• Journal of Environmental Health Sciences
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• v.41 no.2
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• pp.90-101
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• 2015

Objective: This study was conducted to develop a chemical oxygen demand (COD) regression model using water quality monitoring data (January, 2014) obtained from the Han River auto-monitoring stations. Methods: Surface water quality data at 198 sampling stations along the six major areas were assembled and analyzed to determine the spatial distribution and clustering of monitoring stations based on 18 WQPs and regression modeling using selected parameters. Statistical techniques, including combined genetic algorithm-multiple linear regression (GA-MLR), cluster analysis (CA) and principal component analysis (PCA) were used to build a COD model using water quality data. Results: A best GA-MLR model facilitated computing the WQPs for a 5-descriptor COD model with satisfactory statistical results ($r^2=92.64$,$Q{^2}_{LOO}=91.45$,$Q{^2}_{Ext}=88.17$). This approach includes variable selection of the WQPs in order to find the most important factors affecting water quality. Additionally, ordination techniques like PCA and CA were used to classify monitoring stations. The biplot based on the first two principal components (PCs) of the PCA model identified three distinct groups of stations, but also differs with respect to the correlation with WQPs, which enables better interpretation of the water quality characteristics at particular stations as of January 2014. Conclusion: This data analysis procedure appears to provide an efficient means of modelling water quality by interpreting and defining its most essential variables, such as TOC and BOD. The water parameters selected in a COD model as most important in contributing to environmental health and water pollution can be utilized for the application of water quality management strategies. At present, the river is under threat of anthropogenic disturbances during festival periods, especially at upstream areas.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.119-122
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• 1998

Chemical analysis, measurement of pumping rates of 60 production wells and depth to water tables of 57 monitoring wells were carried to protect depletion of water resources and deterioration of water quality for the commercial portable ground-water. Borehole depth of production well averages 149m(31 boreholes), casing depth is 28m(29 boreholes), production rate is 70 $m^3$/day and depth to water table of monitoring well is 23.26m, respectively. The geology of 60 wells can be divided into Daebo granite(20), Okchun metarmorphic complex(18), Precambrian granitic gneiss(15), Bulguksa granite(4), Cheju volcanics(2), Cretaceous sedimentary rock(1). Average electrical conductivity and pH are 152$\mu$S/cm, and 7.35, respectively. The contents of major cation and anion predominantly $Ca^{2+}$>N $a^{+}$>M $g^{2+}$> $K^{+}$ and HC $O_{3}$$^{－}$ >S $O_{4}$$^{2-}$>Cl￣>F￣. Water type is predominantly $Ca^{2+}$-HC $O_{3}$$^{－}$(81.7%). It's possible that water chemistry of some wells were affected not only by the geology of boreholes penetrated but by inflows of surface water or shallow ground-water. Therefore, it is strongly necessary to steadily monitor the water quality and hydrogeologic conditins of production wells.ells.ls.ells.

• Magazine of the Korean Society of Agricultural Engineers
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• v.44 no.4
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• pp.139-148
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• 2002

Pilot study was performed to examine the feasibility of the pond system for further polishing of treatment wetland effluent from December 2000 to June 2001. The wetland system used for the experiment was highly effective to treat the sewage during the growing season, but it was less effective and its effluent was still high to discharge to the receiving water body. Therefore, the wetland effluent may need further treatment to prevent water quality degradation. Pond system could be used to hold and further polish the wetland effluent during the winter season and ots feasibility was evaluated in this study. Additional water quality improvement was apparent in the pond system during winter season, and the pond effluent could be good enough to meet the effluent water quality standards if it is properly managed. Timing of the pond effluent discharge appears to be critical for pond system management because it is a closed system and whole water quality constituents are affected by physical, chemical, and biological pond environments. Once algae started to grow in mid-April, constituents in the pond water column interact each other actively and its control becomes more complicated. Therefore, upper layer of the pond water column which is clearer than the lower layer my need be discharged in March right after ice cover melted. In the experiment, water quality of the upper water column was markedly clear in March than ant other times probably because of freezing-thawing effect. The remaining lower water column could be further treated by natural purification as temperature goes up or diluted with better quality of wetland effluent for appropriate water uses. This study demonstrated the feasibility of pond system for subsequent management of wetland effluent during the winter season, however, more study is needed for field application.

