• 대한환경공학회지
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• 제33권2호
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• pp.71-76
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• 2011

본 연구는 Pb와 Cu로 오염된 사격장 토양을 대상으로 폐자원을 가공하여 만든 안정화제를 이용하여 안정화 처리를 수행하였다. 안정화제는 폐굴껍질을 소성하여 생석회로 가공한 Calcined oyster shells (COS)와 폐소뼈를 가공한 Waste cow bones (WCB)로 오염토 함량대비 각각 5%와 3%를 사용하여, 28일간 습윤양생한 후 각종 용출시험법을 통해 효율성을 평가 하였다. 증류수 용출 및 SPLP에서는 뚜렷한 안정화 효율이 관찰되지 않았는데, 이는 중성 또는 약산성 환경에서는 중금속의 용출량 자체가 많지 않기 때문으로 판단된다. 반면, TCLP 및 0.1 N HCl을 이용한 용출실험에서는 안정화 처리를 한 토양의 경우 중금속의 용출량이 확연하게 감소한 것을 확인할 수 있었다. 특히, 0.1 N HCl 용출 결과에서 Pb 99.9%, Cu 83.9%의 매우 높은 용출량 저감효과를 보였고, 이는 비교적 강산성 용출환경에서는 중금속의 안정화 효과가 크게 나타남을 의미한다. 연속추출 결과를 통해 Pb와 Cu 간에 안정화 경향성의 차이는 Pb가 불용성 물질로의 변환과 안정화 효율이 더 탁월한 것으로 판단된다. 본 연구는 폐자원을 이용한 안정화제가 오염토양 처리에 활용 가능함을 증명하고 있고, 또한 폐기물로 취급되는 폐자원의 재사용 방안을 제시한다는 점에서도 큰 의미를 갖는다.

• 한국환경보건학회지
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• 제29권2호
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• pp.45-49
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• 2003

In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove H$_2$S. According to TGA results, temperature had influenced on H$_2$S removal efficiency. As desulfurization temperature increased, desulfurization efficiency increased. Also, maximum desulfurization efficiency was observed at 80$0^{\circ}C$. Desulfurization was related to calcination temperature. Considering temperature ranges of exhausted gas from hot gas gasification equipment were 400~80$0^{\circ}C$. Thus, desulfurization efficiency would be increased desulfurization temperature situation at highly. Experiments by TGA showed that particle size of sorbents had influenced on desulfurization capacity. Maximum desulfurization capacity was observed at 0.631 mm for oyster and clam. Rest of sorbents showed similar capacity within 0.171~0.335 mm particle size range. So, particle size would be considered. When would be used waste shells as IGCC sorbents. According to the results about desulfurization capacity by TGA, oyster had the best desulfurization capacity among limestone and waste shell. We would be identify to substituted oyster for existing sorbents

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2002년도 가을 학술발표회 논문집
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• pp.681-688
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• 2002

Study was peformed to develop the‘environmental double pile’for the remediation of low-permeable contaminated soil. This technique is similar in function to‘sand drain pile’But this applies recyclable oyster shell treated as waste materials to a drain material and the pile is consisted of two layers. Inner metal pile is located in center and oyster shells are filled around it. By this technology, contaminated ground water is pumped out through the oyster shell and purified by drainage, adsorption, and reaction processes. Afterwards, the grout material is injected through the inner pile for the effect of the solidification / stabilization. As a result, the concept of this technique is a development of one-step process technology. Through the test, a consolidation characteristic by radial drain is going to be evaluated and the optimum standard of this technology will be calculated.

