• 한국농림기상학회지
• /
• 제1권2호
• /
• pp.110-118
• /
• 1999

This experiment was conducted to characterize the vertical transport trend of dissolved elements through throughfall, stemflow, effluent from Ao layer, and leachate out of soil profile on Pinus koraiensis stand in Experimental Forest of Kyunghee University, located in Kwangju, Kyunggi province for 12 months from July, 1998 to Jun, 1999. In addition, we investigated the content of dissolved elements and the factors influencing the water chemistry concentrations separately collected from the field. Water movement in the process of throughfall and stemflow from precipitation, and rainfall leached from Ao layer into soil water was governed by concentration of through fall, precipitation, rainfall intensity, seasonal variation, and other factors. Also, smaller changes of pH in soil water than that of dissolved elements in soil water could contribute buffer capacity, as well as balancing the concentration between cations and anions.

• Corrosion Science and Technology
• /
• 제12권6호
• /
• pp.280-287
• /
• 2013

Flow accelerated corrosion(FAC) of the carbon steel piping in pressurized water reactors(PWRs) has been major issue in nuclear industry. Severe accident at Surry Unit 2 in 1986 initiated the worldwide interest in this area. Major parameters influencing FAC are material composition, microstructure, water chemistry, and hydrodynamics. Qualitative behaviors of FAC have been well understood but quantitative data about FAC have not been published for proprietary reason. In order to minimize the FAC in PWRs, the optimal method is to control water chemistry factors. Chemistry factors influencing FAC such as pH, corrosion potential, and hydrazine contents were reviewed in this paper. FAC rate decreased with pH up to 10 because magnetite solubility decreased with pH. Corrosion potential is generally controlled dissolved oxygen (DO) and hydrazine in secondary water. DO increased corrosion potential. FAC rate decreased with DO by stabilizing magnetite at low DO concentration or by formation of hematite at high DO concentration. Even though hydrazine is generally used to remove DO, hydrazine itself thermally decomposed to ammonia, nitrogen, and hydrogen raising pH. Hydrazine could react with iron and increased FAC rate. Effect of hydrazine on FAC is rather complex and should be careful in FAC analysis. FAC could be managed by adequate combination of pH, corrosion potential, and hydrazine.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
• /
• pp.405-407
• /
• 2005

To evaluate the main hydrogeochemical characteristics, river waters are investigated using element리 and isotopic compositions in South Korea. In this area, the chemical compositions are mostly classified into three groups; $Ca^{2+}-{HCO_3}^-$ type, $Ca^{2+}-Cl^{-}-{NO_3}^-$ type and $Ca^{2+}-{HCO_3}^{-}-Cl^{-}-{NO_3}^-$ type. These types are affected by two major factors: water-rock interaction and anthropogenic inputs such as sewage and fertilizers. Based on the values of ${\delta}^{18}O$ and ${\delta}D$, most of waters are originated from precipitation except two samples contaminated. The lithology and geography of basins mainly control the water chemistry. Elemental and isotopic compositions show that water chemistry are mainly controlled by three end members, especially by carbonate dissolution, and suggest that anthropogenic input affect the water chemistry. Also, three weathering sources are identified: silicates, dolomite and limestone.

• Bulletin of the Korean Chemical Society
• /
• 제6권1호
• /
• pp.33-36
• /
• 1985

The luminescence intensity of $Tb^{3+}$ bound to picolinic acid, squaric acid, and 2,3-pyrazinedicarboxylic acid has been studied in water and water-ethanol mixtures. It has been found that the emission intensity of $Tb^{3+}$ in the complexes is enhanced with the increase of ethanol content in water-ethanol mixtures. Several factors affecting on the emission intensity of $Tb^{3+}$ in waterethanol mixtures are discussed.

• Corrosion Science and Technology
• /
• 제7권2호
• /
• pp.85-91
• /
• 2008

By operation in aqueous environment at high temperature and pressure, the structural materials from Primary Heat Transport System (PHTS) cover with protective oxide films, which maintain the corrosion rate in admissible limits. A lot of potential factors exist, which conduct to degradation of the protective films and consequently to intensification of the corrosion processes. The existing experience of different nuclear reactors shows that the water chemistry has an important role in integrity maintaining of the protective oxide films. To investigate the influence of water chemistry (pH, O2 dissolved, $Cl^-$, $F^-$) on corrosion of some structural materials (carbon and martensitic steel, Zr and Ni alloys) and to establish the maximum permissible values, corrosion experiments by static autoclaving and electrochemical methods were performed. The experimental results allowed us to establish the contribution of the water chemistry in initiation and evolution of some accelerated corrosion processes.

