• Applied Chemistry for Engineering
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• v.35 no.1
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• pp.16-22
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• 2024

Polymer electrolyte membrane fuel cells have the advantage of low operating temperatures and fast startup and response characteristics compared to others. Simulation studies are actively researched because their cost and time benefits. In this study, the resistance of water residual in the gas diffusion layer (GDL) of the unit cell was added to the existing equation to compare the actual data with the model data. The experiments were conducted with a 25 cm² unit cell, and the samples were separated into stopping times of 0, 10, and 60 minutes following primary impedance measurement, activation, and polarization curve data acquisition. This gives 0, 10, and 60 minutes for the residual water in the GDL to evaporate. Without the rest period, the magnitude of the performance improvement was not significantly different at the same potential and flow rate, but the rest period did improve the performance of the membrane electrode assembly when measuring impedance. By changing the magnitude of the resistance reduction to an overvoltage, the voltage difference between the fuel cell model with and without residual water was compared, and the error rate in the high current density region, which is dominated by concentration losses, was reduced.

• Water for future
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• v.15 no.3
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• pp.49-55
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• 1982

The purpose of this study is to examine the methods of estimation, comparing U.S. SCS method and $\Phi$-index with effective rainfall. And also comparision was made among SCS method, Chow method and Mockus method as to the peak discharge of design storm hydrograph by small river basin. Hydrological data of the Shin river basin which was used in this study and the results of study are as follow; 1) As a result of applying the SCS method to determine the effective rainfall out of total rainfall, it turned out that the everage CN of the basin as obtained by the analysis of hydrologic soil-cover complex was varied as follows; AMC-I was 27.9%, AMC-II 16.4%, AMC-III 8.1% less than the value given by SC method using discharge measurement. 2) The comparision of effective rainfall by the ungaged SCS method with that of gauged $\Phi$-index method showed that the $\Phi$-index method showed that the $\Phi$-index method gives large value by 4.7% to those given by hydrograph. The result of analysis by the SCS method resulted in great difference from discharge measurement. 3) The comparision of SCS method, Chow method, and Mockus method showed that dimensionless hydrograph of SCS method and Chow method were close to the peak discharge of the gauged unit hydrograph, while the other methods gave far different results. 4) Attempts were made, for a better adaptation to the Shin river basin, to introduce lag time formula constant of dimensionless hydrograph of the SCS method by using the peak discharge of the gauged flow hydrograph.

• Journal of Environmental Science International
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• v.24 no.11
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• pp.1343-1362
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• 2015

As a result of analysis based on the observed data for BOD, COD and TOC in order to manage non-biodegradable organics in the Geumho River, COD/BOD ratio was analyzed as the occupying predominance proportion. In this study, the classification(changes in water quality measurement : increase, equal, decrease) and measurement of BOD and COD were analyzed for trends over the past 10 years from 2005 to 2014 in the Geumho River. The Geumho River is expected to need non-biodegradable organics management because BOD was found to be reduced 61.1% and COD was found to be increased 50%. As a result of the analysis of land use, the Geumho-A is a unit watershed area of $921.13km^2$, which is the most common area that is occupied by forests. The Geumho-B is a unit watershed area of $436.8km^2$, which is the area that is highest occupied by agriculture and grass of 24.84%. The Geumho-C is a unit watershed area of $704.56km^2$ accounted for 40.29% of the entire watershed, which is the area that is occupied by urban of 15.12%. Load of non-biodegradable organics, which is not easy biodegradable according to the discharge, appeared to be increased because flow coefficient of COD and TOC at the Geumho-B were estimated larger than 1 value. The management of non-point sources of agricultural land is required because the Geumho-B watershed area occupied by the high proportion of agriculture and field. In this segment it showed to increase the organics that biodegradation is difficult because the ratio of BOD and TOC was decreased rapidly from GR7 to GR8. Thus, countermeasures will be required for this.

• The Journal of Engineering Geology
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• v.23 no.2
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• pp.117-125
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• 2013

Flooding of riparian groundwater caused by changes in rainfall patterns has become a critical problem in areas of agricultural and arable land. Therefore, quantitative analysis of direct runoff and baseflow, which are the most important factors in determining the flow rate of a river, is required to clarify the flooding mechanisms of riparian groundwater. In this study, baseflow obtained using the WHAT system of hydrograph analysis based on Web GIS, and baseflow measured from direct runoff were quantitatively analyzed. Baseflow during the rainy season was 0.489 $m^3/s$ on 17 July 2012, 0.260 $m^3/s$ on 18 July 2012, and 0.279 $m^3/s$ on 19 July 2012, while that during the dry season was 0.006 $m^3/s$ on 6 March 2013 and 0.009 $m^3/s$ on 30 March 2013. The results show that an increase in baseflow occurred during the rainy season in the alluvial area of a riparian zone, and that the measurement error was less during the dry season than during the rainy season.

• Journal of the Korean GEO-environmental Society
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• v.17 no.3
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• pp.13-19
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• 2016

The ultrasonic waves for monitoring concrete materials have been used to investigate the setting and hardening process of concrete. This paper presents the application of bender elements for monitoring the hardening properties of Controlled Low Strength Material (CLSM) and the characterization of shear waves in CLSM according to curing time. To ensure the early age properties and flow, the CLSM consists of CSA cement, sand, silt, water, fly ash, and accelerator. In addition, three different type specimens according to fine contents are mixed. A couple of bender elements are installed at the wall of measurement cell and the CLSM specimen are prepared at the measurement cell for 28 days. Experimental results show that the resonant frequency and shear wave velocities increase with an increase in the curing time, regardless of the fine contents. Up to ten hours, the amplitudes of shear waves also increase, and the resonant frequency and shear wave velocities at the same time increase as the fine contents increase. The shear wave measurement technique using the bender elements may be effectively used to evaluate the hardening properties of CLSM along the curing time.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.660-667
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• 2017

