• 제목/요약/키워드: water quality degradation

검색결과 226건 처리시간 0.03초

오존에 노출된 에폭시 코팅재의 표면 열화특성 평가기술 (Techniques for Characterizing Surface Deterioration of Epoxy Exposed to Ozone Damage)

  • 최성민
    • 한국구조물진단유지관리공학회 논문집
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    • 제18권3호
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    • pp.167-177
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    • 2014
  • 최근 수질오염의 악화로 고도정수처리시설에 대한 수요가 커지고 있으며, 오존처리와 같은 밀폐형 고도정수처리시설의 설치가 늘고 있는 실정이다. 그러나 오존의 강력한 산화작용으로 인해 콘크리트 구조물의 침식이 우려됨에 따라 오존에 대응 가능한 에폭시 방수방식재가 콘크리트 표층부 보호 코팅재로 적용되고 있다. 그러나 이러한 에폭시가 오존에 대한 성능수준 및 장기적 내구성을 명확히 측정할 방법과 기준이 없어 정확한 품질관리가 이루어지지 않고 있는 실정이며, 이로 인해 수처리용 콘크리트 구조물의 장기내구성 확보에 대한 우려가 제기되고 있다. 이 연구에서는 AFM과 나노인덴테이션 기법이 기존에 사용하던 평가방법인 육안관찰, 중량변화, 표면관찰, 색차분석 등의 간접적 평가방법과 함께 에폭시 방수방식재 평가방법으로써의 적합한지를 판단하고자 하였으며, 이를 위해 오존용으로 개발된 6종의 다른 성분으로 구성된 에폭시계 방수방식재를 대상으로 열화특성을 분석하였다. 연구결과 AFM과 나노인덴테이션을 활용할 경우 기존 평가방법보다 직접적이고 정량적인 평가가 가능함을 확인하였으며, 일부 에폭시 코팅재료의 경우 오존에 대한 성능 한계치 (임계치)를 명확히 확인할 수 있었다.

고농도 휴믹성분이 포함된 강 원수에서 응집-침전 및 오존 공정을 전처리로 적용한 오존 내성막 pilot plant에서의 운전성 및 투과수 수질변화에 관한 연구 (Pre-Coagulation and Pre-Ozonation for Ozone Resisting Microfiltration Membrane Filtration System of a High Humic Contained Surface Water)

  • 이상협;와타나베 요시마사;이석헌;안규홍
    • 상하수도학회지
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    • 제18권5호
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    • pp.598-607
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    • 2004
  • In this study, the effects of two pre-treatment processes were observed prior to membrane filtration: pre-coagulation and pre-ozonation. To compare the effect of two above-mentioned pre-treatments, we adopted the four schemes: first one is direct membrane filtration of river surface water, second one is membrane filtration after pre-coagulation, third one is membrane filtration after pre-ozonation and fourth one is membrane filtration after pre-coagulation and pre-ozonation. There are two exceptional characteristics in applied processes. One is the usage of the MF membrane which has high ozone resisting characteristic. Therefore, ozone resides in membrane module during filtration. The other is adoption of Jet Mixed Separator (JMS) as coagulation-sedimentation process. The change in transmembrane pressure and permeate water quality were also examined. As a result, considering the filtration performance efficiency and permeate water quality, the process composed of filtration with combination of both pre-coagulation and pre-ozonation was proved most effective. The improved efficiency was due to the reduction of loading rate of fouling inducing materials to membrane module by coagulation process as well as variable reactions, such as degradation, particle destabilization and coagulation, occurred by residual ozone in membrane module. The additional effect of pre-coagulation before pre-ozonation is suppression of AOC, one of the by-products induced by ozonation. Therefore, combination of pre-coagulation and pre-ozonation is the effective process to overcome the major de-merit of ozonation i.e. by-products formation.

Landsat영상과 DEM을 이용한 청주북부지역의 토지이용 변화특성 (Characteristics of Land-use Changes Northern Cheongju Region using Landsat Images and DEM)

  • 나상일;박종화
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2007년도 학술발표회 논문집
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    • pp.667-672
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    • 2007
  • Land-use in Cheongju region is changing rapidly because of the increased interactions of human activities with the environment as population increases. We used multi-temporal Landsat images (1991 and 2000) and DEM data in a post-classification analysis with GIS to map land-use distribution and to analyse factors influencing the land-use changes for Cheongju City. Land-use statistics revealed that substantial land-use changes have taken place and that the built-up areas have expanded by about $17.57km^2(11.47%)$ over the study period (1991-2000). Agricultural lands and forests have decreased substantially while urban and barren lands have been on the increase. Rapid economic developments together with the increasing population were noted to be the major factors influencing rapid land use changes. Urban expansion has replaced urban and barren lands, thereby affecting habitat quality and leading to serious environmental degradation.

