Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.
Much attention has been given recently to solve the environmental contamination in golf courses Changing to culture practice rather than chemical practice that depends on pesticides and fertilizers is a hot issue in golf courses or grasslands. Organic soil conditioners improve soil-plant envirormental conditions rich in physical properties. In this study, measuring systems to evaluate soil conditioning effects were set up for on-site purpose. After establishing the methodology for evaluating soil conditioner effects, 2 kinds of organic conditioners were rested for examination. The systems for the methodology included a set of simulating equipment for field capacity, an impact type soil column compactor, and an infiltration-percolation system. Test results using the systems showed bulk density and infiltration rate of mixed soil were decreased at highter rates of conditioner, but total porocities were increased. Increased porocities were most capillary pore space which has a positive effect on soil water potential. The systems and methodology in this study seem to have an efficiency to measure the effects of soil conditioner on site purpose.
Journal of the Korean Professional Engineers Association
/
v.1
no.1
/
pp.18-25
/
1968
Higher yield in rice paddies is greatly dependent on adequately balanced and timely supply of water. A majority of rice paddy in Korea is generally irrigated by rainfall, but in many cases it has to be supplemented by artificial irrigation for optimum rice culture. Although the water requirement of rice plant is for higher Than that of athec crops, submerged condition of rice paddy is not Necessarily required. The moisture requirement of rice plant varies with its growing stages, and it is possible to increase the irrigation efficiency through reduction of water loss due to percolation in rice paddies. An experimental plots were set up by means of sandomized block design with three duplication; (a) All time submerged, (b) Economically controlled, and (c) Extremely controlled. Three different irrigation periods Were (a) Initial sage, (b) Inter-stage, and (c) Yast stage. The topsoil of the three plots were excavated to the depth of 30 cm and then compacted with clay of 6 cm thickness. There after, they were piled up with the excavated top soils, leveled and cored with clay of 6 cm thickness around footpath in order to prevent leakage. The results obtained from the experiments are as follows, 1. There is no difference among the three experiments plots in terms of physical and chemical conditions, soil properties, and other characteristics. 2. Culm length and ear length are not affected by different irrigation methods. 3. There is no difference in the mature rate and 1, 000 grain weight of rice for the three plots. 4. The control plot which was irrigated every three days shows an increased yield over the all the time submerged plot by 17.8 percent. 5. The clay lined plot whose water holding capacity was held 5 days long, needs only to be irrigated every 7 days. 6. The clay lined plot shows an increased yield over the untreated plot ; over all-the-time submerged plot by 18 percent ; extremely controlled plot by 18 percent, and economically controlled plot by 33 percent. 7. It may be saved in water requirement about one Thirds.
Soil problems and agricultural water management of the reclaimed land in Korea were reviewed through research results conducted in RDA and ADC. According to the Korean Soil Classification and Soil Survey(NIAST, 2002), the 5 soil orders with the 45 soil series were distributed on the fluvio-marine or marine deposit of the west and south coastal plains. Yeompo, Munpo, Hasa, Gwangwhal, and Poseung soil series were most commonly distributed soil on the fluvio-marine deposits, associated with tideland of the sea coast. Former 4 soils were Entisols, and the latest one was the Inceptisols. Buyong soil associated with Poseung series was an Alfisols. Extent of Myeongji soil, a Molisols, and Yongho soil, a Histosol, were minor. Salinity control and management problems were closely related with high water table and low percolation rate due to plow-pan layer developed during the leaching process in the silty textured soil. For evaluation of field salinity, use of an electromagnetic inductance, EM38, with GPS was helpful to understand salinity status and field variability. Deep plowing, subsoiling and drainage improvement by tile drainage might be effective in paddy with plow-pan. New technology such as variable rate fertilization might save fertilizers and thus reduce environmental impact of agriculture on water quality. Water quality of agricultural water resources in reclaimed land was less adequate than that of inland water resources. Proper crop management is necessary depended upon quality for crop growth as well as to match with water quality target.
