• Title/Summary/Keyword: water diffusivity

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Effect of binder composition on the stability of lipid oxidation and antioxidants of nut-sesame yeotgangjeong (Korean traditional candy bar) (결착제 조성이 견과-깨 엿강정의 저장 중 지방질 산화와 산화방지제 안정성에 미치는 영향)

  • Oh, Boyoung;Shin, Malshick;Choe, Eunok
    • Korean Journal of Food Science and Technology
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    • v.50 no.3
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    • pp.280-285
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    • 2018
  • Lipid oxidation and antioxidant stabilities of nut-sesame yeotgangjeong (Korean traditional candy bar) with different binders were evaluated during storage in the dark. S1, S2, and S3 binders consisted of starch syrup, sugar, and water (58:34:7.6, w/w/w); starch syrup, jocheong, honey, trehalose, and water (43.5:11.6:2.9:34:7.6, w/w/w/w/w); and starch syrup, jocheong, honey, sugar, trehalose, and water (43.5:11.6:2.9:17:17:7.6, w/w/w/w/w/w); respectively. Lipid oxidation was determined by peroxide and p-anisidine values, and tocopherol, lignan, and polyphenol contents were determined spectrophotometrically. Peroxide values were significantly higher (p<0.05) in yeotgangjeong samples with S2 or S3 binder than in those with S1; however, the converse was true for tocopherol degradation. Lignan was the most stable antioxidant in yeotgangjeong. The results suggest that tocopherols have a priority over lignans to control the lipid oxidation of yeotgangjeong during storage; reduced lipid oxidative stability after substituting sugar with trehalose might be because it increases oxygen diffusivity and inhibits the antioxidant action of tocopherols on lipids.

Effects of Moisture Content in Concrete on Diffuse Ultrasound (확산초음파의 콘크리트 함수율에 대한 의존성)

  • Ahn, Eunjong;Shin, Myoungsu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.142-147
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    • 2020
  • This study investigates the effects of moisture content on diffuse ultrasound to be applied for the evaluation of micro-structural damage in concrete subjected to various environmental conditions. We monitored diffuse wave parameters for concrete samples in process of water saturation for 5 days. Dried samples were immersed in a water bath, and the change of moisture content in concrete were estimated by measuring the change of mass. For the diffuse wave analysis, a frequency range of 500 kHz, which represents a scattering regime of ultrasound in concrete, was selected. The test results reveal that the ultrasonic diffusivity slightly changed, and the ultrasonic dissipation significantly increased by approximately 120% in the process of water saturation. Therefore, the moisture content in concrete should be considered for the evaluation of micro-structural damage using diffuse wave techniques.

Sorption and Migration Studies of Fission Products for Ground Waste Disposal

  • Lee, Sang-Hoon;Chun, Kwan-Sik;Yoon, Young-Ku
    • Nuclear Engineering and Technology
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    • v.10 no.3
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    • pp.153-163
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    • 1978
  • The problems of solid waste disposal into the ground in connection with environmental aspects in the vicinity of a site would be very significant, though ground disposal for solid waste is safe and economical method. Studies of the waste-movement and migration of radionuclides (Sr-90 and Cs-137) for the disposal into the ground were performed under laboratory and field conditions. Affinity of the soils for radionuclide solution was higher than that in the acid solution. The sorption of radionuclides by the soils showed a time-dependent reation. The migration rates of radiostrontium and radiocesium were a range of 3.73$\times$10$^{-3}$ to 10.9$\times$10$^{-3}$ cm/day. The nuclides in the soil migrate much more slowly than the water, probably due to its high exchange capacity. The observed distribution of tritium was compared with that calculated by a mathematical model based on diffusivity. This study suggests that the tritiated water can be used to trace the movement of ground water.

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A Numerical Model for the Freeze-Thaw Damages in Concrete Structures

  • Cho Tae-Jun
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.857-868
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    • 2005
  • This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

Ecological Model Experiments of the Spring Bloom at a Dumping Site in the Yellow Sea (생태계모델을 이용한 황해투기해역에서의 춘계 식물플랑크톤 대증식 연구)

  • Song, Kyu-Min;Lee, Sang-Ryong;Lee, Seok;Ahn, Yu-Hwan
    • Ocean and Polar Research
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    • v.29 no.3
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    • pp.217-231
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    • 2007
  • To explore limiting factors of spring bloom caused by waste disposal after dumping activity commenced in the Yellow Sea, we used a 1-dimensional temperature-ecological coupled model. The vertical structure of temperature and vertical diffusivity (Kh) are calculated by the temperature model with sea surface temperature using the 2.5 layers turbulence closure scheme. The ecological model applied results at the temperature model consisted of five state variables (DIN, DIP, phytoplankton, zooplankton, and detritus) forced by photosynthetically available radiation. We simulate year-to-year variations of plankton and nutrients using the coupled model from 1998 to 2000 and compare results of the model with observed data. It turned out that temperature is the growth factor of spring bloom in dumping area. During the winter the weak stratification made sufficient supply of the accumulated nutrients from the sea bed into the upper water column and led to the bloom in the coming spring. Radiation also turned out to be another important factor of spring bloom in the study area. Insufficient radiation of March 1999 showed low chlorophyll-a concentration despite sufficient nutrients in the surface.

