• Transactions of the Korean hydrogen and new energy society
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• v.24 no.3
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• pp.223-229
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• 2013

Polymer Electrolyte Membrane Fuel Cell (PEMFC) is a power generation system to convert chemical energy of fuels and oxidants to electricity directly by electrochemical reactions. As a catalyst support for PEMFCs, carbon black has been generally used due to its large surface area and high electrical conductivity. However, under certain circumstances (start up/shut down, fuel starvation, ice formation etc.), carbon supports are subjected to serve corrosion in the presence of water. Therefore, it would be desirable to switch carbon supports to corrosion-resistive support materials such as metal oxide. $TiO_2$ has been attractive as a support with its stability in fuel cell operation atmosphere, low cost, commercial availability, and the ease to control size and structure. However, low electrical conductivity of $TiO_2$ still inhibits its application to catalyst support for PEMFCs. In this paper, to explore feasibility of $TiO_2$ as a catalyst support for PEMFCs, $TiO_2$ nanofibers were synthesized by electrospinning and calcinated at 600, 700, 800 and $900^{\circ}C$. Effects of calcination temperature on crystal structure and electrical conductivity of electrospun $TiO_2$ nanofibers were examined. Electrical conductivity of $TiO_2$ nanofibers increased significantly with increasing calcination temperature from $600^{\circ}C$ to $700^{\circ}C$ and then increased gradually with increasing the calcination temperature from $700^{\circ}C$ to $900^{\circ}C$. It was revealed that the remarkable increase in electrical conductivity could be attributed to phase transition of $TiO_2$ nanofibers from anatase to rutile at the temperature range from $600^{\circ}C$ to $700^{\circ}C$.

• Journal of Energy Engineering
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• v.8 no.2
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• pp.242-247
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• 1999

The characteristics of waste heat effluents from 11 industrial complexes of 7 areas were analyzed to investigate the possibility of waste heat recovery of huge amount of waste heat producing from various industrial complexes. This study presents a part of the research work for the industrial waste heat for development of energy integrated network system in broad city area, which will utilize industrial waste heat for residential and commercial areas, where they are located at some distances from the complexes. The amount of waste heat from the investigated complexes was detected as 148,913 TOE/year. However, It was analyzed 83% of the waste heat was analyzed the temperature range from 0$^{\circ}C$ to 200$^{\circ}C$. Also, it was evaluated that 82% of waste heat was exhausted by flue gases. Especially, the characteristics of waste heat for the areas where most heat concentrated, such as Tae-gu industrial complex, Ul-san petrochemitry complex, Yio-chun petrochemistry complex, and Chun-ju industrial complex were investigated more precisely. Total amount of waste heat discharged from these four areas were analyzed 114,402 TOE/year, which was occupied as 77% of the total waste heat for the studied areas, and 87% of the waste heat from the industries was exhausted by flue gaseous phase and temperature range was from 0$^{\circ}C$ to 200$^{\circ}C$ 18.1 million TOE/year waste heat was released from the fossil fuel power plants, however 95% of waste heat was analyzed as cooling water from surface condensers at power plants. The temperature range was measured from 27$^{\circ}C$ to 34$^{\circ}C$, which are unable to utilize due to its low temperature. Otherwise, 5% (894,800 TOE/year) waste heat released from power plants were observed as flue gas, which temperature ranged from 90$^{\circ}C$ to 170$^{\circ}C$.

• Economic and Environmental Geology
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• v.36 no.3
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• pp.171-176
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• 2003

The fate and behavior of polycyclic aromatic hydrocarbons(PAHs) and heavy metals in the environment are mainly controlled by their interactions with various components of soils and sediments. Due to their large surface area and abundance in many soils, smectites may greatly influence the fate and transport of the contaminants. In our experiment, PAH sorption by hexadecyltimethylammonium(HDTMA)-modified smectite linearly increased in proportion to the amount of HDTMA added on the clay. However, trimethylammonium(TMA)-modified smectite did not show superiority in its sorption of PAH compared with the HDTMA-smectite or dodecyltrimethylammonium(DTMA)- smectite. Meanwhile, the smectites modified with the same cationic surfactants adsorbed Cd$^{2＋}$(heavy metal) significantly from water at low surfactant loading level, but the Cd$^{2＋}$ adsorption linearly decreased as the loading of surfactant increased. The result shows that the sorption tendency of organoclays for organic or inorganic contaminants was significantly influenced by the amount and size of the surfactants added on the clay. This reveals that the stabilization and configuration of cationic surfactant formed on the clay interlayer of different sizes may be an important factor in controlling the sorptive capacity of each pollutant in the environment.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.663-666
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• 2005

