• 제목/요약/키워드: water impregnation

검색결과 137건 처리시간 0.025초

고해와 수침시간이 섬유의 팽윤과 종이 물성에 미치는 영향 (Effect of Beating and Water Impregnation on Fiber Swelling and Paper Properties)

  • 최은연;조병욱
    • 펄프종이기술
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    • 제45권6호
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    • pp.88-95
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    • 2013
  • Effects of beating and water immersion time on fiber swelling and paper properties were elucidated for the fundamental study of producing high bulk paper. Chemical pulps were beaten for various freeness and the beaten pulp was immersed in water up to 24 hours. Fiber swelling was evaluated by measuring water retention value (WRV). It was found that fiber swelling, bulk and paper strength were quickly changed at the initial stage of beating. Immersion in water did not significantly increase WRV, paper density and strength, implying that soaking in water alone could not effectively swell fiber wall. In order to swell further, hydrogen bonds between fibrils in fiber wall and hence fiber wall structure shall be broken by mechanical force during beating.

일단 WGS반응용 백금 담지 촉매 최적화 (Optimization of Supported Pt Catalysts for Single Stage Water Gas Shift Reaction)

  • 김기선;정대운;구기영;윤왕래;노현석
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.156.2-156.2
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    • 2011
  • 본 연구에서는 일단 수성가스전이반응 (Single stage water gas shift reaction)을 위해 높은 활성을 가진 백금 담지 촉매를 함침법 (Incipient wetness impregnation method)으로 제조하여 높은 공간 속도 (Gas hourly space velocity) $45,515h^{-1}$에서 담체에 따른 촉매 활성을 평가하였다. 담체는 $CeO_2$, $ZrO_2$, MgO, MgO-$Al_2O_3$ (MgO = 30 wt%) 그리고 $Al_2O_3$를 사용하였으며 백금의 담지량은 1 wt%로 고정하였다. BET, XRD, TPR, CO-chemisorption 분석을 통하여 담체의 구조적 특성이 촉매 활성에 미치는 영향에 대하여 조사하였다.

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치수안정화를 위한 목질재료의 고분자 하이브리드화에 관한 연구 (Study on the Hybridization of Polymer-macromers for the Dimensional Stabilization of Woody Materials)

  • 임기표;조종수;김익주;나은선
    • Journal of the Korean Wood Science and Technology
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    • 제23권4호
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    • pp.1-9
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    • 1995
  • This study was carried out to experiment the dimensional stabilization of woods of red pine (Pinus densiflora S. et Z.) and sugi(Cryptomeria japonica D. Don) by vacuum impregnation of polyehtylene glycols(PEG) with mo. wt. 200, 400, 600, 1000; polypropylene glycols (PPG) with mo. wt. 425,725 ; PEG-acryloylates, and PPG-acryloylates synthesized, and then by water soaking. The results obtained are as follows: 1. The density of sapwood and heartwood was different from each other in both species. 2. The PEG and PEG-macromers with lower molecular weight by impregnation has increased the density of wood specimens more higher, thereby caused their higher volume expansion, and those with higher molecular weight than 600 has tended to down their density increment. 3. Before and after water soaking, the density decrease of specimen impregnated was high in woods impregnated with simple PEG and PPG, while lower in specimens impregnated with PEG-macromers and PPG-macromers. 4. So PEG-macromer was expected to hold the original dimension of decayed wood for antiques, but it was necessary to develop another penetration method as well as aqueous solvent.

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함침-환원법으로 제조된 수전해용 Pt-SPE 전극촉매의 특성 (Characterizations of Pt-SPE Electrocatalysts Prepared by an Impregnation-Reduction Method for Water Electrolysis)

  • 장두영;장인영;권오환;김경언;황갑진;강안수
    • 한국수소및신에너지학회논문집
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    • 제17권4호
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    • pp.440-447
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    • 2006
  • Solid polymer electrolyte(SPE) membrane with electrodes embedded on both faces offer unique possibilities for the electrochemical cells like water electrolyzer with fuel cell. The Nafion 117 membrane was used as the SPE, and $Pt(NH_3)_4Cl_2$ and $NaBH_4$ as the electrocatalysts and reducing agent, respectively. The 'impregnation-reduction(I-R) method' has been investigated as a tool for the preparation of electrocatalysts for water electrolyzer by varying the concentration of reducing agent and reduction time at fixed concentration of platinum salt, 5 mmol/L. Pt-SPE electrocatalysts prepared by non-equilibrium I-R method showed the lowest cell voltage of 2.17 V at reduction time, 90 min and with concentration of reducing agent 0.8 mol/L and the cell voltage with those by equilibrium I-R method was 2.42 V at reduction time, 60 min and with concentration of reducing agent 0.8 mol/L. The cell voltage were obtained at a current density $1\;A/cm^2$ and $80^{\circ}C$. In water electrolysis, hydrogen production efficiency by Pt-SPE electrocatalyst is 68.2% in case of non-equilibrium I-R method and 61.2% at equilibrium I-R method.