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환경적으로 안전한 농업과 미래용도를 위한 토질 기준 평가 검토 (Review of Assessing Soil Quality Criteria for Environmentally-Sound Agricultural Practics and Future Use)

  • Doug Young Chung
    • 한국토양환경학회지
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    • 제3권2호
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    • pp.127-145
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    • 1998
  • 인간의 건강에 관련된 수질이나 대기의 기준설정과는 달리, 토질은 지협적이고 한정적인 토양의 기능과 이와 관련된 환경요소에 근거한다. 적정한 토질평가제도는 안전한 식품을 생산하거나, 인간과 동물의 건강증진, 그리고 토양의 퇴화 과정을 나타내는 토양성능 지표의 역할을 하여야 한다. 이에 필요한 요소는 첫째로 수분이동과 흡착의 용이성, 둘째로 식물생장의 유지, 셋째로 토양의 물리적 붕괴에 대한 저항성, 넷째로 안전한 식품생산 기반이다. 그리고 끝으로 비용 절감 농업관리와 식품생산 요소로서 토양은 토양과 수질의 영역, 식품사슬, 지속성과 효용성, 환경과 경제성을 포함하여야 한다. 토질지표는 기본 골격 내에서 각각의 기능에 대하여 여러 단계로 분리되며, 각각의 지표는 체계의 원칙에 근거하여 다목적 접근방법을 사웅하여 상대적 중요도를 반영하는 우선 순위와 가중치를 정한다. 각각의점수 환산체계는 낮은 단계부터 높은 단계로 또는 0주터 10의 범위에서 여러 단계로 등급화되어야 한다. 그리고 각각의 범위 수치에 가중치를 곱하고 그리고 토양의 여러 가지의 물리화학적 특성이 고려된 종합 토질등급으로 결론지어져야 된다. 토질 평가 방법을 개발하는데 필요한 기본 골격과 과정은 해당 지역의 대체 또는 기존의 농업방식으로 얻어진 정보를 사용함으로서 결정된다. 토질에 있어서 부수적인 과정, 관리방법, 그리고 정책의 효과를 검증하기 위한 확장된 기본골격의 용도 또한 고려되어져야 한다. 이외에도 하나의 가능한 토질지수의 형태를 개발하기 위해서는 토양의 특성과 토양 내로 유입되는 또는 기존의 화학물질을 연계시켜야된다. 이 연구는 토질의 평가 시 고려되어야 될 요소를 찾기 위한 접근 방법을 제시하고자 한다.

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Effects of microbial enzymes on starch and hemicellulose degradation in total mixed ration silages

  • Ning, Tingting;Wang, Huili;Zheng, Mingli;Niu, Dongze;Zuo, Sasa;Xu, Chuncheng
    • Asian-Australasian Journal of Animal Sciences
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    • 제30권2호
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    • pp.171-180
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    • 2017
  • Objective: This study investigated the association of enzyme-producing microbes and their enzymes with starch and hemicellulose degradation during fermentation of total mixed ration (TMR) silage. Methods: The TMRs were prepared with soybean curd residue, alfalfa hay (ATMR) or Leymus chinensis hay (LTMR), corn meal, soybean meal, vitamin-mineral supplements, and salt at a ratio of 25:40:30:4:0.5:0.5 on a dry matter basis. Laboratory-scale bag silos were randomly opened after 1, 3, 7, 14, 28, and 56 days of ensiling and subjected to analyses of fermentation quality, carbohydrates loss, microbial amylase and hemicellulase activities, succession of dominant amylolytic or hemicellulolytic microbes, and their microbial and enzymatic properties. Results: Both ATMR and LTMR silages were well preserved, with low pH and high lactic acid concentrations. In addition to the substantial loss of water soluble carbohydrates, loss of starch and hemicellulose was also observed in both TMR silages with prolonged ensiling. The microbial amylase activity remained detectable throughout the ensiling in both TMR silages, whereas the microbial hemicellulase activity progressively decreased until it was inactive at day 14 post-ensiling in both TMR silages. During the early stage of fermentation, the main amylase-producing microbes were Bacillus amyloliquefaciens (B. amyloliquefaciens), B. cereus, B. licheniformis, and B. subtilis in ATMR silage and B. flexus, B. licheniformis, and Paenibacillus xylanexedens (P. xylanexedens) in LTMR silage, whereas Enterococcus faecium was closely associated with starch hydrolysis at the later stage of fermentation in both TMR silages. B. amyloliquefaciens, B. licheniformis, and B. subtilis and B. licheniformis, B. pumilus, and P. xylanexedens were the main source of microbial hemicellulase during the early stage of fermentation in ATMR and LTMR silages, respectively. Conclusion: The microbial amylase contributes to starch hydrolysis during the ensiling process in both TMR silages, whereas the microbial hemicellulase participates in the hemicellulose degradation only at the early stage of ensiling.