• KEPCO Journal on Electric Power and Energy
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• v.4 no.1
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• pp.39-45
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• 2018

Ammonia Adsorbed Fly Ash (AAFA) samples produced from coal fired plants equipped with SNCR (Selective Non-Catalytic Reduction) of nitrogen oxides with urea have been chemically analyzed, and their physical and dissolution properties have been investigated. XRD results for the ammonia component in AAFA ascertained that ABS (ammonium bisulfate) and AS (ammonium sulfate) were deposited on fly ash as $SO_3$ reacted with unreacted ammonia at SNCR. SEM and EDS images showed that fine ashes on large fly ash surface of sphere type were agglomerated, due to adhesive role of ammonium salts attached fly ashes. Dissolution test results of ammonium salts absorbed on AAFA in distilled water or sea water showed that the proportion of un-ionized $NH_3$ to $NH_4{^+}$ were primarily a function of pH and temperature. Increasing pH and temperature causes an increase in the fraction of un-ionized $NH_3$. At pHs of 9.6 and 10.7, un-ionized $NH_3$ and $NH_4{^+}$ ions are present in equal amounts at distilled water and sea water, respectively.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.5
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• pp.984-989
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• 2011

Electrical insulation is one of the most important part in a high voltage apparatus. Recently, researchers are interested in the environmental friendly vegetable oil from environmental viewpoint. Accelerated aging transformer insulating material in vegetable oil was compared to that of mineral oil. Accelerated aging oil samples produced in the oven at $140^{\circ}C$ for 500, 1000, 1500, 2000hours. And Real transformer insulation oils samples of vegetable oil and mineral oil were aged by thermal cycles repeating from $30^{\circ}C$ to $120^{\circ}C$. Samples were analyzed at 42, 63, 93, 143, 190, 240, 300 cycles. The mineral and vegetable insulating oils were investigated for breakdown voltage, water content, total acid number, viscosity, volume resistivity, insulating paper and oil permittivity, and dissolved gas analyses. The breakdown voltage of the vegetable insulating oil is higher than that found for the mineral oil; the accelerated aging progress decreased the breakdown voltage. The vegetable oil had a higher water saturation than the mineral oil; the vegetable oil has the superior water characteristics and breakdown voltage. And high viscosity of vegetable oil, care has to be taken, especially when designing the cooling system for a large transformer.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.2
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• pp.99-110
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• 2005

Characteristics of concentrations of total nitrogen (TN), total phosphorus (TP), and chemical oxygen demand (COD) pollutant in percolated water at four paddy field sites (Soro, Odong, Munui, and Boeun) were investigated by a nonparametric test. Percolation rate measurement and percolated water sampling were taken during irrigation periods at $5{\sim}10$ day intervals. The normality of percolation rate and pollutant concentrations were examined using histogram, boxplot, and the Kolmogorov-Smirnov (K-S) test. Pollutant concentrations in percolated water showed positively skewed distribution. The median concentrations of pollutant were 1.91 mg/L for TN, 0.021 mg/L for TP, and 6.6 mg/L for COD, which were lower than its arithmetic mean concentrations by $35\%$ for TN, $36\%$ for TP, and $13\%$ for COD. The median concentrations of TN and TP differed significantly among sample sites according to the Kruskal-Wallis test. However, median concentrations were not significantly different among month except for TN and TP of Soro and COD of Odong. The percolation load of pollutants during irrigation periods in the study area were estimated at $3.12{\sim}7.75\;kg/ha$ for TN, $0.033{\sim}0.155\;kg/ha$ for TP, and 10.7 kg/ha for COD, which were much lower than respective values reported in Japan.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.3
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• pp.399-405
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• 2011