Analytical Method for Moisture Vaporization of Concrete under High Temperature (고온조건에서 콘크리트의 수분증발 해석기법)

  • Lee, Tae-Gyu
    • The Journal of the Korea Contents Association
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    • v.17 no.7
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    • pp.538-545
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    • 2017
  • Moisture evaporates, when concrete is exposed to fire, not only at concrete surface but also at inside the concrete to adjust the equilibrium and transfer properties of moisture. The equilibrium properties of moisture are described by means of water vapor sorption isotherms, which illustrate the hysteretical behavior of materials. In this paper, the prediction method of the moisture distribution inside the concrete members at fire is presented. Finite element method is employed to facilitate the moisture diffusion analysis for any position of member. And the moisture diffusivity model of high strength concrete by high temperature is proposed. To demonstrate the validity of this numerical procedure, the prediction by the proposed algorithm is compared with the test result of other researcher. The proposed algorithm shows a good agreement with the experimental results including the vaporization effect inside the concrete.

Parameter estimation for identification on cause of drawdown around underground LPG storage cavern (지하 LPG저장공동 주변의 지하수위 강하 원인규명을 위한 파라미터추정)

  • Han, Il-Yeong;Lee, Dae-Hyuck;Lee, Jung-Eun;Jung, Kwang-Pil
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.76-80
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    • 1998
  • In order to identify the cause of ground water drawdown of a piezometer installed around the LPG storage cavern, parameter estimations were conducted by inverse and forward numerical models. An inverse model, SK-EST developed by SK Engineering & Construction Co., Ltd.(SKEC,1997) was performed to estimate the change of the hydraulic conductivity. It was verified by the commercial forward model, AQUA3D (VATNASKIL,1995). The simulation results showed that the hydraulic diffusivity of the rock mass between the piezometer and the cavern had been increased and the change rate of the hydraulic head had been abruptly increased in response to the change of the operation pressure. Finally the statistical analysis for observed data showed the increase of the change rate of the hydraulic head and thus proved the applicability of SK-EST.

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The Effect Of Stability On The Intensity Of Vertical Turbulent Diffusion In The Western Channel Of The Korea Strait

  • Chung, Jong Yul
    • 한국해양학회지
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    • v.12 no.1
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    • pp.7-12
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    • 1977
  • Vertical mixing in the ocean affects the formation of water masses as well as the vertical distribution of nutrients and dissolved substances. this study is to investigate the effect of stability on the intensity of vertical transfer in the case of shallow and straitfied channel. It is found that the relation of the stability and vertical turbulent diffusion is given by K$\sub$z/ = -${\beta}$-(c+${\beta}$) / ${\alpha}$(E-1/${\alpha}$) where K$\sub$z/ and E denotes the vertical turbulent diffusion coefficient and stability, respectively. The empirical coefficients ${\alpha}$, ${\beta}$ and c depend on the magnitude of vertical components and stability, i.e., through thermocline intensity. The study indicates that the diffusivity of the surface mixed layer is (K$\sub$z/)=300∼1,200$\textrm{cm}^2$/sec, the thermocline layer is (K$\sub$z/)= 50∼200$\textrm{cm}^2$/sec and the cold layer is (K$\sub$z/)=200∼600$\textrm{cm}^2$/sec based on near- minimum least-squares error estimates from the regression analysis. An important result of our study comes out that the model is in accordance with the general trends of the effect of stability on the vertical turbulent diffusion coefficients in the case of shallow and strongly stratified channel.

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Residence Time Distributions of Liquid pbase Flow and Mass Transfers in the Trickle Bed Reactor (점적상 반응기에서 액상흐름의 체류시간 분포 및 물질전달)

  • Kim, Ki-Chang
    • Journal of Industrial Technology
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    • v.6
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    • pp.19-31
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    • 1986
  • The residence time distribution of liquid flow in a 4.0cm diameter column packed with porous $Al_2O_3$ spheres of 0.37cm diameter were measured with pulse injections of a tracer under cocurrent trickling flow conditions. The mean residence time of liquid flow and liquid hold-up calculated by the transient curve of tracer were unaffected by gas flow rates under experimental ranges of liquid flow rates from 2.4 to $4.5(kg/m^2\;sec)$ and gas flow rates from 0 to $0.13(kg/m^2\;sec)$. The axial dispersion coefficient of liquid stream and apparent diffusivity of tracer in a micropore of solid particle were estimated from the response curve of tracer. The calculated Peclet No. were increased in ranges of 68-to 82 with a increasing of liquid mass velocity, and the external effective contacting efficiency between liquid and solid which can be expressed. by $(D_i)_{app}/D_i$ varied in ranges of 0.54 to 0.68 depending on the liquid flow rates. The gas to liquid(water) volumetric mass transfer coefficient were determined from desorption experiments with oxygen at $25^{\circ}C$ and 1 atm. The measured mass transfer coefficients were increased with liquid flow rates and the effect of gas flow rates on the mass transfer coefficient was insignificant.

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Parameter Estimation of Perillyl Alcohol in RP-HPLC by Moment Analysis

  • Row Kyung Ho;Lee Chong Ho;Kang Ji Hoon
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.16-20
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    • 2002
  • Parameter estimations were made for the reversed-phase adsorption of perillyl alcohol (POH), a potent anti-cancer agent, on octadecylsilyl-silica gel (ODS). The average particle diameter of ODS was about $15\;{\mu}m$, and the particles were packed in the column $(3.9\;\times\;300mm)$. The mobile phase used was a mixture of acetonitrile and water, in which the acetonitrile ranged between 50 and $70\;(v/v\;\%)$. The first absolute moment and the second central moment were determined from the chromatographic elution curves by moment analysis. Experiments were carried out using POH solutions within the linear adsorption range. The fluid-to-particle mass transfer coefficient was estimated using the Wilson-Geankoplis equation. The axial dispersion coefficient and the intra particle diffusivity were determined from the slope and intercept of a plot of H vs $1/u_0$, respectively. The contributions of each mass-transfer step were axial dispersion, fluid-to-particle mass transfer, and intraparticle diffusion.