진해 용원수로의 COD 및 영양염류 농도 추세분석 (Trend Analysis of the COD and Nutrients Concentrations in the Yongwon Channel, Chinhae)

  • 조홍연;채장원;박정규;구명서
    • 한국해안·해양공학회논문집
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    • 제20권4호
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    • pp.421-428
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    • 2008
  • 부산 신항 개발사업으로 형성된 용원수로는 좁고 긴 형태로 해수흐름이 정체되어 환경악화가 우려되는 지역이다. 본 연구에서는 2003년부터 2007년까지의 월별 관측 자료를 이용하여 용원수로의 수질변화 양상을 분석하였다. 추정된 연평균 농도와 오차범위를 분석한 결과 용원수로 내부가 용원수로 입구에 비하여 전반적으로 뚜렷하게 수질이 악화되어 있는 것으로 파악되었다. 수로 입구의 수질농도를 기준으로 수로 내부의 수질농도는 COD, TN, TP 항목의 경우 각각 1.34배, 2.08배, 1.80배로 높은 것으로 파악되었다. 한편, Mann-Kendall 방법을 이용한 오염물질 농도변화의 추세검정 결과, 일반적으로 사용되는 95% 신뢰수준에서 추세를 가지는 경우는 SW-26 지점 TP 항목(증가추세)을 제외하고는 모두 뚜렷한 변화 추세는 없는(엄밀한 통계적인 용어로는 "있지 않은") 것으로 파악되었다.

주거단지 건설이 하천에 미치는 생태영향평가 (Environmental Impact Assessments along with Construction of Residential and Commercial Complex)

  • 안광국;한정호;이재훈
    • 환경영향평가
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    • 제21권5호
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    • pp.631-648
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    • 2012
  • The integrative ecological approaches of chemical assessments, physical habitat modelling, and multi-metric biological health modelling were applied to Gwanpyeong Stream within Gap-Stream watersheds to evaluate environmental impacts on the constructions of residential and commercial complex. For the analysis, the surveys conducted from 45 sites of reference streams within the Gap-Stream watershed and 3 regular sites during 2009 - 2010. Physical habitat health, based on the habitat model of Qualitative Habitat Evaluation Index(QHEI) declined from the headwaters(good - fair condition) to the downstream(poor condition). Chemical water quality, based turbidity and electric conductivity(EC), was degraded toward to the downstream, and especially showed abrupt increases, compared to the values of control streams(CS). Also, concentrations of chlorophyll-a in the downstreams were greater compared to the control stream(CS), indicating an eutrophication. Biological health conditions, based on the Index of Biological Integrity(IBI) using fish assemblages, averaged 19.3 which is judged as a fair condition by the biological criteria of the Ministry of Environment, Korea. The comparisons of model metric values in sensitive species and riffle-benthic species on the Maximum Species Richness Line(MSRL) of 45 reference streams indicated a massive disturbances in all sampling locations. Also, tolerance guild and trophic guild analyses suggest that dominances of tolerant species and omnivores were evident, indicating a biological degradation by habitat disturbances and organic matter pollutions. There was no distinct longitudinal variations of IBI model values from the headwater to the downstream in spite of slight chemical and habitat health gradients among the sampling sites. Overall, integrative ecological health(IEH) scores, based on the chemical, physical, and biological parameters, were low compared to the 45 reference streams due to physical and chemical disturbances of massive constructions of the residential and commercial complex. This stream, thus showed a tendency of typical urban streams which are disturbed in the chemical water quality, habitat structures, and biological integrity. Effective stream management plans and restoration strategies are required in this urban stream for improving integrative stream health.