An automatic calibration tool of Hydrological Simulation Program-Fortran (HSPF), Parameter Estimation (PEST) program, was applied at the Imha lake watershed to get optimal hydrological parameters of HSPF. Calibration of HSPF parameters was performed during 2004 ~ 2008 by PEST and validation was carried out to examine the model's ability by using another data set of 1999 ~ 2003. The calibrated HSPF parameters had tendencies to minimize water loss to soil layer by infiltration and deep percolation and to atmosphere by evapotranspiration and maximize runoff rate. The results of calibration indicated that the PEST program could calibrate the hydrological parameters of HSPF with showing 0.83 and 0.97 Nash-Sutcliffe coefficient (NS) for daily and monthly stream flow and -3% of relative error for yearly stream flow. The validation results also represented high model efficiency with showing 0.88 and 0.95, -10% relative error for daily, monthly, and yearly stream flow. These statistical values of daily, monthly, and yearly stream flow for calibration and validation show a 'very good' agreement between observed and simulated values. Overall, the PEST program was useful for automatic calibration of HSPF, and reduced numerous time and effort for model calibration, and improved model setup.
Kim, Jeong-Kon;Son, Kyong-Ho;Noh, Jun-Woo;Jang, Chang-Lae;Ko, Ick-Hwan
Journal of Korea Water Resources Association
/
v.39
no.10
s.171
/
pp.881-890
/
2006
Hydrological characteristics and urbanization effects in the Gap river catchment were investigated employing the SWAT model. The hydrological characteristics analysis showed that total runoff in the whole catchment from 2001 to 2004 consists of 44% of groundwater flow, 6% of lateral flow and 50% of surface flow under year 2000 landuse conditions. The analysis of urbanization effect using different landuse maps for year 1975 and 2000 indicated that although 5% increase in urbanized areas did not significantly impact on the total runoff in the whole catchment, a sub-basin where urbanized area increased by 32% over the past 30 years showed $68{\sim}73%$ decrease in groundwater flow and $22{\sim}66%$ increase in surface flow. It was found that urbanization decreased overall soil moisture and percolation rate except for some increase in soil moisture during dry season. Urbanization effect was found more sensitive during a dry year which has less rainfall and higher evapotranspiration than during a wet year. Therefore, from the results of this study we could infer increased flood damage during wet season and dried stream during dry season due to urbanization. To conclude, the results of this study can provide fundamental information to the eco-friendly restoration project for the three major rivers (Gap-cheon, Yudeung-cheon and Daejeon-cheon) in Daejeon Metropolitan City.
A mathematical model based on the water flow equation was developed with the Ohm's analogy and the partial differential equations. Simulation of water uptake was performed by numerically solving the equations with the aid of a differential equation solver, DGEAR in IMSL package, in FORTRAN version. The input data necessary were climatological parameters (temperature, solar radiation, humidity and wind speed). plant parametors (leaf water potential, leaf area, root conductivity and root length density) and soil parameters (hydraulic conductivity and The graphical comparison of the simulated and measured water contents as the functions of time showed good agreement, but there still was some disparity due to possible inacouracy of the field measured parameters. The simulated soil evaporation showed about 2 mm/day early in the growing period and dropped to about 0.4 mm/day as the full canopy developed and the soil water depleted. During the dry period, soil evaporation was as low as 0.1 mm/day. The transpiration was as high as 5mm/day. Deep percolation calculated from the flux between the 180-cm layer was about 0.2mm/day and became smaller with time. After the soil water of upper layers depleted, the flux reversed showing capillary rise. The rate of the capillary rise reached about 0.07mm/day, which was too low to satisfy water uptake of the root system. Therefore, to increase use of water in deep soil, expansion of the root system is necessary.
To provide a reliable tool for runoff simulations of ungauged watersheds upstream of reservoirs, a daily runoff simulation model, Tank model, is restructured, the parameter regionalization of the model is conducted, and the model's applicability is evaluated. Taking into account the characteristics of runoffs from the watersheds, a three-tank model is employed. The percolation process of the model's third tank is eliminated, considering the water budgets of the watersheds, and its evapotranspiration component is improved, reflecting the conditions of meteorological observation in South Korea. The sensitivity analysis of the model shows that the model's behaviors, varying with a sensitive parameter, ${\alpha}$, are reasonable. The regional parameter estimation equations are determined, using the characteristics and land uses of the watersheds as variables. The model is applied for the runoff simulations of three watersheds and the water stage simulation of one reservoir, and the simulation results are then compared with the observed values, which prove to be in close agreement with the observations. In addition, the results from simulating inflows of twenty-four reservoirs using the model show that the averages of evapotranspiration rate and runoff rate are 42.8% and 56.6%, respectively, which are resonable. Consequently, it is concluded that the model is practically applicable to simulating runoffs from watersheds upstream of reservoirs, and simulated inflow data are useful for watershed management and reservoir planning, design, and operation.