In a desalination technology using RO membranes, chemical cleaning makes damage for membrane surface and membrane life be shortened. In this research cleaning technology using direct osmosis (DO) was introduced to apply it under the condition of high pH and high concentration of feed. When the high concentration of feed is injected to the concentrate side after release of operating pressure, then backward flow occurred from treated water toward concentrated for osmotic pressure. This flow reduces fouling on the membrane surface. Namely, flux of DO was monitored under pH 3, 5, 10 and 12 conditions at feed concentrations of NaCl 40,000 mg/L, 120,000 mg/L and 160,000 mg/L. As a result, DO flux in pH 12 increased about 21% than pH 3. DO cleaning was performed under the concentrate NaCl 160,000 mg/L of pH 12 during 20 minutes. Three kinds of synthetic feed water were used as concentrates. They consisted of organic, inorganic and seawater; chemicals of SiO2 (200 mg/L), humic acid (50 mg/L) sodium alginate (50 mg/L) and seawater. As a result, fluxes were recovered to 17% in organic fouling, 15% in inorganic fouling and 14% of seawater fouling after cleaning using DO under the condition of concentrate NaCl 160,000 mg/L of pH 12.

• Journal of Environmental Health Sciences
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• v.24 no.2
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• pp.38-46
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• 1998

The purpose of this study is to evaluate and compare the effective coagulation of commercial humic acid which is well known as major precursor of trihalomethane, with LAS and PAC and to quantify the residual aluminum in the treated water. Then the optimum pH, the dosage of coagulant were determined. 1. Humic acid concentrati6n, UV absorbance and color were well correlated and UV absorbance(254 nm) and color seem to be used in quntificative analysis of humic acid of same kind. 2. Optimal dosage of LAS and PAC increase as humic acid concentration increases. And optimal pH range for coagulation using LAS is pH 5.5-7.0 and pH 3.5-6.5 for PAC. Within these ranges the removal efficiency is 90-99%. 3. The results of quantification of residual aluminum in treated water shows that minimal aluminum remains on the optimal coagulation condition. But the residual aluminum increses as the dosage of coagulant is beyond the optimal range. Thus the dosage of coagulant should be chosen with the condition on which humic acid removal is maximum and the residual aluminum concentration is minimum. 4. In the water treatment process the raw water pH range is 6.5-8.0, and it seems to be possible to remove humic acid by charge neutralization not by sweep floc. But it should be considered that different commercial humic acids have different physical and chemical characteristics.

• Ecology and Resilient Infrastructure
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• v.3 no.4
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• pp.256-262
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• 2016

Rapid industrialization and a significant population growth has led to an increased use of chemicals, which has limited the biological processes that account for most of the existing water and wastewater treatment methods. Ozone microbubble technology, which is one of advanced oxidation processes, has recently attracted attention as a method to solve these issues. In this paper, we reviewed both the physical and the chemical characteristics of microbubbles, and evaluated microbubble-based ozone oxidation processes focusing on the removal of various toxic contaminants. In addition, we discussed the potential of an ozone microbubble process as water and wastewater treatment processes by combining it with other treatment technologies.

• Magazine of the Korean Society of Agricultural Engineers
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• v.45 no.4
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• pp.66-77
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• 2003

Monitoring data from agricultural reservoirs throughout the country were analyzed to classify agricultural reservoirs according to physical characteristics and COD concentrations, and evaluate the relationships bet-ween water quality items. The physical and chemical data of total 498 reservoirs were analyzed from 1990 to 2001. Average COD, TP, TN, Chl-a, SS concentrations for the reservoirs and pollutant loadings from their watersheds were used for the analysis. It was possible that reservoirs were classified to 4 types using the relationships between the ratios of effective storage per water surface (ST/WS ratio) and COD concentrations. It is recommended that the improvement measures of polluted reservoirs should be performed as following order : integrated consolidation type (complex mechanism type) $\rightarrow$ watershed consolidation type $\rightarrow$ integrated consolidation type (external mechanism type) $\rightarrow$ in-lake consolidation type $\rightarrow$ conservation type and the depth (ST/WS ratio) of reservoir maintained over 5~6 m for water quality improvement. The decision coefficients ($r^2$) between Chl-a and other items (COD, T-P, SS, T-N) were 0.6915, 0.6732, 0.5327, 0.3352, respectively. Therefore, reservoir managers could evaluate the trophic state of reservoirs by COD concentrations.