• Journal of the Korean institute of surface engineering
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• v.44 no.2
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• pp.50-54
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• 2011

Hydrophobic a-C:F film was coated on polycarbonate film with $CF_4$, $C_2F_6$ and HFC ($C_2F_4H_2$) gas in helium discharge generated by 5~100 kHz AC power supply at atmospheric pressure and room temperature. The highest water contact angle of the a-C:F film formed with $He/C_2F_6$ mixed gas is $155^{\circ}$. X-ray photoelectron spectrum showed that there was 40% of C-$CF_3$ bond at the surface of the super hydrophobic film. The contact angle and deposition rate were decreased with increasing substrate temperature. The contact angle was generally increased with the surface roughness of the film. The contact angle was high when the surface microstructure of the film was fine and sharp at the similar roughness and chemical composition of the surface.

• Laser Solutions
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• v.13 no.3
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• pp.13-18
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• 2010

In this paper, polyimide (PI) surface was modified by UV Laser with a low laser fluence and investigated changes of surface geometry and chemical characteristics by SEM (scanning electron microscope), X-ray diffraction (XRD), XPS (x-ray photoelectron spectroscopy) and the measurements of contact angle of water. PI surface was peeled off and modified with microstructure fabrications by photochemical ablation over the laser fluence of 50 mJ/cm2. As laser fluence increased, delamination of PI surface was occurred largely and strongly. In chemical characteristics, the O/C and N/C atomic ratios increased and contact angle decreased from $80^{\circ}$ to $40^{\circ}$.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.18 no.8
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• pp.38-43
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• 2019

Electrowetting on dielectric (EWOD) is a unique method of shape control of small-volume droplets in microfluidic biochips that relies on modification of surface wetting characteristics using electrical methods. In this study, the droplet shape control on various dielectric surfaces by the EWOD and the effect of droplets on the contact angle as well as the shape were investigated. The droplet used in the experiment was on a sample substrate with $5{\mu}l$ of de-ionized water (DIW) using a micropipette, and wettability was measured with a contact angle meter. This study is expected to be helpful for the development of various micro-total-analysis-systems (${\mu}TAS$) and microfluidic systems with MEMS technology.

• Journal of the Korean Society of Clothing and Textiles
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• v.29 no.3_4 s.141
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• pp.561-568
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• 2005

The irradiation of Ultra-Violet (UV) is an efficient treatment for polymer to improve hydrophilic properties. 4-Channel PET knit fabrics were treated with UVA and UVC to develop functional and environment-friendly fabric. The fabric was treated with various treatment times and distances from UV lamps having different wavelength. FT-IR and XPS investigated the chemical changes. To confirm the change of surface properties, contact angle, surface energy and SEM were examined. The study of UV as a treatment for PET knit fabric shows significant changes in chemical and surface properties, which is proved by analyses. FT-IR and XPS analyses prove the augmentation of carboxylic, Hydrophilic groups on the surfaces treated by UV. The increase of water contact angle and surface energy means more water wettable and surface energy of PET film was substantially increased by UV irradiation time. The ageing after surface treatment had little influence on the surface energy of the irradiated PET film. SEM proves the surface modification of PET such as etching, bubble and crack. The negative effects are increased in accordance with increasing treatment time.

• Journal of the Korean Society for Precision Engineering
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• v.26 no.12
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• pp.117-122
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• 2009

The hexagonal network-type PDMS microstructures were fabricated and they were employed to low-friction drag surfaces. While the lowest contact angle measured from the smooth surface was $108^{\circ}$ the highest contact angle measured from the microstructured surfaces was $145^{\circ}$ The moving speed of bullet-type capsule attached with a PDMS pad of smooth surface ($CA=108^{\circ}$) was 0.1261 m/s and that with a PDMS pad of microstructured surface ($CA=145^{\circ}$) was 0.1464 m/s. Compared with the smooth surface, the microstructured surface showed 16.1% higher moving speed. The network-type microstructures have a composite surface that is composed with air and PDMS solid. Therefore, the surface does not wet: rather water is lifted by the microstructures. Because of the composite surface, water shows slip-flow on the microstructures, and thus friction drag can be reduced.