New record of five Euplotes species(Protozoa, Ciliophora) collected from South Korea

  • Jeong Hyeon Yeo;Pablo Quintela-Alonso;Jae-Ho Jung
    • Journal of Species Research
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    • 제12권3호
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    • pp.203-211
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    • 2023
  • Five ciliate species of Euplotes were isolated from fresh and coastal water during a sampling survey to identify unrecorded ciliates in South Korea. Their morphology was investigated using live observation, protargol and "wet" silver nitrate staining methods. Brief descriptions and microphotographs of each species and a comparison with related species are provided. Euplotes focardii is characterized by an average size of 65×47 ㎛ after protargol impregnation, 6 dorsal and 3 ventral ridges and dorsal argyrome pattern of double-eurystomus type. Euplotes nobilii shows an average size of 34×20 ㎛ after protargol staining, 6 dorsal and 3 ventral ridges and dorsal argyrome pattern of double-patella type. Euplotes octocarinatus, the only freshwater species described in the present study, is characterized by an average size of 66×46 ㎛ after protargol impregnation, 6 dorsal and 3 ventral ridges and dorsal argyrome pattern of double-patella type. Euplotes petzi has an average size of 43×30 ㎛ after protargol staining, a macronucleus hook-shaped and dorsal argyrome pattern in double-patella type. Euplotes raikovi is characterized by an average size of 40×24 ㎛ after protargol staining, 6 dorsal and 3 ventral ridges and dorsal argyrome pattern of double-patella type.

A Fuel Feasibility Study of Sewage Sludge by Melting of Thermoplastic Polyethylene

  • Lee, Byeong-Kyu;Jeong, Wang-Seok
    • 한국환경과학회지
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    • 제19권1호
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    • pp.9-16
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    • 2010
  • This pilot study evaluated fueling feasibility of sewage sludge, which contains a large amount of water content, by applying melting of thermoplastic polyethylene (PE). This study has identified a simultaneous achievement of drying and heating value improvement of the sewage sludge. The sewage sludge collected from a sewage sludge treatment plant during a winter period had a water content of 83.7 wt%, a combustible volatile content of 12.5 wt%, and an ash content of 3.8 wt%. The higher heating value (HHV) of the dried sewage sludge, before impregnation or coating of PE, was 4,600 kcal/kg. The collected sewage sludge was immersed into the melted PE solution, which had a HHV of 11,070 kcal/kg, and kept immersing with increasing reaction time. As the reaction (immersing or coating or impregnation) time increased, the water content of the sludge decreased. However, the HHV of the sludge increased with increasing the reaction time. The HHVs of the sewage sludge immersed or dipped into the melted PE solution for 15 min ranged from 6,780 to 8,170 kcal/kg with water content less than 7 wt%. This result indicates the melted PE solution can be utilized as an improvement technology for dryness and heating value of the sewage sludge with high water content. The sewage sludge impregnated or coated with melted PE can be utilized as potential fuel or energy resources.

Improvement of Fast-Growing Wood Species Characteristics by MEG and Nano SiO2 Impregnation

  • DIRNA, Fitria Cita;RAHAYU, Istie;ZAINI, Lukmanul Hakim;DARMAWAN, Wayan;PRIHATINI, Esti
    • Journal of the Korean Wood Science and Technology
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    • 제48권1호
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    • pp.41-49
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    • 2020
  • Jabon (Anthocephalus cadamba) is a fast-growing wood species that is widely utilized for light construction and other purposes in Indonesia. The objectives of the current study were to determine the effects of monoethylene glycol (MEG) and SiO2 nanoparticles (nano SiO2) impregnation treatment on the dimensional stability and density of jabon wood and to identify the characteristics of impregnated jabon wood. Wood samples were immersed in water (as untreated), MEG, 0.5% MEGSiO2, then impregnated by applying 0.5 bar of vacuum for 60 min, and then applying 2.5 bar of pressure for 120 min. The results showed that impregnation with MEG and Nano SiO2 had a significant effect on the dimensional stability of jabon wood. Polymers can fill cell walls in wood indicated by increasing weight percentgain, antiswelling efficiency, bulking effect, and density, then decreasing in water uptake value. Jabon wood morphology by using SEM showed that MEGSiO2 polymers can cover part of the pitsin the wood vessel wall of jabon. This finding was reinforced by EDX results showing that the silicon content was increased due to the addition of SiO2 nano. The XRD diffraction pattern indicated that MEGSiO2 treatment increased the degree of crystallinity in wood samples. Overall, treatment with 0.5% MEGSiO2 led to the most improvement in the dimensional stability of 5-year-old jabon wood in this study.

