• 제목/요약/키워드: water absorption properties

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에폭시 몰딩 컴파운드를 위한 에폭시 나노복합재료의 소수성 실리카의 영향 (Influence of Hydrophobic Silica on Physical Properties of Epoxy Nanocomposites for Epoxy Molding Compounds)

  • 김기석;오상엽;김은성;신헌충;박수진
    • Elastomers and Composites
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    • 제45권1호
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    • pp.12-16
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    • 2010
  • 본 연구에서는 에폭시 나노복합재료의 수분 흡수, 열적 안정성 및 기계적 특성에 대한 소수성 실리카의 효과에 대해 고찰하였고, 에폭시 수지의 필러로는 디메틸디크로로실란에 의해 소수성으로 처리된 실리카를 사용하였다. 실험 결과, 실리카는 실란 커플링제의 첨가후 용융혼합법에 의하여 에폭시 수지내에서 균일하게 분산되었으며, 나노복합체의 수분 흡수율은 소수성으로 처리된 실리카의 함량 증가와 함께 감소하는 것을 확인하였다. 열분해 온도, 유리전이 온도, 그리고 열팽창 계수를 통한 나노복합재료의 열안정성은 실리카의 첨가와 함께 향상되는 것을 확인하였다. 또한, 인장강도 및 탄성율을 통한 나노복합재료의 기계적 특성은 실리카 함량 증가와 함께 증가하였고, 이는 에폭시 수지내에 고르게 분산된 실리카와 에폭시 수지 간의 강한 물리적 상호작용에 기인하는 것으로 판단된다.

목재 고분자 복합재료의 환경 특성에 따른 기계적 물성연구 (A Study on Mechanical Properties of Wood-Polymer Composites due to Environmental Characteristic)

  • 이중희;전상진;허석봉;김홍건
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 추계학술발표대회 논문집
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    • pp.91-94
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    • 2005
  • Polypropylene as a matrix has been used for wood polymer composites(WPC). In preparing WPC, the coupling agent, Polypropylene grafted Maleic Anhydride(PP-G-MA) was used in order to obtain a good interfacial bonding force between matrix and fillers and dispersion of wood powders. In this study, the effects of wood powder contents and water absorption on the mechanical properties were experimentally investigated. The tensile strength and flexural strength of composites reached its peak value when the wood powder content was around 60 wt%. However, the peak value of the impact was observed about 30 wt% of wood powder content. The tensile strength and flexural strength increase with increasing the wood power contents. But the impact strength decrease with increasing the wood powder contents. The slight change was observed with the water absorption in the WPC. The optimal condition of the compositions such as Anti-oxidant and UV stabilizers for the outdoor application was suggested in this research.

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혼합재 치환율에 따른 경량소재의 물리적 특성 (Physical Properties of Lightweight Materials According to the Replacement Ratios of the Admixture)

  • 정연조;추용식;이종규;송훈
    • 한국세라믹학회지
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    • 제46권6호
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    • pp.633-638
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    • 2009
  • Lightweight materials were fabricated using glass abrasive sludge, bottom ash and slag powder in this study. This study tried to draw the correlation between physical properties and internal pore of lightweight material. The content of bottom ash and slag powder was from 10% to 50% and firing temperature from $760{^{\circ}C}\;to\;800{^{\circ}C}$ in rotary kiln. The lightweight material containing bottom ash or slag powder had a specific gravity of $0.21{\sim}0.70$ at particle size $2{\sim}4$ mm. Replacement ratio of the admixture increasing with specific gravity increased. Fracture strength of panel made with various lightweight materials was $32{\sim}55\;kgf/cm^2$ and flexural strength was $11{\sim}18\;kgf/cm^2$. Fracture strength increased by 72% and flexural strength was 63% compared with reference. Thermal conductivities of panel was $0.07{\sim}0.11W/m{\cdot}k$. The water absorption ratios of panel with lightweight materials containing bottom ash were $1.8{\sim}2.8$% and slag powder were $2.65{\sim}2.8$%. Excellent results on resistant of water absorption.

