• Title/Summary/Keyword: volume specific resistance

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Fabrication of Organic Electrolytes for Electric Double Layer Capacitor with Activated Carbon Cloth Electrode (활성탄소계 섬유포 전극을 이용한 전기이중층 커패시터용 유기 전해액의 제조)

  • 강안수
    • Journal of the Korea Safety Management & Science
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    • v.2 no.2
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    • pp.95-108
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    • 2000
  • Electrochemical charateristics of activated carbon fiber cloth(ACFC) electrode were studied with propylene carbonate(PC), ${\gamma}$-butyrolactone(GBL) and N,N-dimethyl-formamide(DMF) as a solvent and tetraethylammoniumtetrafluoroborate(TEABF$_4$), tetraethylammoniumhexafluorophosphate(TEABF$_{6}$), tetrabutylammoniumtetrafluoroborate(TBABF$_4$) and tetrabutylammonium hexafluorophosphate(TBAPF$_6$) as an electrolytes(active material). The concentrations of electrolytes were in the range of 0.2~1.2 N, the volume ratios of PC and DMF as a mixed solvent system, were 90:10, 80:20, 70:30, 60:40, 50:50, and 40:60 vol%. Electrochemical characteristics such as electric conductivity, internal resistance, and electric capacitance of fabricated unit cells were measured after the moisture of activated material was removed with molecular sieve. Electrochemical characteristics were better in mixed solvents system than in mono solvent system. The mono solvent system of 1.0 N electrolyte of GBL/TEABF$_4$ with activated carbon cloth electrodes showed better result but the mixed solvent system with PC and DMF/TEABF$_4$(50:50 vol%) and the concentration of 1.0 N electrolyte showed the best characteristics. Internal resistance was 3.47 $\Omega$ and specific capacitance was 19.1 F/g respectively.y.

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Effect of Thermal Post-Treatment using the Black Body Networking of Carbon Nano Structure For Internal Conduction from Solar Radiation (태양복사열 내부전도 성능향상을 위한 탄소 나노구조체 흑체코팅 열처리 효과연구)

  • Kim, Dae Weon;Jang, Seong Min;Lee, Du Hui;Park, June Yi;Kim, Young Bae
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.4
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    • pp.159-164
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    • 2021
  • The Improvement of thermal performance using heat treatment of carbon nanotubes coated on the copper heat sink to take the radiation energy from solar ray for the energy harvesting in earth orbit. Using the additive coating of purified CNT for the increase of specific area and development of thermal conductive capacity, the performance of heat transfer is improved about 0.181 K/W while applying the power of 22 W under temperature of 3.98℃. Coating of purified CNT shows increase of area and volume of thermal layer however it led the partial thermal resistance.

A Study on Corrosive Wear Characteristics and the Mechanism of Austempered Low-Alloy Ductile Iron (오스템퍼링 한 저합금구상흑연주철의 부식마멸특성 및 그 기구에 관한 연구)

  • 박흥식;진동규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1404-1411
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    • 1993
  • This study was undertaken to investigate the corrosive wear charateristics upon various transformation condition of austempered low-alloy ductile cast iron in corrosive environments against mating specimen made of the hardened SM45C. The corrosive wear test was carried out by rubbing the annular surface of two test pieces in distilled water and aqueous solution at constant sliding speed of 0.5m/s. In severe wear region, the corrosive wear rate Wc increased hastily with NaCl concentration owing to intermetallic adhesion but Wc went down slowly in mild wear region due to lubricating effect of the corrosion product. The critical sliding distance decreased with increasing NaCl concentration due to increased generation rate of the corrosion product and the specific corrosive wear rate has maximum in 1% NaCl aqueous solution at mild wear region. With the variation of matrix, the corrosive wear resistance of the fine acicular bainite was higher than that of coarse upper bainite because of reducing the local cell reaction by carbides. A growth in volume fraction of retained austenite in matrix increased the Wc due to soften surface, but has a declining tendency of Wc in mild wear region.

Electrochemical Performance of Activated Carbon Electrode Materials with Various Post Treatments for EDLC (활성탄의 후 처리에 의한 EDLC 전극재의 전기화학 성능 개선)

  • Lee, Eunji;Kwon, Soon Hyung;Choi, Pooreum;Jung, Ji Chul;Kim, Myung-Soo
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.285-292
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    • 2014
  • Commercial activated-carbon used as the electrode material of an electric double-layer capacitor (EDLC) was posttreated with various acids and alkalis to increase its capacitance. The carbon samples prepared were then heat-treated in order to control the amount of acidic functional groups formed by the acid treatments. Coin-type EDLC cells with two symmetric carbon electrodes were assembled using the prepared carbon materials and an organic electrolyte. The electrochemical performance of the EDLC was measured by galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the various activated carbons, the carbon electrodes (CSsb800) prepared by the treatments of coconutshell-based carbon activated with NaOH and $H_3BO_5$, and then heat treated at $800^{\circ}C$ under a flow of nitrogen gas, showed relatively good electrochemical performance. Although the specific-surface-area of the carbon-electrode material ($1,096m^2/g$) was less than that of pristine activated-carbon ($1,122m^2/g$), the meso-pore volume increased after the combined chemical and heat treatments. The specific capacitance of the EDLC increased from 59.6 to 74.8 F/g (26%) after those post treatments. The equivalent series resistance of EDLC using CSsb800 as electrode was much lower than that of EDLC using pristine activated carbon. Therefore, CSsb800 exhibited superior electrochemical performance at high scan rates due to its low internal resistance.