인공수침 칠기를 이용한 고대칠기 보존연구 (Conservation of Excavated Lacquer-wares for using artificially water-soaked Lacquer-wares)

  • 김수철
    • 보존과학회지
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    • 제21권
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    • pp.49-58
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    • 2007
  • 고대칠기 보존처리를 모의시험하기 위하여 현생 칠기를 대상으로 다양한 보존처리법을 적용한 결과 PEG#3350 40%(수용액)처리가 수축률이 낮아 치수안정화 처리효과가 우수한 것으로 나타났다. Sucrose 19%+Glycerin 1%(t-butanol 5% in water)처리의 경우 지속적으로 중량이 증가되었다. 반면 Sucrose의 함침처리과정에서 시험편내부와 처리용액의 농도평형을 이루지 못하여 농도 차가 발생되므로 내부의 수분이 시험편 밖으로 나오는 탈수현상에 의해 중량이 감소하였다. 따라서 보다 긴 함침기간이 요구되는 것으로 판단되며 이는 장기간 함침처리로 탈수 현상을 방지할 수 있다. 또한 고분자량(PEG #3,350)의 처리제와 저분자량의 처리제 모두 칠기 내부로의 침투가 확인되어 진공 동결건조법뿐 만 아니라 각 처리제를 고농도로 함침 처리 한 후 자연건조 조습건조처리도 가능함을 보여주고 있다.

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양이온 교환 및 염 함침을 통한 메조다공성 실리카와 유기-금속 구조체의 수분 흡착 특성 조절 (Control of Water-Adsorption Properties of Mesoporous Silica and MOF by Ion Exchange and Salt Impregnation)

  • 이은경;조강희;김상겸;임종성;김종남
    • 청정기술
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    • 제24권1호
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    • pp.55-62
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    • 2018
  • $90^{\circ}C$ 이하의 저온열원 구동 수분 흡착식 냉방 시스템에 사용되는 흡착제는 효과적인 냉열 생산을 위해서 상대습도($P/P_0$) 0.1 ~ 0.3에서 높은 수분 흡-탈착량 차를 보이는 것이 좋다. 메조다공성 실리카(MCM-41)와 다공성 유기-금속 구조체(MIL-101) 의 경우 최대 수분 흡착량은 많지만 상대습도($P/P_0$) 0.1 ~ 0.3 구간에서 각각 $0.027{g_{water}\;g_{ads}}^{-1}$, $0.074{g_{water}\;g_{ads}}^{-1}$의 낮은 수분 흡-탈착량 차를 갖는다. 이 연구에서는 메조다공성 실리카와 다공성 유기-금속 구조체의 표면 성질을 조절하여 상대습도($P/P_0$) 0.1 ~ 0.3에서 수분 흡-탈착량 차를 증가시켰다. 주로 수분 흡착이 상대습도($P/P_0$) 0.5 ~ 0.7에서 일어나는 메조 다공성 실리카의 경우 알루미늄을 관능화 시킨 후에 염기도가 다른 여러 양이온($Na^+$, ${NH_4}^+$, $(C_2H_5)_4N^+$)들로 교환하거나 염($CaCl_2$)을 20 wt% 함침하여 각각의 흡착제들에 대해 $35^{\circ}C$에서 수분 흡착 등온선을 측정하였다. 양이온 교환 후 수분 흡착이 주로 일어나는 구간이 상대습도($P/P_0$) 0.5 부근으로 이동하였으나 여전히 상대습도($P/P_0$) 0.1 ~ 0.3에서 낮은 수분 흡-탈착량 차를 보였다. 하지만 흡습성을 갖는 염($CaCl_2$)을 20 wt% 함침한 메조다공성 실리카는 상대습도($P/P_0$) 0.1 ~ 0.3에서 수분 흡-탈착량 차가 $0.027{g_{water}\;g_{ads}}^{-1}$에서 $0.152{g_{water}\;g_{ads}}^{-1}$으로 증가하였다. 수분 흡착이 상대습도($P/P_0$) 0.3 ~ 0.5에서 주로 일어나는 다공성 유기-금속 구조체에도 염($CaCl_2$)을 20 wt% 함침하였더니 상대습도($P/P_0$) 0.1 ~ 0.3에서 수분 흡-탈착량 차가 $0.330{g_{water}\;g_{ads}}^{-1}$까지 증가하였다.

물유리와 이산화탄소로 가압함침한 가문비 나무의 연소특성 (Combustion Characteristics of Spruce Wood by Pressure Impregnation with Waterglass and Carbon Dioxide)

  • 박형주;이세명
    • 한국화재소방학회논문지
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    • 제26권4호
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    • pp.18-23
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    • 2012
  • 이산화탄소 주조법에서 사용되고 있는 방법을 응용하여 목질내에 규산겔과 탄산소다, 이산화규소가 석출된 목재를 제조한 후 외부 복사열원(20, 25, 35 및 50 $kW/m^2$)에 따른 점화시간, 점화온도, 질량감소속도, 임계열유속을 측정하였다. 연구결과, 물유리와 이산화탄소를 이용한 가압함침 처리된 목재는 Pre-Flashover 단계에서의 복사열원(20 $kW/m^2$ 이하)에서 난연성능이 있음을 확인할 수 있었다. 향후 지속적인 연구를 통해 우수한 배합비율을 찾는다면 난연목재로서의 활용가능성이 있다고 판단된다.