고농도 도공과 원지의 흡수특성이 인쇄모틀에 미치는 영향 - PEA Module를 이용한 인쇄모틀 평가 - (Effect of High Solid Coating and Water Absorption Uniformity of Base Paper on Print Mottle - Evaluation of print mottle with PEA module -)

  • 유성종;조병욱;김용식;이용규;이세현
    • 펄프종이기술
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    • 제39권2호
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    • pp.17-24
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    • 2007
  • PEA(Print Evenness Analyzer) Module can be utilized as a tool to evaluate print mottle. The tester is de-signed to measure the uniformity of liquid penetration into paper at very short contact time. To evaluate effects of base paper properties on print mottle, the experiments were performed with 3 types of base pa-per whose sizing degree, roughness and porosity were varied. Coated papers were produced with high solid coating color (70%) and low solid coating color (67%). Uniformity of water absorption into base paper and coated paper was measured with PEA. It was found that, in order to minimize print mottle, base paper shall be produced with a high sizing degree and low roughness and the concentration of coating color shall be kept as high as possible, providing that it has proper rheology properties for coating process.

유리연마슬러지를 사용한 경량골재의 미세구조 및 기공 특성 (Pore properties and Microstructure on the each regions of a Light-Weight Aggregate using Glass Abrasive Sludge)

  • 권춘우;추용식;김영엽;정석조;송훈;이종규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.533-536
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    • 2006
  • A light-weight aggregate with a surface layer was fabricated using glass abrasive sludge and expanding agents. The glass abrasive sludges were mixed with expanding agents ($Fe_2O_3,\;graphite,\;CaCO_3$) and formed into precursors. These precursors were sintered in the range of $700-900^{\circ}C$ for 20min. The sintered light-weight aggregate had a surface layer with smaller pores and an inner region with larger pores. The surface layer and pores controlled the water absorption ratio and physical properties. As the expanding agent fraction and the sintering temperature increased, the porosity and pore size increased. The light-weight aggregate with $Fe_2O_3$ and graphite as the expanding agents had a low water absorption ratio while the porous material with $CaCO_3$ as the expanding agent had a higher water absorption ratio and more open pores.

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무기안료가 시멘트모르타르의 압축강도와 흡수율에 미치는 영향 (The Influence of Inorganic Pigments on the Compressive Strength and Absorption of Cement Mortars)

  • 송혁;이재용;고성석
    • 한국안전학회지
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    • 제19권2호
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    • pp.104-111
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    • 2004
  • The aim of this study was to investigate the influence of inorganic pigments on the physical properties of cement mortar. For this purpose, the compressive strength and absorption test were carried out on cement mortar imxed with inorganic pigments by changing the proportion of cement mortar, water-cement ratio, and ratio of pigment. The result of this study can be summarized as follows: the compressive strength of colored mortar rapidely increased in red and yellow mortar, as the mix ratio of pigment increased. In case of green and black mortar, however, the compressive strength decresed as the mix ratio incresed. In case of red and yellow mortar, the absorption of colored mortar increased as the mixing ratio increased, if the mean particle diameter of the pigment is small. In case of green and black mortar, the absorption ratio decreased as the mix ratio increased. After investigating the overall physical properties of colored mortar, it was confirmed that the proper mix ratio of pigment securing the properties of colored mortar was below 6% of the weight of the cement to be used.

