• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.95-103
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• 2018

As a guideline for desulfurization and dehumidification pretreatment facility for optimizing utilization of biogas, the $H_2S$ concentration is set at 150 % which can be treated with iron salts, dehumidification is the optimum value for generator operation, and the relative humidity applied at the utilization of biogas in EU is set at 60 %. We have set up the generator facility guidelines to optimize utilization of biogas. The appropriate amount of biogas should be at least 90 % of the total gas generation, and the capacity of generator facility should be set at 20~30 %. In order to equalize the pressure of the incoming gas the generator, a gas equalization tank should be installed and the generator room average temperature should be kept at $45^{\circ}C$ or less. Since the gas is not produced at a certain methane concentration in the digester, the efficiency is lowered. Therefore, it is required to install an air fuel ratio control system according to the change in methane concentration. Therefore, it is necessary to compensate for the disadvantages of biogasification facilities of organic waste resources and optimize utilization of biogas and improve operation of facilities. This study was conducted to optimize biogas utilization of type of organic waste(containing sewage sludge and food waste, animal manure), investigate the facilities problem and propose design, operation guidelines such as pre-treatment facilities and generators.

• Resources Recycling
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• v.17 no.2
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• pp.3-15
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• 2008

Different toxic wastes are disposed of in our surroundings and these will ultimately threaten the existence of living organisms. Biohydrometallurgy, which includes the processes of bioleaching and bioremediation through the activities of microorganisms such as bacterial or fungal species, is a technology that has the potential to overcome many environmental problems at a reasonable economic cost. Bioleaching were carried out for dissolution of metals from different materials using most important metal mobilizing bacteria such as Thiobacillus ferrooxidans, Thiobacillus thiooxidans and Laptospirillum ferrooxidans. According to the reaction, bioleaching is parted as direct and indirect mechanism. In direct mechanism the bacteria oxidize the sulphides minerals by accepting electron and producing sulphuric acid in leaching media for their growth and metabolism. In other hand the indirect bioleaching is demonstrated as the oxidation of sulphides mineral by the oxidant like $Fe^{3+}$ produced by the iron oxidizing bacteria. Through this process, substantial amount of metal can be recovered from low-grade ores, concentrates, industrial wastes like sludge, tailings, fly ash, slag, electronic scrap, spent batteries and spent catalysts. This may be alternative technology to solve the high deposition of waste, which moves toward a healthy environment and green world.

• Journal of the Korean GEO-environmental Society
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• v.9 no.5
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• pp.5-13
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• 2008

In this study, It was carried out to evaluate the feasibility of recycled crushed concrete as aggregate used cement mortar replace sand and to investigate engineering properties of recycled aggregate for hazardous waste solidification. The compressive strength of cement mortar replaced 5-15% (wt.) recycled aggregate was over $163kgf/cm^2$ which is the standard of first grade concrete block class C. And cement mortar was examined to evaluate the stability by leaching test. Cu, Cd, Pb, Cr, and As as the heavy metals were proved very stable but mercury (Hg) was leached high concentration because it was simply tied to the cement surface. We investigated the crystal structures of cement mortar and they had shown the peaks of $Ca(OH)_2$, ettringite, and CSH (calcium silicate hydrate). As the result, the longer curing time, the higher CSH peak that means to increase compressive strength and the cement mortar was more stable. Therefore it was shown that it may be possible to apply hazardous waste solidification using recycled aggregate, fly ash and sewage sludge ash.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.1
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• pp.55-64
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• 2018

The purpose of this study is to provide a design and operation technical guideline for meeting the appropriate design criteria to biogas utilization treating organic wastes. In accordance with the government's mid-to long-term policies on bio-gasification and energization of organic wastes, the expansion of the waste-to-energy (WTE) facilities is being remarkably promoted. However, because of the limitation of livestock manure containing low-concentration of volatile solids, there has been increased in combined bio-gasification without installing new anaerobic digestion facilities. The characteristics and common problems of each treatment processes were investigated for on-going 11 bio-gasification facilities. The seasonal precision monitoring of chemicophysics analysis on anaerobic digestor samples was conducted to provide guidelines for design and operation according to the progress of biogas utilization. Consequently, Major problems were investigated such as large deviation of organic materials depending on seasons, proper dehumidification of biogas, pretreatment of hydrogen sulfide, operation of power generation and steam. This study was conducted to optimize biogas utilization of type of organic waste(containing sewage sludge and food waste, animal manure), research the facilities problem through field investigation.

