• 제목/요약/키워드: waste alkali

검색결과 194건 처리시간 0.032초

고온 고압 조건에서의 난분해성 액상폐기물 분해 특성 (Decomposition Characteristics of Non-Degradable Liquid Waste under High Temperature and High Pressure Conditions)

  • 이강우;손병현
    • 한국산학기술학회논문지
    • /
    • 제8권6호
    • /
    • pp.1572-1578
    • /
    • 2007
  • 지정폐기물은 폐산, 폐알칼리, 폐유, 폐유기용제, 폐합성수지, 먼지, 슬러지, 감염성폐기물 등이며, 이 중에서 많은 부분이 폐산, 폐알칼리, 폐유, 폐유기용제, 폐합성수지 등 액상지정폐기물이다. 이와 같은 액상지정폐기물을 적절히 분해하기 위해 먼저 액상지정폐기물에 대하여 밀도, 삼성분, 원소분석, 발열량 등 물리화학적 특성을 분석하고 0.3톤/일급의 고온고압시스템을 설계하였으며, 반응온도는 $1,200^{\circ}C$ 이상, 압력은 최대 4 $kg_f/cm^2(g)$ 조건에서 실험을 수행하였다. 폐유의 평균 밀도값은 0.93 g/mL. 폐유기용제는 0.93 g/mL, 폐합성수지는 0.91 g/mL이었으며, 삼성분과 원소분석 결과 폐유기용제는 수분 54.34%, 회분 3.35%, 가연분 42.31%이었고, 탄소 29.73%, 수소 3.82%, 산소 5.94%, 질소 2.31%, 황 0.51%이었다. 폐유의 평균 저위발열량은 8,294 kcal/kg, 폐유기용제의 경우 7,462 kcal/kg, 그리고 례합성수지는 5,809 kcal/kg으로 나타났다. 액상례기물 중 유해물질의 분해 특성을 보기 위해 대상 폐기물에 혼합한 톨루엔, TCE 그리고 톨루엔이 고온에서 분해될 때 발생하는 벤젠 3가지 물질에 대해 고온 고압 처리 전후의 양으로 각물질의 DRE를 비교한 결과, 상압조건에서 벤젠 99.73%, 톨루엔 99.73%, TCE가 99.95% 이었으며 가압조건에서 벤젠99.97%, 톨루엔 99.82%, TCE가 99.99%으로 나타나 가압조건이 상압조건보다 유해물질의 분해율이 향상된 결과를 보였다. 본 실험결과 TCE/톨루엔 혼합물의 DRE는 99.73% 이상으로 매우 높게 나타나 유해물질이 적절히 분해됨을 확인할 수 있었다.nes., CWT+35‰+Anes., NWT+15‰+Anes. 및 CWT+15‰+Anes.의 8개 실험구를 2반복으로 설정하여 경북울진∼부산까지 약 400 km (6시간)를 차량수송하였다. 수송용기는 스티로폼상자(66×42×20 cnn)로서, 여기에 해수 3 L와 액화산소를 넣은 비닐봉지에 넙치 8마리씩 수용하여 수송하였다. 혈액의 성상 및 분석항목은 수송전ㆍ후에 채혈하여 비교하였다. 수송전 hematocrit는 22.2±3.8%에서 수송후 NWT+35‰에서 15.3+3.9%, CWT+35‰은 16.7±3.0%, NWT+15‰구에서는 19.2±1.8%로 낮아졌으며, CWT+15‰구는 20.9±3.6%로 수송전과 차이가 없었다. 한편 NWT+15‰+Anes.구는 17.8±0.9%, CWT+15‰+Anes.구는 14.5±1.5%로 낮아졌다. Cortisol은 수송전 2.4±0.1 ng/ml로부터 CWT+35‰구는 16.7±12.8 ng/ml, NWT+35‰구는 47.9+19.8 ng/ml, NWT+15‰구는 43.5±13.9 ng/ml, CWT+15‰구는 26.1±8.3 ng/ml, NWT+15‰+Anes.구는 61.7±3.3 ng/ml, CWT+15‰+Anes.구는 86.1±19.0 ng/ml로 높아졌다. Glucose는 수송전 74.2±32.6 mg/dl로부터 NWT+35‰구는 197.9±27.5 mg/dl, CWT+35‰구도 272.1±29.9 mg/dl로 유의하게 높아졌다. Na/sup +/의 수송전 농도는 163.5±0.6 mEq/L로부터 NWT+35‰구와 CWT+35‰구는 각각 175.3±1.2 mEq/L, 190.0±5.0 mEq/L로 높아졌으며, 다른 실험구에서는 차이가 없었다. 본 연구 결과, cortisol과 glucose에서 수송전보다는 모든 실험구에서 높게