Experimental and statistical analysis of hybrid-fiber-reinforced recycled aggregate concrete

  • Tahmouresi, Behzad;Koushkbaghi, Mahdi;Monazami, Maryam;Abbasi, Mahdi Taleb;Nemati, Parisa
    • Computers and Concrete
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    • 제24권3호
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    • pp.193-206
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    • 2019
  • Although concrete is the most widely used construction material, its deficiency in shrinkage and low tensile resistance is undeniable. However, the aforementioned defects can be partially modified by addition of fibers. On the other hand, possibility of adding waste materials in concrete has provided a new ground for use of recycled concrete aggregates in the construction industry. In this study, a constant combination of recyclable coarse and fine concrete aggregates was used to replace the corresponding aggregates at 50% substitution percentage. Moreover, in order to investigate the effects of fibers on mechanical and durability properties of recycled aggregate concrete, the amounts of 0.5%, 1%, and 1.5% steel fibers (ST) and 0.05%, 0.1% and 0.15% polypropylene (PP) fibers by volumes were used individually and in hybrid forms. Compressive strength, tensile strength, flexural strength, ultrasonic pulse velocity (UPV), water absorption, toughness, elastic modulus and shrinkage of samples were investigated. The results of mechanical properties showed that PP fibers reduced the compressive strength while positive impact of steel fibers was evident both in single and hybrid forms. Tensile and flexural strength of samples were improved and the energy absorption of samples containing fibers increased substantially before and after crack presence. Growth in toughness especially in hybrid fiber-reinforced specimens retarded the propagation of cracks. Modulus of elasticity was decreased by the addition of PP fibers while the contrary trend was observed with the addition of steel fibers. PP fibers decreased the ultrasonic pulse velocity slightly and had undesirable effect on water absorption. However, steel fiber caused negligible decline in UPV and a small impact on water absorption. Steel fibers reduce the drying shrinkage by up to 35% when was applied solely. Using fibers also resulted in increasing the ductility of samples in failure. In addition, mechanical properties changes were also evaluated by statistical analysis of MATLAB software and smoothing spline interpolation on compressive, flexural, and indirect tensile strength. Using shell interpolation, the optimization process in areas without laboratory results led to determining optimal theoretical points in a two-parameter system including steel fibers and polypropylene.

Effect of rheological properties on chemical absorption of carbon dioxide with MEA

  • Park, Sang-Wook;Kim, Tae-Young;Park, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제16권1호
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    • pp.35-45
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    • 2004
  • Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.

탄성에폭시의 열적.기계적 특성에 관한 연구 (Study on the Thermal and Mechanical Properties of Elastic Epoxies)

  • 민지영;이관우;이경용;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.248-251
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    • 2003
  • In this paper, it was experimented about thermal and mechanical insulation properties of a elastic epoxy specimen. We made elastic epoxy specimen adding a ratio of 0[phr], 20[phr], 35[phr] and 53[phr] with modifier to existing epoxy. Each specimen was absorbed by 25h, 196h, 361h 484h with water. In water-absorption state, it was experimented a change of heat flows by temperature of elastic epoxy and changes of thermal expansion coefficient. Also, a hardness-change of each specimen was experimented by change of water-absorption time. In this experiment DSC (Differential Scanning Calorimetry) and TMA (Thermomechanical Analysis) were used. A temperature range of DSC was changed from -0[$^{\circ}C$] to 200[$^{\circ}C$], TMA was changed from -0[$^{\circ}C$] to 350[$^{\circ}C$]. In addition, we investigated structural analysis of water absorbed specimen using SEM (Scanning electron microscope).

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외래종목재(外來種木材)의 해부학적(解剖學的) 및 물리적(物理的) 성질(性質)에 대(對)한 연구(硏究) (A Study on Anatomical and Physical Properties of Imported Woods)

  • 심종섭;조재명
    • Journal of the Korean Wood Science and Technology
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    • 제10권3호
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    • pp.46-47
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    • 1982
  • 1. The physical and anatomical properties investigated in this study are the ones, which may give more effect on absorption of preservatives, such as variation of annual ring, specific gravity, shrinkage, E.M.C. of desorption and adsorption at 70 percent relative humidity condition, general and minute properties of wood. 2. On this study, the positive effects of wood structure, in particular, the appearances of tyloses in vessel element upon the absorption of creosote were observed. 3. Thirteen percent sodium chloride solution treatment and boiling hot water treatment have shown poor results to improve the preservative absorption characteristics of tested species however, some slight difference between treated and control could be seen. (see Tables 6 and 7).

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