• Journal of the Korean Ceramic Society
• /
• v.27 no.7
• /
• pp.833-840
• /
• 1990

For the development of multi-functional materials which has water reducing power, air entraining power and waterproofing power as well as blending additive in cement mortar the coal ash was modified with asphalt-stearic acid or asphalt-boiled oil mixtures by mechanical treatment. And the physical properties of cement mortar blended with modified coal ashes were compared with those of the water-tightness-cement mortar and the ordinary-portland-cement mortar added with AE.water reducing agent. The mortar of coalash-blend-cement modified with asphalt-stearic mixture was increased acid about 20% in initial strengths and decreased about 20% in water absorption ratio than those of ordinary coalash-blend-cement. The mortar of coalash-blend-cement modified with asphalt-bolied oil mixture was similar to the cement mortar added with AE.water reducing agent in water reduction ratio, air entraining conents and the initial strengths, also was similar to the water-tightness-cement mortar in water absorption and water permeability ratios.

• Proceedings of the Korean Society of Agricultural Engineers Conference
• /
• 2000.10a
• /
• pp.266-271
• /
• 2000

This study was performed to find out how much water the cement hydration reaction need. It is real situation that it is difficult to find out the amount of chemical combined water with stoichiometric chemical reaction form. Because several variation occurred during hydration reaction it's not easy to divide water which used at cement paste mixture. In this study high temperature(105$^{\circ}C$) dry method was used to divide evaporable water and non-evaporable water. The last is combined water chemically and some free water absorbed to products of hydration physically. The test was processed with variation of water cement ratio from 10% to 45% with 5% intervals. The weight of cement paste specimens were measured after dry for 72hours at each checking time(0.5, 1, 3, 5, 10, 24, 48, 72, 168hour). In this study some conclusions such as follows were derived. Firstly, Pure combined water contents required at cement hydration result in 23.3percent of the weight of cement. Secondly, The sufficient mixing water needed to fully hydrated cement result in about 40∼45percent of weight of cement. That is, gel pores water could be about 16.7∼21.7percent of weight of cement.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.04a
• /
• pp.160-165
• /
• 1999

Osmotic pressure induced by semi-permeability of hardened cement pasts and cement mortar was studied, which was considered to be a cause of failure such as separation and blistering of floor coatings or wall coatings from the concrete substrate. The specimens with a water cement ratio of 45, 60 and 75% were installed between the solution of sodium chloride and distilled water. First, we measured water flux from distilled water to sodium chloride and the ion flux of Na+ and Cl- through the specimens. Then, we measured osmotic pressure induced by semi-permeability of the specimens using an apparatus which was specially developed for this study. It was made clear that hardened cement paste and cement mortar have properties of semipermeability, and the osmotic pressure is closely related to their water cement ratio. Finally, we calculated the osmotic pressure according to Staverman's equation, which was obtained for organic membranes, and tried to explain quantitatively the observed pressure.

• Journal of the Korean Ceramic Society
• /
• v.26 no.5
• /
• pp.698-704
• /
• 1989

Basic investigation for the flexural strength and water stability of hardened cement pastes using ordinary portland cement with water-soluble polyer (hydroxypropyl methyl cellulose ; HPMC) was carried out with 0.2 of water cement ratio. For molding of the specimen, the paste was mixed by twin roll mill. According to increase in the content of HPMC, the setting time of cement paste was delayed and the flexural strength was increased. The maximum flexural strength of hardened cement paste with 5.0wt% of HPMC was about 330 kg/$\textrm{cm}^2$. The expansion of the hardened cement paste immersed in water was increased with the content of water soluble polymer(HPMC). Consequently, the strength and the water stability of the hardened cement pastes were remarkably reduced by the expansion of them.

• Journal of the Korean Ceramic Society
• /
• v.34 no.10
• /
• pp.1037-1044
• /
• 1997

Mechanical properties and water stability of HAC/PVA based MDF cement composite were investigated using polyurethane(PU) resin, silane coupling agent and various PVA. The results were as follows ; The flexural strength of MDF cement composite increased as increasing with PVA content. Low-viscosity PVA developed higher flexural strength than high-viscosity PVA under a drying curing condition. But the strength of water immersed specimen decreased. Water stability of MDF cement improved as increasing with content of PU. Consequently, water stability of polyurethane 7% added MDF cement was about 2 times higher than that of the controlled specimen. Furthermore, the strength and water stability of diamine group based silane couling agent in using MDF cement increased and improved dramatically.