• 한국지구과학회지
• /
• 제42권5호
• /
• pp.556-570
• /
• 2021

This study presents the data analysis results of groundwater chemistry and the occurrence of fluoride in groundwater obtained from the groundwater quality monitoring network of Korea. The groundwater data were collected from the National Groundwater Information Center and censored for erratic values and charge balance (±10%). From the geochemical graphs and various ionic ratios, it was observed that the Ca-HCO₃ type was predominant in Korean groundwater. In addition, water-rock interaction was identified as a key chemical process controlling groundwater chemistry, while precipitation and evaporation were found to be less important. According to a non-parametric trend test, at p=0.05, the concentration of fluoride in groundwater did not increase significantly and only 4.3% of the total groundwater exceeded the Korean drinking water standard of 1.5 mg/L. However, student t-tests revealed that the fluoride concentrations were closely associated with the lithologies of tuff, granite porphyry, and metamorphic rocks showing distinctively high levels. This study enhances our understanding of groundwater chemical composition and major controlling factors of fluoride occurrence and distribution in Korean groundwater.

• Membrane and Water Treatment
• /
• 제10권6호
• /
• pp.417-429
• /
• 2019

Poly Sulfone nanofibers were electrospun to fabricate membranes of different characteristics. To fabricate the fiber mats, polymer concentration, flowrate, and current density were determined as the most influencing factors affecting the overall performance of the membranes and studied through Response Surface Methodology. The Box-Behnken Design method (three factors at three levels) was used to design, analyze, and optimize the parameters to achieve the best possible performance of the electrospun membranes in forward osmosis process. Also, internal concentration polarization that characterizes the efficiency of the forward osmosis membranes was determined to better assess the overall performance of the fabricated electrospun membranes. Water flux to reverse salt flux was considered as the main response to assess the performance of the membranes. As confirmed experimentally, best membrane performance with the minimal structural parameter value could be achieved when predicted optimal values were used to fabricate the membranes through electrospinning process.

• Corrosion Science and Technology
• /
• 제8권3호
• /
• pp.126-131
• /
• 2009

The interaction between wear and corrosion can significantly increase total material losses in water chemistry environment. The corrosive wear tests of a PWR steam generator tube material (Alloy 690) against the anti vibration bar material (409 SS) were performed at room temperature. The tests were performed in alkaline water chemistry conditions. NaOH solution was selected for test condition to investigate the corrosive wear effect of steam generator tube material in alkaline pH condition without other factors. The flow induced vibration can caused tube damage and the corrosion can be occurred by water chemistry. The test results showed that, in the alkaline solution at pH 13.9, the corrosion current density was increased about ten times than that in the distilled water. And wear rate at pH 13.9 was increased about ten times from that at neutral condition. However, the wear rate was decreased with time. The decrease would be attributed to the change in roughness of specimen or sub-layer of the worn surface with time. From microstructure observation, severe abrasive shape and several wear debris were found. From those results, it could infer that the oxide film on Alloy 690 changed to easily breakable one in the alkaline water, and then abrasion with corrosion became the main wear mechanism.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
• /
• pp.450-452
• /
• 2004

Using factor analysis and bivariate comparisons of major components in ground water, three geochemical processes were identified as controlling factors of ground water chemistry; 1) natural mineralization by water rock interactions, 2) effect of seawater which includes salinization by seawater near seashores and deposition of sea salt, and 3) nitrate contamination by N fertilization. Contribution of rainfall was also estimated from the measured composition of wet deposition. The geochemical processes were separated using total alkalinity as an indicator for natural mineralization, Cl for effect of seawater, and nitrate for N fertilization. Relatively high correlation of major components with nitrate suggests that nitrification of nitrogenous fertilizers significantly affects ground water chemistry. Total cations derived from nitrate sources have good linearity for nitrate in equivalent basis with a slope of 1.8, which is a mean of proton production coefficients in nitrification of two major compounds in nitrogenous fertilizers, ammonium and urea. Contribution of nitrate sources to base cations, Cl, and SO$_4$ in ground water was determined considering maximum contribution of natural mineralization to estimate a threshold of the effect of N fertilization for ground water chemistry, which shows W fertilization has a greatest effect than any other processes in ground water with nitrate concentration greater than 50 mg/L for Ca, Mg, Na and with concentration greater than 30 mg/L for Cl and SO$_4$.

• Bulletin of the Korean Chemical Society
• /
• 제12권2호
• /
• pp.214-219
• /
• 1991

To study the effect of solvents and counterions in Z-DNA crystal of d(5BrC-G-5BrC-G-5BrC-G), we performed the local energy analysis and then molecular dynamics simulations. Since counterions raise serious caging problems in crystal simulations, it is very important to search for the possible positions before simulations. For this purpose, the local energy analysis was done for the whole crystal volume. It is shown from our simulation that counterions along with water molecules play a bridging role to bind adjacent oligomers so as to form the crystal. In this crystal, each water molecule bound to Gua-N2H, either directly or indirectly, hydrates the adjacent anionic phosphate oxygen, and thus assists Gua to be in a syn position. From the simulation, the average root-mean-square deviation of allthe DNA heavy atom coordinates from the X-ray data is $0.99{\AA}$ . The bases are less deviated from the X-ray positions than the phosphates. The temperature factors from the simulation are consistent with those from the X-ray refinement, showing that the phosphates are more mobile than the bases.