Gas hydrates are ice-like compounds that form at the low temperature and high pressure conditions common in shallow marine sediments at water depths greater than 300-500 m when concentrations of methane and other hydrocarbon gases exceed saturation. Estimates of the total mass of methane carbon that resides in this reservoir vary widely. While there is general agreement that gas hydrate is a significant component of the global near-surface carbon budget, there is considerable controversy about whether it has the potential to be a major source of fossil fuel in the future and whether periods of global climate change in the past can be attributed to destabilization of this reservoir. Also essentially unknown is the interaction between gas hydrate and the subsurface biosphere. ODP Leg 204 was designed to address these questions by determining the distribution, amount and rate of formation of gas hydrate within an accretionary ridge and adjacent basin and the sources of gas for forming hydrate. Additional objectives included identification of geologic proxies for past gas hydrate occurrence and calibration of remote sensing techniques to quantify the in situ amount of gas hydrate that can be used to improve estimates where no boreholes exist. Leg 204 also provided an opportunity to test several new techniques for sampling, preserving and measuring gas hydrates. During ODP Leg 204, nine sites were drilled and cored on southern Hydrate Ridge, a topographic high in the accretionary complex of the Cascadia subduction zone, located approximately 80km west of Newport, Oregon. Previous studies of southern Hydrate Ridge had documented the presence of seafloor gas vents, outcrops of massive gas hydrate, and a pinnacle' of authigenic carbonate near the summit. Deep-towed sidescan data show an approximately $300\times500m$ area of relatively high acoustic backscatter that indicates the extent of seafloor venting. Elsewhere on southern Hydrate Ridge, the seafloor is covered with low reflectivity sediment, but the presence of a regional bottom-simulating seismic reflection (BSR) suggests that gas hydrate is widespread. The sites that were drilled and cored during ODP Leg 204 can be grouped into three end-member environments basedon the seismic data. Sites 1244 through 1247 characterize the flanks of southern Hydrate Ridge. Sites 1248-1250 characterize the summit in the region of active seafloor venting. Sites 1251 and 1252 characterize the slope basin east of Hydrate Ridge, which is a region of rapid sedimentation, in contrast to the erosional environment of Hydrate Ridge. Site 1252 was located on the flank of a secondary anticline and is the only site where no BSR is observed.

• Korean Journal of Soil Science and Fertilizer
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• v.28 no.4
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• pp.312-318
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• 1995

To investigate the effect of N split application on the increasing ratio of yield and the yield of rice, urea and slow-releasing complex for sideband placement of fertilizer were applied in Jeonbuk series of Honam plain area. Increasing ratio of yield by N split application was higher in puddled drill seeding (PDS) than flooded direct seeding surface (FDSS) under split application of 40-0-30-30% and 70-0-0-30% at basal, 3 leaf, 5 leaf and panicle initiation stage, respectively. It was also higher in LCU application of 70 % of total urea amount than urea application but was not different between two methods of seeding in urea application. Nitrogen ratio transfered to rough grain of rice was higher in FDSS than PDS, errespective of methed of split application, except for the split application of 0, 40, 30 and 30% N fertilizer at basal, 3 leaf, 5 leaf and panicle initiation stage, respectively. Nitrogen amount outflowed by artificial drainage for paddy field drying in a day after application of fertilizer was 1,134g/10a in PDS. $NH_4-N$ incerased higher in PDS than FDSS under split application of urea, while was versa under LCU application.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.5 no.4
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• pp.363-373
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• 2000

To understand and investigate chemical characteristics of thermal environment in the southwestern Paciflc, we have measured hydrological and chemical parameters such as temperature, salinity, transparency, pH, nutrients and hydrogen sulfide (H$_2$S). Samples were collected with CTD-casting at 12 station, in Manus Basin including PACMANUS, DESMOS and Susu Knolls, Hydrothermal systems consist of circulation zones where seawater interacts with rock, thereby changing chemical and physical characteristics of both the seawater and the rock. The altered seawater, called hydrothermal fluid, is injected back into the ocean from the hydrothermal vent fields and forms hydrothermal plumes. Consequently, we detected hydrothermal plume with transparency and sulfide anomalies at PACMANUS and Susu Knolls. Sulfide, as geochemical tracer of hydrothermal plume, ranged 0-3.31 ${\mu}$M, and averaged 0.63 ${\mu}$M in the study area. The height, flux and activity of the plume are affected by circulations in the deep water and the spread of plume follows along the isopycnal surface. Therefore the observed H$_2$S anomaly can provide important clue for the source location and it appears that the targestsource in the PACMANUS is aligned in the north-south direction.

