box and the gas permeability of the silty soils was calculated. Increasing the equivalent diameter results in a decrease in the calculated gas permeability. It is concluded that the gas permeability determined over the 1,500 to 2,000 $cm^3/s$ flow rates are the most accurate values which yields gas permeability of about 3.152 Darcy.

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Low-costBacksheet Materials with Excellent Resistance to Chemical Degradation for Photovoltaic Modules (태양전지모듈용 고내구성 저가형 백시트)

  • Pyo, Se Youn;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.3
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    • pp.287-294
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    • 2015
  • Photovoltaic (PV) modules are environmentally friendly energy-conversion devices to generate electricity via the photovoltaic effect of semiconductors on solar energy. One of key elements in PV modules is "Backsheet," a multi-layered film to protect the devices from a variety of chemicals including water vapor. A representative Backsheet is composed of polyvinyl fluoride (PVF) and poly(ethylene terephthalate) (PET). PVF is relatively expensive, while showing excellent resistance to chemical attacks. Thus, it is necessary to develop alternatives which can lower its high production cost and guarantee lifetime applicable to practical PV modules at the same time. In this study, PET films with certain levels of crystallinity were utilized instead of PVF. Since it is well known that PET is suffering from trans-esterification and hydrolysis under a wide pH range, it is needed to understand decomposition behavior of the PET films under PV operation conditions. To evaluate their chemical decomposition behavior within a short period of times, accelerated decomposition test protocol is developed. Moreover, electrochemical long-term performances of the PV module employing the PET-based Backsheet are investigated to prove the efficacy of the proposed concept.

Sorption Characteristics of Binary Mixture of Corn Starch- Soy Protein Isolates in Plastic film Packaging (Plastic필름 포장에 따른 옥수수 전분과 분리 대두단백질의 이성분 혼합물의 흡습특성)

  • Kim, Duck-Woong;Woo, Sang-Gyu
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.17 no.3
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    • pp.191-197
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    • 1988
  • Sorption properties of corn starch(CS) and Soy protein isolates(SPI) in plastic films packaging were investigates for binary system. The mixture were sealed in plastic films of low density polyethylene(LDPE), oriented polypropylene(OPP) and LDPE/OPP coated film and packaging effect on the changes of moisture sorption during storage at $40^{\circ}C$ were studied. The following results were obtained. The water vapor permeability of material films was $32.6g/m^2/24hrs(below\;g)$ for 0.02mm LDPE film, 14.01g for 0.04mm LDPE film, 7.30g for 0.02mm OPP film, 3.37g for 0.04mm OPP film and 4.869 for 0.02mm LDPE/0.02 mm OPP confine film at $40^{\cire}C$ 90%RH, therefore the OPP film was more effective than LDPE film on the resistance of relative humidity. And the OPP film packaging sealed mixture of food samples was also more elective then LDPE film, having same thickness for increase of water vapor permeability during storage at $40^{\cire}C$. A general increase in sorption rate was found more in SPI than CS in the packaged mixtures.

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A Study on Standardization of Test Method for Water Vapour Permeability of Textiles Fabrics (군용 피복류의 투습도 시험방법 표준화 연구)

  • Lee, Min-Hee;Hong, Seong-Don;Chung, Il-Han
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.10
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    • pp.27-33
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    • 2016
  • Military textiles with breathable waterproof materials are expanding as form of winter clothes. Waterproof moisture-permeable clothes are very important for soldiers to survive in cold weather operations because they prevent loss of body heat from the penetration of water into the human body. Korea military uses the water resistance and moisture permeability to test the performance of waterproof moisture-permeable materials. Moisture permeability is measured according to the amount of evaporated water vapor passing through a fabric under specified temperature and humidity by using acetic acid potassium presented in KS K 0594. However, the test procedure for measuring the moisture permeability in the standard is presented only briefly and the preparation procedures for the test in accredited testing institutions are applied differently, leading to significant deviation of the results. This paper compares the procedures of testing institutions and examines the factors that affect moisture permeability. Finally, we propose a procedure to reduce the deviation of results and apply the proposed procedure in testing institutions. Our analysis results with one-way ANOVA under significant level (0.05) confirm that the deviation of results is reduced.

Review of Spatting Effect on Concrete Element in Fire (화재시 콘크리트 요소 폭렬영향성 고찰)

  • Kim, Hyung-Jun;Han, Sang-Hoon;Choi, Seng-Kwan
    • Fire Science and Engineering
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    • v.21 no.2 s.66
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    • pp.54-63
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    • 2007
  • Concrete is generally accepted to have good inherent fire resistance. It mainly relies on the assumption that concrete has low heat-transfer characteristic and spatting does not occur during the course of a fire. However, the significant numbers of fire accidents have shown in recent years that incidence of spatting has caused sever damages to many structures. This review has systematically investigated the behaviour of concrete in fire, including phenomenon of spatting, with respect to the theorical consideration and experimental results. Explosive spatting is caused by the build-up of water vapor pressure in concrete subjected to increasing temperatures. When this pressure exceeds the tensile strength of the concrete over a fire-exposed area, explosive spatting can result in a typical temperature range between $200^{\circ}C\;and\;400^{\circ}C$. The major functions are known to be moisture content, pore pressure, load ratio, and heating regime.