Water Resources Management Challenge in the Citarum River Basin, Indonesia

  • Wicaksono, Albert;Yudianto, Doddi;Jeong, Gimoon;Kang, Doosun
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2016년도 학술발표회
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    • pp.198-198
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    • 2016
  • The Citarum River Basin is the biggest river basin in West Java Province, Indonesia and it plays strategic roles in providing water for irrigation, domestic and industrial uses, and power generation, besides controlling the flood during rainy season. Flowing through seven major cities makes the river flow and water demand are vulnerable to land use change around the river. The present water resources management has involved the regulator, operator, and users in deciding an appropriate water management plan for the entire basin. The plan includes an operation plan for three reservoirs, construction or maintenance of the river channel, and water allocation for all users along the river. Following this plan, a smaller operation group will execute and evaluates the plan based on the actual flow condition. Recently, a deforestation, environment degradation, river sedimentation, a rapid growth of population and industry, also public health become new issues that should be considered in water basin planning. Facing these arising issues, a new development program named ICWRMIP was established to advance the existing management system. This program includes actions to strengthen institutional collaboration, do the restoration and conservation of the river environment, improve water quality and public health, also advance the water allocation system. At present, the water allocation plan is created annually based on a forecasted flow data and water usage prediction report. Sometimes this method causes a difficulty for the operator when the actual flow condition is not the same as the prediction. Improving existing system, a lot of water allocation studies, including a development of the database and water allocation simulation model have been placed to help stakeholders decide the suitable planning schemes. In the future, this study also tries to contribute in advancing water allocation planning by creating an optimization model which ease stakeholders discover a suitable water allocation plan for individual users.

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멀티 플라즈마 공정을 이용한 하수 미생물의 불활성화 (Inactivation of Sewage Microorganisms using Multi-Plasma Process)

  • 김동석;박영식
    • 한국환경과학회지
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    • 제23권5호
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    • pp.985-993
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    • 2014
  • For the field application of dielectric barrier discharge plasma reactor, a multi-plasma reactor was investigated for the inactivation of microorganisms in sewage. We also considered the possibility of degradation of non-biodegradable matter ($UV_{254}$) and total organic carbon (TOC) in sewage. The multi-plasma reactor in this study was divided into high voltage neon transformers, gas supply unit and three plasma modules (consist of discharge, ground electrode and quartz dielectric tube). The experimental results showed that the inactivation of microorganisms with treated water type ranked in the following order: distilled water > synthetic sewage effluent >> real sewage effluent. The dissolved various components in the real sewage effluent highly influenced the performance of the inactivation of microorganisms. After continuous plasma treatment for 10 min at 180 V, residual microorganisms appeared below 2 log and $UV_{254}$ absorbance (showing a non-biodegradable substance in water) and TOC removal rate were 27.5% and 8.5%, respectively. Therefore, when the sewage effluent is treated with plasma, it can be expected the inactivation of microorganisms and additional improvement of water quality. It was observed that the $NH_4{^+}$-N and $PO{_4}^{3-}$-P concentrations of sewage was kept at the constant plasma discharging for 30 min. On the other hand, $NO_3{^-}$-N concentration was increased with proceeding of the plasma discharge.

하천형 저수지의 단순 물질수지 모델링 (Simple Material Budget Modeling for a River-Type Reservoir)

  • 윤성규;공동수;배우근
    • 한국물환경학회지
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    • 제26권3호
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    • pp.420-431
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    • 2010
  • 하천형 저수지인 팔당호의 건기시 수질을 모의하기 위하여 단순 물질수지 모델을 개발하였다. 대상 물질은 총인 (TP), 클로로필${\alpha}$ ($Chl.{\alpha}$), 5일 생물학적 산소 요구량 (BOD) 화학적 산소요구량 (COD)이었다. 모델은 지난 20년간의 실측치를 잘 재현하였으며 유기물질의 성인을 밝히는데 이용될 수 있었다. 모델을 통하여 분석한 결과, 팔당호에서 인에 대한 조류의 이용성을 결정하는 임계 수리부하는 약 $1.5m\;d^{-1}$로 나타났다. 팔당호의 $Chl.{\alpha}$, COD, BOD 농도는 임계부하보다 작은 수리부하의 조건에서 생산과 호흡 및 침전과 같은 조류의 변화에 민감하게 반응하였다. 최근 유기오염 저감을 위한 중앙정부와 지방정부의 강도 높은 노력에도 불구하고 팔당호의 수질은 크게 개선되지 않았으며 오히려 COD 농도는 증가하였다. 모델 해석을 통하여 이는 조류 생산량의 증가와 아울러 비점오염원 등에서 외래성 부하가 증가하였기 때문인 것으로 나타났다. 특히 2000~2007년 기간의 조류 기원성 유기물 농도는 전체 유기물 농도의 절반에 해당하는 것으로 추정되었으며, 이는 1988~1994년 기간에 비하여 2.5배, 1995~1999년 기간에 비하여 1.3배에 달하는 수준이었다. 이러한 연구의 결과는 팔당호의 수질개선을 위해서는 조류 발생을 억제하는 것이 필요함을 시사하는 것이었다.