• Resources Recycling
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• v.22 no.3
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• pp.73-80
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• 2013

Metal prices are rapidly rising due to increasing demand of metals and limited available resources according to the industrial requirement. As a result, securing a stable supply of these metal resources has been recognized as a core element of national competitiveness and sustained economic growth. In the case of magnesium and its alloys which are entirely depending on import, low-grade magnesium scraps from end-of-life vehicles and 3C(Camera, Computer, Communication) parts and magnesium wastes such as sludge and dross generated during melting process are hardly recycled. Accordingly, the development and commercialization of recycling technology of low-grade magnesium scrap is desperately needed to improve efficiency of resource circulation and to establish the required proprietary of resource metal supply and demand. In this study, papers and patents on recycling technologies of waste magnesium were analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1974 to 2012. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals was analyzed by the years, countries, companies, and technologies.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.1
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• pp.77-85
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• 2019

Biogasification is a technology that uses organic wastes to reproduce as environmental fuels containing methane gas. Biogasification has attracted worldwide attention because it can produce renewable-energy and stable land treatment with prohibit from landfilling and ocean dumping of organic waste. Biomethane is produced by refining biogas. It is injected into natural gas pipeline or used transportation fuel such as cars and buses. 90 bio-gasification facilities are operating in 2016, and methane gas production is very low due to it is limited to organic wastes such as food waste, animal manure, and sewage sludge. There are seven domestic biomethane manufacturing facilities, and the use of high value-added such as transport fuels and city-gas through upgrading biogas should be expanded. On the other hand, the rapid biogasification of organic wastes in domestic resulted in frequent breakdowns of facilities and low efficiency problems. Therefore, the problem is improving as technical guidance, design and operational technical guidance is developed and field experience is accumulated. However, while improvements in biogas production are being made, there is a problem with low utilization. In this study, the problems of biomethane manufacturing facilities were identified in order to optimize the production and utilization of biogas from organic waste resources. Also, in order to present the design and operation guideline of the gas pretreatment and the upgrading process, we will investigate precision monitoring, energy balance and economic analysis and solutions for on-site problems by facility.

• Korean Journal of Environmental Agriculture
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• v.18 no.1
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• pp.54-60
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• 1999

Three different types of lab-scale anaerobic bioreactors, AF and two-stage ASBF-PR and ASBF-SP, were evaluated in treating swine wastewater by operating at $1{\sim}2$ days of hydraulic retention time with increasing organic loading rate upto 6.3 $kg-COD/m^3{\cdot}d$ at $35^{\circ}C$. Seeding the anaerobic bioreactors with waste anaerobic digester sludge from a municipal wastewater treatment plant was effective and a 40-day acclimation period was required for steady-state operation. Three anaerobic bioreactors were effective in treating swine wastewater with COD removal efficiency of $66.4{\sim}84.9$% and biogas production rate of $0.333{\sim}0.796m^3/kg-COD_{removed}{\cdot}d$. Increases of organic loading rate by increasing influent COD concentration and/or decreasing hydraulic retention time caused decreases in COD removal efficiency and increases in biogas production rate. At relatively high organic loading rate employed in this study, the treatment efficiency of AF and ASBF-PR were similar but superior than that of ASBF-SP, indicating that porosity and pore size of the media packed in the bioreactors are more important factors contributing the performance of to bioreactors than specific surface area of the media. TKN in swine wastewater must be removed prior to the anaerobic processes when anaerobic process is considered as a major treatment process since influent TKN concentration of $1,540{\sim}1,870mg/L$ to the bioreactors adversely affect the activity of methanogenic bacteria, resulting in decreases of treatment efficiency and biogas production rate by 50%.

• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.179-191
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• 2016

In addition to the measurement of the concentration of soil contaminants, the new idea of indicative parameters was proposed to validate the remedial works through the monitoring for the changes of soil characteristics after applying the clean up technologies. The parameters like CFU (colony forming unit), pH and soil texture were recommended as indicative parameters for land farming. In case of soil washing, water content and the particle size distribution of the sludge were recommended as indicative parameters. The sludge is produced through the particle separation process in soil washing and it is usually treated as a waste. The parameters like water content, organic matter content, CEC (cation exchange capacity) and CFU were recommended as indicative parameters for the low temperature thermal desorption method. Besides the indicative parameter, sampling methods in stock pile and the optimal minimum amount of composite soil sample were proposed. The rates of sampling error in regular grid, zigzag, four bearing, random grid methods were 17.3%, 17.6%, 17.2% and 16.5% respectively. The random grid method showed the minimum sampling error among the 4 kinds of sampling methods although the differences in sampling errors were very little. Therefore the random grid method was recommended as an appropriate sampling method in stock pile. It was not possible to propose a value of optimal minimum amount of composite soil sample based on the real analytical data due to the dynamic variation of $CV_{fund{\cdot}error}$. Instead of this, 355 g of soil was recommended for the optimal minimum amount of composite soil sample under the assumption of ISO 10381-8.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.141-151
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• 2016

Recently, technology for energy recovery from waste has been increasing interest globally including the Korea. In Korea, we have interested in using biogas generated from the sewage treatment process. As one alternative, there are operating biogas combined heat and power plant. The generation amount of the Sewage Sludge are expected to grow in the future. For this reason, total processing cost of Sewage Sludge will increase. To solve this problem, it seems will be invested with the expansion of facilities that use biogas as energy. Therefore, quantitative information on such facilities is required. Thus, this study attempts to economic feasibility analysis for Seonam Biogas Combined Heat and Power Plant. Meanwhile, as the benefit items for economic feasibility analysis consider electricity supply benefit except for heat supply benefit. The average prices of electricity use were residence 123.69, commercial 130.46, and industry 102.59 won per kWh for the year 2015, In addition, the economic benefit are calculated to be residence 310.21, commercial 378.49, and industry 222.87 won per kWh. The results of economic feasibility analysis is NPV 72.18 billion won, B/C 1.90, IRR 37%, shows that economic validity of Seonam Biogas Combined Heat and Power Plant.

• Journal of the Korean Ceramic Society
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• v.39 no.7
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• pp.680-686
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• 2002

The solidification/stabilization mechanism of each cementious material was investigated. It was found that when $C_3$S was hydrated , the Pb element could be transferred to the insoluble Ca[Pb(OH)$_3$.$H_2O$]$_2$and the Cr element to the CaCr $O_4$$H_2O$. The addition of heavy metal tends to delay the hydration until initial 7 days. The Pb element as also delayed the hydration and the Cr element was substituted for the ettringite. On the occasion of the hydration of $C_4$ $A_3$ $S^{S}$, the Pb and Cr ions were solidified/stabilized by the substitution into the ettringite and/or monosulfate. Leaching of the Pb, Cr and Zn elements in the solidified material was extremely little, indicating that heavy metals were effectively solidified/stabilized in the hydrated cementious materials. Solidification/stabilization of heavy metal ions in the industrial wastes such as the STS, BF and COREX sludge was investigated. In case of the mixing ratio of cement and slag was 3 : 7, leaching of hazardous heavy metal ions was very little, indications that the solidification and stabilization was very successful.l.