Fretting Wear Evaluation of TiAIN Coated Nuclear Fuel Rod Cladding Materials (TiAIN 코팅한 핵연료봉 피복재의 프레팅 마멸 평가)

  • Kim, Tae-Hyeong;Kim, Seok-Sam
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.88-95
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    • 2002
  • Fretting of fuel rod cladding material, Zircaloy-4 Tube, in PWR nuclear power plants must be reduced and avoided. Nowadays the introduction of surface treatments or coatings is expected to bean ideal solution to fretting damage since fretting is closely related to wear, corrosion and fatigue. Therefore, in this study the fretting wear experiment was peformed using TiAIN coated Zircaloy-4 tube as the fuel rod cladding and uncoated Zircaioy-4 tube as one of grids, especially concentrating on the sliding component. Fretting wear resistance of TiAIN coated Zircaloy-4 tubes was improved compared with that of TiN coated tubes and uncoated tubes and the fretting wear mechanisms were delamination and plastic flow following by brittle fracture at lower slip amplitude but severe oxidation and spallation of oxidative layer at higher slip amplitude.

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Compound-A inhibited the Asthmatic Responses in the Conscious Guinea Pigs

  • Lee, Ji-Yun;Lee, Jin-Hee;Kim, Youn-Joung;Sim, Sang-Soo;Kim, Chang-Jong
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.127.1-127.1
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    • 2003
  • Effect of Compound-A, a phenylpropanoid isolated from Arctium lappa fruit, on the early- (EAR) and late-phase asthmatic responses (LAR) of guinea pigs were studied in vivo. Guinea pigs were sensitized by injection of 100 mg of ovalbumin (OA). Twenty-one days after sensitization, animals were challenged with exposure to aerosolized 1 % OA for five minutes in double-chambered plethysmograph box with jet nubulizer. Immediately and twenty-four hours after challenge, EAR and LAR ashmatic responses were determined the tidal volume (TV), respiration rate (RR) and specific airway resistance (sRaw), and then animals anethetized and taken the bronchoalveolar lavage fluid (BALF) by lavage the lung with HEPES buffer through cannulation into trachea. (omitted)

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Expression, Purification, Crystallization and Preliminary X-Ray Crystallographic Analysis of CnrX from Cupriavidus metallidurans CH34

  • Kim, Kook-Han;Jung, Eun-Jung;Im, Ha-Na;Lelie, Daniel Van Der;Kim, Eunice Eun-Kyeong
    • Journal of Microbiology and Biotechnology
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    • v.18 no.1
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    • pp.43-47
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    • 2008
  • The nickel and cobalt resistance of Cupriavidus metallidurans CH34 is mediated by the CnrCBA efflux pump encoded by the cnrYHXCBAT metal resistance determinant. The products of the three genes cnrYXH transcriptionally regulate expression of cnr. CnrY and CnrX are membrane-bound proteins, probably functioning as anti-sigma factors, whereas CnrH is a cnr-specific extracytoplasmic functions (ECF) sigma factor. The periplasmic domain of CnrX (residues 29-148) was cloned as a N-terminal His-tagged protein, expressed in Escherichia coli, and purified using affinity chromatography and gel filtration. The molecular mass was estimated to be about 13.6kDa by size exclusion chromatography, corresponding to a monomer. The tetragonal bipyramid crystals were obtained by mixing an equal volume of protein in 50mM Tris-HCl, pH 7.5, 1% glycerol, 100mM NaCl, 1mM DTT, and the reservoir solution of 15% w/v PEG 2000, 100mM lithium chloride at 277K in 2-4 days using hanging drop vapor diffusion. The protein concentration was 24mg/ml. The crystal that diffracted to $2.42{\AA}$ resolution belongs to space group $P4_1\;or\;P4_3$ with unit cell parameters of $a=b=32.14{\AA},\;c=195.31{\AA},\;{\alpha}={\beta}={\gamma}=90^{\circ}$, with one molecule of CnrX in the asymmetric unit.