• Korean Journal of Environmental Agriculture
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• v.13 no.2
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• pp.231-239
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• 1994

A reed-sand-filter system was used to purify swine wastewater economically. Reeds (Phragmites communis Trin) were planted on the sand / gravel bed of a 20/30cm layer depth. After the input of waste-water up to a depth of l0㎝, the effluent was monitored for pollutants on the 1st, 3rd, 5th and 7th day thereafter. As swine wastewater stayed longer, the pollutants in the effluent such as T-N, $PO_4^{3-}$, COD and BOD were removed more effectively. The sand-filter system with reeds showed a superior removal efficiency to that without reeds. Especially in summer, the former showed greater purification rates than the latter, being 30% greater in T-N, 37% in $PO_4^{3-}$, 42% in COD and 30% in suspended solids. The seasonal purification efficiency was in the decreasing order of July, October and April. Reeds took up 40.1g N, 10.8g $P_2O_5$, 38.9g $K_2O$, 2.8g CaO, 2.1g MgO per square meter of the above surface area.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.7
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• pp.1-11
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• 2020

This study investigated the mesozooplankton community and the related environmental factors in the Nakdong River Estuary in May and early October shortly after passage of the typhoon "DUJUAN" in 2015. The mesozooplankton community was dominated by barnacle nauplii, foraminiferans, and Noctiluca scintillans, and the environmental characteristics were characterized by freshwater inflow through the Nakdong River barrage, the intrusion of warm currents, and the effect of typhoon passage in October. In May, cladocerans, such as Evadne nordmanni and Podon polyphemoides, as indicator species of brackish water, prevailed throughout the study area. The surface salinity was lowest on the inner side of the barrier-islands and increased gradually to the outer side during the study. The average concentration of total suspended solids in October was higher than that in May, while the averaged concentration of nitrate and chlorophyll-a in May was higher than those in October. On the other hand, there was no temporal difference in the total averaged abundance of mesozooplankton. In contrast, the distributional pattern of the mesozooplankton community was associated with the salinity gradient in both seasons. These results suggest that the temporal difference of the mesozooplankton community depended on the extent of freshwater inflow by barrage opening, the intrusion intensity of warm currents, and typhoon passage in the Nakdong River estuary in 2015.

• Journal of radiological science and technology
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• v.21 no.2
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• pp.36-42
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• 1998

Treatment of a large diseased area with electron often requires the use of two or more adjoining fields. In such cases, not only electron beam divergence and lateral scattering but also fields overlapping and separation may lead to significant dose inhomogeneities(${\pm}20%$) at the region of junction of fields. In this study, we made Acrylic Electron Wedges to improve dose inhomogeneities(${\pm}5%$) in these junction areas and to apply it to clinical practices. All measurements were made using 6, 9, 12, 16, 20 MeV Electron beams from a linear accelerator for a $10{\times}10\;cm$ field at 100cm of SSD. Adding a 1 mm sheet of acryl gradually from 1 mm to 15 mm acquires central axis depth dose beam profile and isodose curves in water phantom. As a result, for all energies, the practical range was reduced by approximately the same distance according to the acryl insert, e.g. a 1 mm thick acryl insert reduces the practical range by approximately 1 mm. For every mm thickness of acryl inserted, the beam energy was reduced to approximately 0.2 MeV. These effects were almost Independent of beam energy and field size. The use of Acrylic Electron Wedges produced a small increase(less than 3%) in the surface dose and a small increase(less than 1%) in X-ray contamination. For acryl inserts, thickness of 3 mm or greater, the penumbra width increased nearly linear for all energies and isodose curves near the beam edge were nearly parallel with the incident beam direction at the point of penumbra width($35\;mm{\sim}40\;mm$). We decide heel thickness and angle of the wedge at this point. These data provide the information necessary to design Acrylic Electron Wedge which can be used to improve dose uniformity at electron field junctions and it will be effectively applied to clinical practices.

• Korean Journal of Remote Sensing
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• v.33 no.2
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• pp.231-242
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• 2017

Monitoring of facilities such as roads, dams and bridges is important for their long-term sustainable usage. It has usually suffered with safety and cost problems, which makes more frequent monitoring difficult. As an efficient and economicalsolution to these problems, one may consider the use of smartphone to capture the status of the facilities. To derive quantitative analysis results with the smartphone images for facility monitoring, one should first rectify the images in a way as automatic and economical as possible. In thisstudy, we propose such a rectification method, which rectifiessmartphone images acquired from arbitrary locations based on reference images.In the proposed method, we determine the camera extrinsic parameters of each smartphone images using the reference imagesrather than ground control points, and project the image to the target surface of the facility based on the determined camera parameters. The method were applied to test data acquired from a small dam toward water-area facility monitoring. The experimental results showed that the camera extrinsic parameters were determined with the accuracy of 5 cm and $0.28^{\circ}$ in the position and attitude. The accuracy of the distance measured from the rectified image was evaluated to 10 cm. With the rectified images, one can accurately determine the location and length of the target objects required for facility monitoring.