• KSBB Journal
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• v.13 no.2
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• pp.209-213
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• 1998

The characteristics of de-emulsification of pertroleum emulsion by Nocardia amarae were investigated. Insoluble medium containing n-hexadecane was more effective than soluble medium in de-emulsification of emulsion containing diesel and bunker C as the organic phase. Emulsion made by the addition of xanthan or bioemulsifier was de-emulsified by N. amarae, and longer culture age was effective. In low viscosity range, organic phase with longer carbon chain was more effective. The contact, angle between bacterial film and water droplet in air increased from 16 degree for 4 day culture age to 26 degree for 15 day. The contact angle between bacterial film and water droplet in kerosene, n-heyxane or n-hexadecane also increased to greater than 100 degree after 3 day culture age. The hydrophobicity of bactgerial film increased according to the culture age.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.4
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• pp.424-431
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• 2003

The evaporation cooling phenomenon of a droplet containing a surfactant on a heated surface has been studied experimentally. The two kinds of heater modules made of brass and Teflon$^{TM}$ were tested to investigate the cooling characteristics of droplet. Solutions of water containing Sodium Lauryl Sulfate(0 ppm, 100 ppm, 1000 ppm) were tested in the experiments. The results showed that the contact angle decrease as the concentration of surfactant increases. The tendency did not very with different heated solid materials. As initial temperature of the heated surface becomes high, time averaged heat flux increases and evaporation time decreases with the denser concentration of surfactant. Therefore, water with denser concentration of surfactant could be effective to cool flammable materials. However, the effect of surfactant becomes low as the material temperature is higher than the boiling temperature of water.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.448-448
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• 2011

We investigated the fabrication method of superhydrophobic nanocoating prepared by a simple spin-coating and the chemisorption of fatty acid. The resulting coating showed a tremendous water repellency (static water contact angle = $154^{\circ}$) and the water contact angle can be modulated by changing the number of deposition cycles of ZnO and the carbon length of Self-Assembled Monolayers (SAM). Varying the number of deposition cycles of ZnO controlled the surface roughness, and affected to the superhydrophobicity. This simple coating method can be universally applicable to any substrates including flexible surfaces, papers and cotton fabrics, which can effectively be used in various potential applications. We also observed the thermal and dynamic stabilities of SAM on ZnO nanoparticles. The superhydrophobicic surface maintained its superhydrophobic properties below $250^{\circ}C$ and under dynamic conditions.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2390-2395
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• 2008

The water droplet motion in an air flow microchannel with pores through which water emerges is studied numerically by solving the equations governing the conservation of mass and momentum. The gas-liquid interface is tracked by a level set method which is based on a sharp-interface representation for accurately imposing the matching conditions at the interface and is modified to implement the contact angle conditions on the wall and pores. The numerical results show that the droplet growth and detachment pattern depend significantly on the contact angle and inlet air velocity. Also, the dynamic interaction between the droplets growing on multiple pores is investigated. The pore arrangement subject to droplet merging is found to be not effective for water removal.

• Applied Chemistry for Engineering
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• v.21 no.1
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• pp.98-103
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• 2010

The effect of plasma treatment on surface characteristics of polycarbonate (PC) films was investigated using low pressure plasma and atmospheric pressure plasma with oxygen and argon. Untreated PC has a contact angle of $82.31^{\circ}$ with de-ionized water which reduced to $9.17^{\circ}$ as the lowest value after being treated with a low pressure plasma treatment with oxygen. Increase of delivered powers such as RF and AC with a high frequency and gas flow rates was not effective to reduce contact angles dramatically but gave the trend of reducing gradually. The surface of PC treated with plasma shows a low contact angle but the contact angle increases rapidly according to the exposure time in air ambient. Oxygen plasma was more effective to generate the polar functional group regardless of the type of plasma. Conclusively, a low plasma treatment with oxygen is more recommendable when the hydrophilic surface of PC is required.