Performance Evaluation of Protective Clothing Materials for Welding in a Hazardous Shipbuilding Industry Work Environment (조선업의 유해 작업환경 대응을 위한 용접 보호복 소재의 성능평가 연구)

  • Kim, Min Young;Bae, Hyun Sook
    • Fashion & Textile Research Journal
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    • v.15 no.3
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    • pp.452-460
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    • 2013
  • This study conducted a performance evaluation of protective clothing materials used for welding in a hazardous shipbuilding industry work environment. The welding process was selected as the one that most requires industrial protective clothing according to work environment characteristics. Flame proofing and convection heat protection performance (HTI) in the heat transfer characteristics of protective clothing material were indicated in the order of SW1(Oxidant carbon)>SW2(silica coated Oxidant carbon)>SW4(Oxidant carbon/p-aramid)>SW3(flame proofing cotton). However, radiant heat protection performance (RHTI) and the heat transfer factor (TF) were indicated in the order of SW1>SW4>SW2>SW3 and showed different patterns from the convection heat protection performance. SW1 showed superior air permeability and water vapor permeability. The tensile strength and tear strength of welding protective clothing material were indicated in the order of SW4>SW2>SW3>SW1 and showed that a blend fabric of p-aramid was the most superior for the mechanical properties of SW4. SW1 had excellent heat transfer properties in yet met the minimum performance requirements of tensile strength proved to be inappropriate as being a material for welding protective clothing. The abrasion resistance of woven fabric proved superior compared to nonwoven fabric; however, seam strength and dimensional change both met the minimum performance requirements and indicated that all samples appeared non-hazardous. Finally, oxidant carbon/p-aramid blend fabric appeared appropriate as a protective clothing materials for welding.

Estimation of Optimum PP Fiber Content for the Spalling Control of High Strength Reinforced Concrete Columns (고강도 철근콘크리트 기둥의 폭열제어를 위한 최적의 PP섬유함유량 산정)

  • Kim, In Ki;Yoo, Suk Hyeong;Shin, Sung Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.2
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    • pp.155-163
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    • 2007
  • High Strength Concrete (HSC) has weakness that in a fire, it is spalled and brittles. The phenomenon of spalling is made by water vapor's (resulting from evaporation in the material at over $100{^{\circ}C}$)' being confined in watertight concrete. As the concrete strength increases, the degree of damage caused by the spalling becomes more serious because of the permeability. It is reported that the polypropylene(PP) fiber has an important role in protecting concrete from spalling and the optimum dosage of PP fiber is 0.2%. This study was conducted on the nonreinforced concrete specimens. The high-temperature behavior of high-strength reinforced concrete columns with various concrete strength and various dosage of PP fibers was investigated in this study. The results show that the ratio of unstressed residual strength of columns increases as the concrete strength increases and the ratio of unstressed residual strength of columns increases as the dosage of PP fiber increases from 0% to 0.2%, however, the effect of fiber dosage on residual strength of column barely changes above 0.2%.

Modification of Na-Alginate Films by $CaCl_2$ Treatment ($CaCl_2$의 처리에 의한 알긴산 필름의 물성개선)

  • Rhim, Jong-Whan;Kim, Ji-Hye;Kim, Dong-Han
    • Korean Journal of Food Science and Technology
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    • v.35 no.2
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    • pp.217-221
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    • 2003
  • Effect of direct addition of $CaCl_2$ into sodium alginate film-making solution and immersion of alginate films into $CaCl_2$ solutions on tensile strength (TS), percentage elongation at break (E), water vapor permeability (WVP), and water solubility (WS) of the films were investigated. TS of alginate films prepared by both methods increased. E of $CaCl_2-added$ films did not change significantly (P>0.05), whereas that of $CaCl_2-immersion$ films decreased significantly (p<0.05). WVP of films prepared by both methods decreased significantly, but the effect was more significant in the $CaCl_2-immersion$ films. Water resistance was not changed in the $CaCl_2-added$ films, whreras increased significantly in $CaCl_2-immersion$ films (p<0.05). Properties of alginate films depend on the concentration of $CaCl_2$ treatments in both methods, and they also depend on treatment time in the immersion method.

Development of Accident Response Information Sheets for Hydrogen Fluoride (불화수소에 대한 사고대응 정보시트 개발)

  • Yoon, Young Sam;Park, Yeon Shin;Kim, Ki Joon;Cho, Mun Sik;Hwang, Dong Gun;Yoon, Jun heon;Choi, Kyung Hee
    • Korean Journal of Hazardous Materials
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    • v.2 no.1
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    • pp.18-26
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    • 2014
  • We analyzed the demand of competent authorities requiring adequate technical information for initial investigation of chemical accidents. Reflecting technical reports on chemical accident response by environmental agencies in the U.S. and Canada, we presented information on environmental diffusion and toxic effects available for the first chemical accident response. Hydrogen fluoride may have the risk potential to corrode metals and cause serious burns and eye damages. In case of inhalation or intake, it could have severe health effects. The substance itself is inflammable, but once heated, it decomposes producing corrosive and toxic fume. In case of contact with water, it can produce toxic, corrosive, flammable or explosive gases and its solution, a strong acid, may react fiercely with a base. In case of hydrogen fluoride leak, the preventive measures are to decrease steam generation in exposed sites, prevent the transfer of vapor cloud and promptly respond using inflammable substances including calcium carbonate, sodium bicarbonate, ground limestone, dried soil, dry sand, vermiculite, fly ash and powder cement. The method for fire fighting is to suppress fire with manless hose stanchions or monitor nozzles by wearing the whole body protective clothing equipped with over-pressure self-contained breathing apparatus from distance. In case of transport accident accompanied with fire, evacuation distance is 1,600m radius. In cae of fire, fire suppression needs to be performed using dry chemicals, CO2, water spray, water fog, and alcohol-resistance foam, etc. The major symptoms by exposure route are dyspnoea, bronchitis, chemical pneumonia and pulmonary edema for respiration, skin laceration, dermatitis, burn, frostbite and erythema for eyes, and nausea, diarrhea, stomachache, and tissue destruction for digestive organs. In atmosphere, its persistency is low, and its bioaccumulation in aquatic organism is also low.