• 자원리싸이클링
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• 제11권2호
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• pp.45-51
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• 2002

본 연구는 수산폐기물인 폐굴껍질과 우리나라에 넓게 분포되어 있는 황토를 이용하여 응집제를 제조하기 위한 것으로서 응집제원료의 성분조사 결과, 폐굴껍질은 CaO성분이 55.43(wt%)로 가장 많이 함유되어 있었고, 황토는$ SiO_2$가 45.30(wt%)로 주성분임을 알 수 있었다. 폐굴껍질 내의 CaO순도를 높이기 위해 $900^{\circ}C$에서 2시간동안 소성 하였으며. ball mill을 사용하여 0.074 mm(200mesh)로 분쇄 하였다. 소성된 폐굴껍질 분말과 황토 분말을 각각 6:4, 7:3, 8:2, 9: 1의 비율로 혼합하여 응집제를 제조하였다 또한 제조된 응집제와 화학 소석회와의 비교실험을 통해 화학 소석회의 대체 가능성을 확인하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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• pp.397-401
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• 2005

Acid mine drainage and waste of abandoned mine area have caused serious water pollution and destruction of an ecosystem because of exposing to environment without an appropriate treatment. Gwang-yang mine area also has a serious problem in the nearby residential area and waterway ecosystems. The objectives of this research are to develop the most suitable remediation system for acid mine drainage by using waste materials, and to diagnose stream environments impacted by acid mine drainage through the new ecological health assessment methodology, and thus ultimately providing a restoring methodology to mining regions. In the water system health assessment, the result of ESHI model, RBP and Karr suggested by US EPA is revised by ecological features of our country, come to ESHI score 13; 'Very poor' at some points. Together with pH value and heavy metal concentration, it's the aggravation of ecological health index caused by chemical disturbances. In the acid mine drainage treatment, we apply marine shells and slags to this system. Slags had the best removal ability for heavy metals, but pH value was more than 10 exceeding the standard for drain water. In case of marine shells, pH of treated water maintained 7 to 8, and concentrations of Fe and Zn decreased significantly after treatment.

• 청정기술
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• 제28권2호
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• pp.97-102
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• 2022

Lithium sulfur (Li-S) batteries have attracted considerable attention as a promising candidate for next-generation power sources due to their high theoretical energy density, low cost, and eco-friendliness. However, the poor electrical conductivity of sulfur and its insoluble discharging products (Li₂S₂/Li₂S), large volume changes, severe self-discharge, and dissolution of lithium polysulfide intermediates result in rapid capacity fading, low Coulombic efficiency, and safety risks, hindering Li-S battery commercial development. In this study, a three-dimensionally (3D) connected hierarchical porous carbon framework (HPCF) derived from waste sunflower seed shells was synthesized as a sulfur host for Li-S batteries via a chemical activation method. The natural 3D connected structure of the HPCF, originating from the raw material, can effectively enhance the conductivity and accessibility of the electrolyte, accelerating the Li⁺/electron transfer. Additionally, the generated micropores of the HPCF, originated from the chemical activation process, can prevent polysulfide dissolution due to the limited space, thereby improving the electrochemical performance and cycling stability. The HPCF/S cell shows a superior capacity retention of 540 mA h g^-1 after 70 cycles at 0.1 C, and an excellent cycling stability at 2 C for 700 cycles. This study provides a potential biomass-derived material for low-cost long-life Li-S batteries.

• 한국세라믹학회지
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• 제53권1호
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• pp.1-6
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• 2016

In this year, Koreans have a shortage in agricultural and drinking water due to severe algal blooms generated in major lakes. Waste oyster shells were obtained from temporary storage near the workplace at which oysters were separated from their shells. Heating ($1000^{\circ}C$ for 1 h in air) was employed to convert raw oyster shell powders into calcium oxide powders that reacted efficiently with phosphorus and nitrogen to remove algal blooms from eutrophicated wastewater. As the dispersed amount of heated oyster shell powders was increased, water clarity and visual light penetration were improved. Coagulation, precipitation and carbonation process of the heated oyster shell powders in a water purifier facilitated removal of eutrophication nutrient such as phosphorus and nitrogen, which is both beneficial and economically viable. $CO_2$ implantation by carbonation treatment not only produced thermodynamically stable CaO in oyster shells to derive precipitated calcium carbonate (PCC) but also accelerated algal removal by activation of coagulation and precipitation process. The use of oyster shell powders led to a mean reduction of 97% in total phosphate (T-P), a mean reduction of 91% in total nitrogen (T-N) and a maximum reduction of 51% in chemical oxygen demand (COD), compared with the total pollutant load of raw algal solution. Remarkable water quality improvement of algal removal by heated oyster shell powders and PCC carbonation treatment will allow utilization as water resources to agricultural or industrial use.