  • PDF

광산폐기물과 폴리머를 이용한 Liner 개발에 관한 연구 (A Study on Development of a Liner Manufactured by Mine Wastes and Polymer)

  • 진호일
    • 자원환경지질
    • /
    • 제33권2호
    • /
    • pp.139-146
    • /
    • 2000
  • Development of an effective liner by utilization of the tailings frm the Imcheon mine and polymer has been tried. The tailings piled in the Imcheon mine, whose true specific gravity is about 2.86, are composed mainly of quartz, alkali-feldspar, muscovite and pyrite, and mostly (93.7% in volume) coarser than sand grain size (50${\mu}{\textrm}{m}$). Strength, leaching and permeability tests have been performed on the test specimens of polymer concrete manufactured with various mixing proportions of tailings, unsaturated polyester resins(UPR), calcium carbonates, stone powder sludges and granite soils. Polymer concrete specimens with stone powder sludges or granite soils as fillers and aggregates indicate 2.5 to 3 fold higher flexural and compressive strengths and lower permeabilities than those with calcium carbonates, which shows their usability as a waterproof liner. Also, the polymer concrete liner with stone powder sludge fillers is more advisable in aspects of utilization of waste sludges than that with other fillers.

  • PDF

무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 모르타르의 내화학성 (Chemical resistance of Non-Sintered Cement Mortar using Inorganic Industrial Wastes as activator)

  • 문경주;이철웅;박원춘;소양섭
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
    • /
    • pp.607-610
    • /
    • 2005
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by $CO_2$ discharge, and reduction of the production cost. This research investigates the chemical resistance of NSC mortar added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chemical resistance, showed that NSC is very excellent in acid resistance and seawater resistanc. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

  • PDF

무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 콘크리트의 염소이온 침투 저항성 (Chloride ion Permeability of Non-Sintered Cement Concrete using Inorganic Industrial Wastes as activator)

  • 문경주;이철웅;박원춘;소승영;소양섭
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
    • /
    • pp.453-456
    • /
    • 2006
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by CO2 discharge, and reduction of the production cost. This research investigates the chloride ion permeability of NSC concrete added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chloride ion permeability, showed that NSC is very excellent in seawater resistance. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

  • PDF

굴껍질을 이용한 도금폐수의 중화 및 중금속 이온 제거 (Neutralization and removal of heavy metal ions in Plating wastewater utilizing Oyster Shells)

  • 성낙창;김은호;김정권;김형석
    • 한국환경보건학회지
    • /
    • 제22권3호
    • /
    • pp.81-87
    • /
    • 1996
  • The purpose of this research is to examine the utilization of oyster shells for neutralization and removal of heavy metal ions in plating wastewater, because oyster shells have been known to be very porous, to have high specific surface area and to have alkaline minerals such as calcium and magnesium. The results obtianed from this research showed that oyster shells had a buffer capacity to neutralize an acidic.alkali system in plating wastewater. Generally, it could be showed that the removal efficiencies of heavy metal ions were very influenced by reaction times and oyster shell dosages. In point of ocean waste, if oyster shells substituted for a valuable adsorbent such as actviated carbon, they could look forward to an expected economical effect.