Magazine of the Korean Society of Agricultural Engineers
/
v.8
no.2
/
pp.1193-1199
/
1966
More stable and higher yields in rice paddy depend mainly upon an adequately balanced supply of water for higher yield. Rice paddy is supplied naturally by rainfall but inevitably requires artificial supplenental irrigation for higher yields. Even though it may be true that the water requirement of rice plants is generally higher than those of other crops, the submerged condition is not necessarily required for rice. The moisture requirements of rice vary according to its growing stages and it is possible to increse the irrigation efficiency by means of lessening the loss due to percolation and evapolation in the field. This experiment was conducted on the effect of the various amount of water supply and different irrigation periods for yield and yield components, and was carried out to find out the most suitable irrigation method and to increase the irrigation efficiency for higher yields in rice paddy. Randomized block design with 3 replications was employed where the 3 levels of the amount of irrigation water; (120% moisture contents), unirrigated (90~100%) and more un irrigated candition (80~90% moisture content), and levels of the various irrigation periods; usual, initial, intermediate and final periods, being treated. The results obtained in this experiment are as follows: 1. As for the physical and chemical and soil properfies, and other characteristics, there are no differences among the treatments enough to be effective for the growth of rice plants. 2. Culm length was measured after harvest as shown in table 2. 3. Difference of the amount of irrigation water did not change the culm length and ear length, however it also indicated more apparent increase in final treatment plots thatn that of usual. 3. No difference in the number of ears and number of ears pers per hill was founded treatments both in the difference of water supply and in the various irrigation periods. 4. There is no difference in the maturing rate and 1000 grains weight. 5. The number of panicles and grains and more increased in 80~100% moisture contents soil than those of 120%. and it shows in un irrigated plots, more irrigated plots and control plots in turn. Other wise according to the period\ulcorner of irrigation the trend is appeared in turn initial, usual, final and intermediate treatments.6. Yield as shown in table 7. 8 was more increased in unirrigated plots(90~IOO% moisture content) than the control plots (120% moisture content) by up to 8.2% and also 3. 2% in more unirrigated plots than that of control by periods is shown: usual plots final, initial, inter mediate treatment plots in turn. 7. The above resutts lead to the conclusion that no remarkable, differences in yields and soil properties are made by the unirrigation. However, it is apparent that this treatment has .some advantages in the points that one could spare the amount of water supply for irrigation with more increase in yield. In addition, a higher temperature and a brisk oxygen supply would be possible throug h this treatments. Accordingly, these treatment would be a more reasonable and economical cultivation method of rice for the better harvest.
This study was conducted to obtain quantitative data on the behavior of surface-applied urea to a paddy field which would help to protect against environmental pollution as well as to increase the efficiency of nitrogen fertilizer. The percolating water samples were collected with porous ceramic cups installed at 25, 50 and 75cm depths in a paddy field during the rice growing season(June 1992-September 1992) and analyzed for urea-N. NHAN and $NO_3-N$. In the paddy field to which urea fertilizer was applied at the rates of 12 and 24kg N/10a, the surface-applied urea was detected even at 75cm depth as the form of urea-N upto 12days after application. The maximum concentrations of urea-N in the percolating water sampled at 25, 50 and 75cm depths were the same irrespective of soil depth and the values were 0.06 and $0.12{\mu}g/m{\ell}$ for the application rates of 12 and 24kg N/10a respectively. The concentrations of $NH_4-N$ gradually decreased with time during the vegetative growth period : thereafter. the concentrations remained nearly constant. The maximum concentrations of $NH_4-N$ at 25cm depth were 1.2 and $5.6{\mu}g/m{\ell}$ for 12 and 24kg N/10a rate respectively. The $NO_3-N$ concentrations of percolating water ranged 0.1~0.5 and $0.2{\sim}0.5{\mu}g/m{\ell}$ for urea application rates of 12 and 24kg N/10a respectively. The nitrate concentration data suggest that nitrification process occurred continuously in paddy field during the rice growing season.
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