Equilibrium data of the mixture is essential in the design and operation of separation equipment such as distillation or extraction in chemical processes. These equilibrium data can be obtained through experiments or by calculations using the known binary parameters and the thermodynamic models. Generally, to obtain these parameters, phase equilibrium experimental data such as gas-liquid and liquid-liquid are used. In this study, the excess enthalpy of the mixture was measured using the flow type microcalorimeter which is a simpler method than phase equilibria experiments, and the parameters of various theories were obtained by using this data. In order to investigate the relationship between carbon chain length, enthalpy and binary parameters in the alkane system, excess enthalpies for the n-hexane + alkane (n-pentane, n-heptane, n-octane and n-dodecane) were measured at 298.15 K and the banary interaction parameters of Wilson, NRTL, and UNIQUAC were obtained from the experimental data. In addition, we wanted to obtain basic information on the interaction and association phenomena of the system including electrolyte applicable to various fields by using the excess enthalpy experimental data and the existing theory. First, we investigated the excess enthalpy for the NaOH / Water / Ethanol system as a basic experiment and examined the applicability using the electrolyte-NRTL (eNRTL) theory.

• Journal of the Korean Society of Radiology
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• v.14 no.7
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• pp.857-862
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• 2020

In March 2011, a tsunami off Japan caused radioactive material that had seeped into the sea from the Fukushima nuclear accident to flow to the Pacific Ocean, causing pollution to sea life. For a comparative evaluation with the area surrounding the site of a nuclear power plant by the release of radioactive materials, an area 20 to 30 km away from the emergency protection plan area was selected as a comparative point considering weather conditions, population distribution, etc. In addition, the government intends to analyze the minimum detection radiation received by residents around the nuclear power plant and evaluate the effective dose. Analysis of tritium radiation from water samples showed that most of the samples were not detected and that 0.0014 % to 0.777 % of the annual legal standard of 1 mSv for the general public had little effect on the human body. Therefore, the measurement and analysis of water samples around the nuclear power plant site is expected to help relieve anxiety, such as exposure to the general public and neighboring residents due to radiation release.

• Nuclear Engineering and Technology
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• v.41 no.5
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• pp.655-676
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• 2009

The first-ever integral effect test for simulating a guillotine break of a DVI (Direct Vessel Injection) line of the APR1400 was carried out with the ATLAS (Advanced Thermal-hydraulic Test Loop for Accident Simulation) from the same prototypic pressure and temperature conditions as those of the APR1400. The major thermal hydraulic behaviors during a DVI line break accident were identified and investigated experimentally. A method for estimating the break flow based on a balance between the change in RCS inventory and the injection flow is proposed to overcome a direct break low measurement deficiency. A post-test calculation was performed with a best-estimate safety analysis code MARS 3.1 to examine its prediction capability and to identify any code deficiencies for the thermal hydraulic phenomena occurring during the DVI line break accidents. On the whole, the prediction of the MARS code shows a good agreement with the measured data. However, the code predicted a higher core level than did the data just before a loop seal clearing occurs, leading to no increase in the peak cladding temperature. The code also produced a more rapid decrease in the downcomer water level than was predicted by the data. These observable disagreements are thought to be caused by uncertainties in predicting countercurrent flow or condensation phenomena in a downcomer region. The present integral effect test data will be used to support the present conservative safety analysis methodology and to develop a new best-estimate safety analysis methodology for DVI line break accidents of the APR1400.

• Journal of the Korean Society of Food Science and Nutrition
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• v.33 no.1
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• pp.34-40
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• 2004

The purpose of this study was to measure the changes of regional cerebral blood flow (rCBF) and blood pressure (BP) in rats, following the intravenous injection of Schizandrae fructus water extract. The measurement was continually monitored by laser-doppler flowmeter and pressure tranducer in anesthetized adult Sprague-Dawley rats for 2 hours to 2 hours and a half through the data acquisition system composed of MacLab and Macintosh computer. The result of this experiment was as followed. Schizandrae fructus increased the changes of rCBF in rats significantly. The rCBF of Schizandrae fructus did not change by pretreated propranolol, atropine, L-NNA and indomethacin. But the rCBF of Schizandrae fructus was increased by pretreated methylene blue. Schizandrae fructus decreased the changes of BP, significantly. The BP of Schizandrae fructus did not change by pretreated propranolol, atropine, L-NNA and indomethacin. But the BP of Schizandrae fructus was decreased by pretreated methylene blue. There results indicated that Schizandrae fructus can increase the rCBF and decrease the BP, that is related to guanylyl cyclase activity.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.141-141
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• 2013

We have generated the needle-typed nonthermal plasma jet by using an Ar gas flow at atmospheric pressure. Diagnostics of electron temperature anddensity is critical factors in optimization of the atmospheric plasma jet source in accordance with the gas flow rate. We have investigated the electron temperature and density of plasma jet by selecting the four metastable Ar emission lines based on the atmospheric collisional radiative model and radial profile characteristics of current density, respectively. The averaged electron temperature and electron density for this plasma jet are found to be ~1.6 eV and ~$3.2{\times}10^{12}cm^{-3}$, respectively, in this experiment. The densities of OH radical species inside the various bio-solutions are found to be higher by about 4~9 times than those on the surface when the argon bioplasma jet has been bombarded onto the bio-solution surface. The densities of the OH radicalspecies inside the DI water, DMEM, and PBS are measured to be about $4.3{\times}10^{16}cm^{-3}$, $2.2{\times}10^{16}cm^{-3}$, and $2.1{\times}10^{16}cm^{-3}$, respectively, at 2 mm downstream from the surface under optimized Ar gas flow 250 sccm.