  • PDF

미생물을 이용한 미역줄기에서 알긴산염 추출 및 저분자화 (Extraction and Degradation of Alginate from Brown Seaweed Stem Using Microorganism)

  • 안성준;김영숙;박권필
    • 한국환경과학회지
    • /
    • 제13권12호
    • /
    • pp.1139-1144
    • /
    • 2004
  • We studied a extraction and degradation of alginate from seaweed-stems using microorganism DS-02. DS-02 has a maximum growth rate at $30^{\circ}C$ and the enzyme has a maximum activity of alginate extraction at $35^{\circ}C.$ The yield of alginate extraction using DS-02 is about $16.0{\%}$ for 3.0 hour and molecular weight of the alginate decreased to about 1/8 of initial value after 24 hour extraction. Alginate extraction method by DS-02, compared with general alkali-extraction method, has an advantage of decreasing the molecular weight of alginate during extraction.

비소성시멘트를 사용한 고강도 콘크리트의 현장적용을 위한 모의부재에 관한 연구 (Study on Mock-up test for field application of High Strength Concrete using Non-Sintered Cement)

  • 김한식;한다희;김광기;백민수;문경주;정상진
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2006년도 추계 학술논문 발표대회 논문집
    • /
    • pp.33-36
    • /
    • 2006
  • This Study is based on manufacture non-sintering cement(NSC) by adding phosphogysum and waste lime to GBFS as sulfate and alkali activators. This study also investigates the basic physical properties and duality of NSC, and evaluates its reusing possibility as construction materials. Therefore, we design 40MPa and 60MPa for compressive strength using OPC and NSC by binder. And There is a purpose to present fundamental data, applying in field and analyzing quality control of concrete using NSC according to rate of replace between OPC and NSC.

  • PDF

비소성 시멘트 경화체의 공극구조 (Pore Structure of Non-Sintered Cement Matrix)

  • 문경주;박원춘;소양섭
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
    • /
    • pp.329-332
    • /
    • 2004
  • This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the pore structure of NSC Matrix. The result of experiment of pore structure properties, showed no considerable difference for total pore volume by cement mixing ratio but shows a large distinction in distribution of pore diameter. On the whole, pore-diameter of paste of NSC show that occupation ratio of pore diameter below 10mm is larger and is smaller than OPC and BFSC at pore diameter of over 10nm. Such a reason is that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

  • PDF

드라이아이스로 탄산화 처리한 순환골재의 pH 특성 (pH Characteristics of the Recycled Aggregate Being carbonated by Dry Ice)

  • 홍성록;복영재;성종현;이일선;김진만
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2013년도 춘계 학술논문 발표대회
    • /
    • pp.337-338
    • /
    • 2013
  • Recent research is needed for the reduction of the pH of the recycled aggregates, recycled aggregates for alkali social problems have emerged. This was confirmed through preliminary experiments using a self-made reactor with dry ice, the possibility of reducing the pH of the recycled aggregates. The pH reduction of coarse recycled aggregates plant was made to apply the field to the middle of construction waste treatment process to reduce the pH of the plant room, and measured the pH change with time. The measurement results showed that dry ice after the reaction, the pH of the aggregate 5% reduction than untreated recycled aggregates.

  • PDF

Preparation and Evaluation of Chitin Derivatives and Their Utilization for Waste-water Treatement

  • Aly, Aly Sayed;Jeon, Byeong-Dae;Kim, Young-Jun;Park, Yun-Heum
    • 한국섬유공학회:학술대회논문집
    • /
    • 한국섬유공학회 1996년도 추계 학술발표회
    • /
    • pp.53-58
    • /
    • 1996
  • The Chitin Thiocarbonate-Fe(II)-H2O2 redox initiator system was investigated for the graft copolymerization of acrylonitrile(AN) and acrylic acid(AA) monomers onto chitin powder. The reactions with vinyl monomers onto chitin were carried out under various the graft copolymerization conditions to elucidate the polymerization behavior in terms of graft yield. Reactions of chitin-acrylonitrile graft copolymer with hydroxyl amine hydrochloride and those with sodium hydroxide were conducted in order to obtain chitin-(amidoxime-co-acrylonitrile) and chitin-(acrylate-co-acrylamide) graft copolymers, respectively. The reaction efficiency was observed to depend on the alkali concentration, time, temperature, and the reactant concentrations. The prepared chitin derivatives were evaluated to find potential applications for use in wastewater treatments for adsorption and desorption of heavy metal ions as well as acidic and basic dyes.

  • PDF