• Computers and Concrete
• /
• v.13 no.3
• /
• pp.309-323
• /
• 2014

Based on the compositions and structures of cement-based materials, the geometrical models of the tortuosity of transport paths in hardened cement pastes, mortar and concrete, which are associated with the capillary porosity, cement hydration degree, mixture particle shape, aggregate volume fraction and water-cement ratio, are established by using a geometric approach. Numerical simulations are carried out to investigate the effects of material parameters such as water-cement ratio, volume fraction of the mixtures, shape and size of aggregates and cement hydration degree, on the tortuosity of transport paths in hardened cement pastes, mortar and concrete. Results indicate that the transport tortuosity in cement-based materials decreases with the increasing of water-cement ratio, and increases with the cement hydration degree, the volume fraction of cement and aggregate, the shape factor and diameter of aggregates, and the material parameters related to cement pastes, such as the water-cement ratio, cement hydration degree and cement volume fraction, are the primary factors that influence the transport tortuosity of cement-based materials.

• Advances in concrete construction
• /
• v.8 no.1
• /
• pp.47-54
• /
• 2019

Portland cement pervious concrete has been expected to have good water permeability, mechanical properties and abrasion resistance at the same time when Portland cement pervious concrete is applied to the actual vehicle pavement. In this study, the coarse aggregate and cement were replaced by the fine aggregate and the silica fume to improve actual road performance Portland cement pervious concrete. The Mechanical properties, the water permeability and the abrasion resistance of Portland cement pervious concrete were investigated. The results show that the compressive strength, the flexural strength and the abrasion resistance are increased when the fine aggregate and the silica fume are added to Portland cement pervious concrete separately. However, the porosity and the water permeability are decreased simultaneously. With assistance of silica fume and fine aggregate simultaneously, Portland cement pervious concrete could achieve a higher strength. The compressive strength, the flexural strength and the abrasion resistance of Portland cement pervious concrete mixed with 5% fine aggregates and 8% silica fume are increased by 93.1%, 65% and 65.2%, respectively. The porosity and the water permeability are decreased by 22.4% and 85% when Portland cement pervious concrete is mixed with 5% fine aggregate and 8% silica fume. Therefore, the replacement ratio of the fine aggregates and the silica fume should be considered comprehensively and determined on the premise of ensuring the water permeability coefficient.

• Proceedings of the Korean Geotechical Society Conference
• /
• 1999.02a
• /
• pp.84-95
• /
• 1999

Laboratory experiments were performed to evaluate the strength characteristics of solidified sandy soils by portland cement with mixing conditions. Factors considered in the experiments were the fine content(<#200, %), cement content(%) and water-cement ratio and unconfined compressive strength tests were performed on samples at 7 and 28 cured day. Results of tests showed that for a low cement content(7%∼10%) the fine content was very important while for a high cement content the water-cement ratio was very important. For 7%∼10% cement content, the optimum fine content which gained maximum strength was about 30%. But for 13% cement content, low fine content and water-cement ratio were more useful than others. In the multi regression analysis, significant equation was gained.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.05a
• /
• pp.584-587
• /
• 2004

This research investigates the rheological behavior and the confined water ratio of the cement paste and binder condition in order to predict mix design proportion of the high flowing concrete. The purpose of this study is to determine the optimum replacement ratio of binders including fly ash, and lime stone powder by the cement weight. For this purpose, belite cement, blast furnace slag cement and ordinary portland cement are selected. As test results, the confined water ratio shows the following range ; OPC>blast furnace slag cement>belite cement. Therefore, belite cement is proved very excellent cementitious materials in a view point of the flowability. The optimum replacement ratio of lime stone powder is shown over $30\%$ in case of belite cement and about $10\%$ in case of slag cement type. Also, the optimum replacement ratio of fly ash is shown $30\%$ by the cement weight considering the confined water ratio and deformable coefficient of the paste condition.

• Journal of the Korea Institute of Building Construction
• /
• v.9 no.5
• /
• pp.71-77
• /
• 2009

In a range of forms, such as latex, water-soluble polymer, liquid resin, and monomer, polymer dispersions have been widely used in the construction industry as cement modifiers because of their excellent properties, such as acid-resistance, water-proofness, and good ductility in mortar and concrete. Polymer cement slurry (polymer-modified slurry) is made of cement and polymer dispersions, with a high polymer-cement ratio of 50% or more. The purpose of this study is to evaluate the water permeability and drying shrinkage of polymer cement mortar (polymer-modified mortar) and cement concrete coated by polymer cement slurry. The polymer cement mortar and cement concrete are prepared with various polymer types, polymer-cement ratios and curing methods, and are tested for water permeability, drying shrinkage and strength. The test results showed thatthe weight of permeable water of polymer cement mortar decreases with an increase in the polymer-cement ratio, reaching a minimum at the polymer-cement ratio of 20%. In particular, the weight of permeable water of St/BA-modified mortar with a polymer-cement ratio of 20% coated with St/BA-modified slurry is about 1/55 that of unmodified mortar. The EVA- and St/BA-modified slurries coated on cement concrete have about 4 or 5 times higher drying shrinkage compared to cement concrete. The strength of polymer cement mortars tends to increase with a higher polymer-cement ratio, and is considerably higher than that of unmodified mortar. It is thus concluded that polymer cement mortars coated by polymer cement slurry are effective for industrial application, and have superior properties such as waterproofness and strengths, compared with conventional cement mortar.