• 한국결정성장학회지
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• 제30권4호
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• pp.143-149
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• 2020

전복패각을 Ca원으로 이용하여 바이오 소재로 중요한 인산칼슘(calcium phosphates)들을 침전법을 통해 합성하였다. 전복패각에서 유래한 수산화칼슘(Ca(OH)₂)을 칼슘 공급원(전구체)으로 사용하였다. 수용액상에서 수산화칼슘과 인산(H₃PO₄)을 반응시켜 침전반응을 유도하여 인산칼슘화합물로의 합성을 유도하였다. 초기 전구체 Ca/P 비율을 1.50, 1.59 및 1.67로 조절하였으며 이 조성변화와 침전물에 대한 열처리가 분말 및 소결체의 물성에 미치는 영향에 대해 조사하였다. 초기 전구체 Ca/P 비율을 조절함으로써 소결체 상합성의 조절이 가능하였고, 1150℃에서 소결한 소결체에서(hydroxyapatite(HAp), β-tricalcium phosphate(β-TCP) 및 HAp와 β-TCP가 혼합된 2상 인산칼슘(BCP, HA/β-TCP))들이 합성되었다. 이러한 결과는 저비용, 고가용성을 가지는 경제적인 출발물질로부터 고부가가치 인산칼슘을 합성할 수 있는 가능성을 보여주었다.

• 한국해양환경ㆍ에너지학회지
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• 제5권2호
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• pp.35-40
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• 2002

어구용 폐스티로폼을 자원으로 활용할 수 있도록 하기 위하여 세정과 건조공정을 도입하여 감용하는 장치를 자체 개발하였으며, 시스템을 폐스티로폼 발생 지자체에 설치하여 설비의 운전 신뢰성을 확인하였다. 굴피 및 홍합피 등의 이물질을 완벽하게 제거하고 해수에 포함된 염분을 육상에서 발생되는 스티로폼 수준까지 낮춤으로써 어구용 폐스티로폼은 플라스틱의 원료로 탈바꿈할 수 있었으며, 종래의 처리 방법에 비해 1/10수준에 불과한 비용으로 어구용 폐스티로폼의 처리가 가능하도록 함으로써 설비의 설치나 운영에 따르는 경제성 문제를 해결하고자 하였다.

• 한국농공학회논문집
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• 제55권3호
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• pp.35-40
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• 2013

The present study was conducted to investigate the adsorption potential of red mud for fluoride removal. Different operation parameters such as the effect of contact time, initial concentration, pH, competing anions, seawater, adsorbent dose amount, and adsorbent mixture were studied. Nearly 3 hr was required to reach sorption equilibrium. Equilibrium sorption data were described well by Langmuir model and the maximum adsorption capacity of red mud was 5.28 mg/g. The fluoride adsorption at pH 3 was higher than in the pH range 5-9. The presence of anions such as sulfate, nitrate, phosphate, and bicarbonate had no significant effect on fluoride adsorption onto red mud. The fluoride removal by red mud was greater in seawater than deionized water, resulting from the presence of calcium and magnesium ion in seawater. The use of red mud alone was more effective for the removal of fluoride than mixing red mud with other industrial waste such as oyster shells, lime stone, and steel slag. This study showed that red mud has a potential application in the remediation of fluoride contaminated soil and groundwater.