Durability and Performance Requirements in Canadian Cement and Concrete Standards (캐나다 시멘트 및 콘크리트의 내구성 및 제성능에 대한 규준)

  • Hooton, R.D.
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05a
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    • pp.5-21
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    • 2006
  • Traditional standards and specifications for concrete have largely been prescriptive, (or prescription-based), and can sometimes hinder innovation and in particular the use of more environmentally friendly concretes by requiring minimum cement contents and SCM replacement levels. In December 2004, the Canadian CSA A23.1-04 standard was issued which made provisions (a) for high-volume SCM concretes, (b) added new performance requirements for concrete, and (c) clearly outlined the requirements and responsibilities for use in performance-based concrete specifications. Also, in December 2003, the CSA A3000 Hydraulic Cement standard was revised. It (a) reclassified the types of cements based on performance requirements, with both Portland and blended cements meeting the same physical requirements, (b) allows the use of performance testing for assessing sulphate resistance of cementitious materials combinations, (c) includes an Annex D, which allows performance testing of new or non-traditional supplementary cementing materials. From a review of international concrete standards, it was found that one of the main concerns with performance specifications has been the lack of tests, or lack of confidence in existing tests, for judging all relevant performance concerns. Of currently used or available test methods for both fresh, hardened physical, and durability properties, it was found that although there may be no ideal testing solutions, there are a number of practical and useful tests available. Some of these were adopted in CSA A23.1-04, and it is likely that new performance tests will be added in future revisions. Other concerns with performance standards are the different perspectives on the point of testing for performance. Some concrete suppliers may prefer processes for both pre-qualifying the plant, and specific mixtures, followed only with testing only 'end-of-chute' fresh properties on-site. However, owners want to know the in-place performance of the concrete, especially with high-volume SCM concretes where placing and curing are important. Also, the contractor must be aware of, and share the responsibility for handling, constructability, curing, and scheduling issues that influence the in-place concrete properties.

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Conditioning and Dewatering Properties of Digested and Thickened Sludge with Inorganic Conditioner (무기개량제를 이용한 소화 및 농축슬러지의 개량 및 탈수 특성)

  • Kim, Jeong-Ho;Nam, Se-Yong
    • Journal of Environmental Health Sciences
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    • v.37 no.6
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    • pp.467-473
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    • 2011
  • Objectives: Wastewater treatment plants typically produce a large volume of waste sludge. In this study, the conditioning and dewatering properties of a digested and thickened sludge from an industrial wastewater treatment plant were investigated in order to improve the dewaterbility of the sludge. Methods: Jar-tests and Buchner funnel tests were carried out to assess the conditioning and dewatering properties of a waste sludge. TTF (Time to Filter Test) and SRF (Specific Resistance to Filtration) were adopted as the indices of sludge dewaterbility. Results: The valuation indices influencing the dewaterbility of the waste sludge, including TTF, SRF, water contents, VS/TS ratio and turbidity, were measured. The TTF and SRF of the digested and thickened sludge were decreased to 40 sec, $3.43{\times}10^{12}$ m/kg, and 39 sec, $1.09{\times}10^{12}$ m/kg, respectively. Conclusions: The conditioner composed of natural inorganic materials turned out to be effective in the reduction of sludge water contents.

Inhibitory effects of 2,6-di-tert-butyl-4-hydroxymethylphenol on asthmatic responses to ovalbumin challenge in conscious guinea pigs

  • Jeong, Seul-Yong;Lee, Ji-Yun
    • The Korean Journal of Physiology and Pharmacology
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    • v.22 no.1
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    • pp.81-89
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    • 2018
  • This study evaluated the anti-asthmatic activities of 2,6-di-tert-butyl-4-hydroxymethylphenol (DBHP) that is a potent phenolic antioxidant in edible vegetable oil. The effects of DBHP on bronchial asthma were evaluated by determining the specific airway resistance (sRaw) and tidal volume (TV) during the immediate asthmatic response (IAR) and the late-phase asthmatic response (LAR) in guinea pigs with aerosolized ovalbumin-induced asthma. Recruitment of leukocytes and the levels of biochemical inflammatory mediators were determined in the bronchoalveolar lavage fluids (BALFs), and histopathological surveys performed in lung tissues. DBHP significantly inhibited the increased sRaw and improved the decreased TV on IAR and LAR, and also inhibited recruitment of eosinophils and neutrophils into the lung, and release of biochemical inflammatory mediators such as histamine and phospholipase $A_2$ from these infiltrated leukocytes, and improved pathological changes. However, anti-asthmatic activities of DBHP at oral doses of 12.5 to 50 mg/kg was less than those of dexamethasone (5 mg/kg, p.o.) and cromoglycate (10 mg/kg, p.o.), but more potent or similar to that of salbutamol (5 mg/kg, p.o.). These results in the present study suggest that anti-asthmatic effects of DBHP in the guinea pigs model of OVA-induced asthmatic responses principally are mediated by inhibiting the recruitments of the leukocytes and the release of biochemical inflammatory mediators from these infiltrated leukocytes.