• Title/Summary/Keyword: volume specific heat

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Combustion Characteristics and Criterion of Quenching Condition in Micro Combustor Parameterized by Initial Pressure and Fuel in the Combustor (초기 압력과 연료특성에 따른 마이크로 연소기 내에서의 연소 특성 및 소염 조건 변화)

  • Na, Han-Bee;Lee, Dae-Hoon;Kwon, Se-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.1 s.232
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    • pp.55-62
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    • 2005
  • Combustion Characteristics and quenching criteria of micro combustor in various condition was exploited experimentally. Two different gases were used, and various geometric matrixes were considered to figure out quenching characteristic of micro combustor. The micro combustor studied in this study was constant volume, and has cylindrical shape. Geometric parameter of combustor was defined to be combustor height and diameter. The effect of height was exploited parametrically as 1 mm, 2mm and 3mm and the effect of diameter was parameterized to be 7.5mm and 15mm. Three different combustibles. (1) Stoichiometric mixture of methane and are, (2) Stoichiometric mixture of hydrogen and air and (3) Mixture of hydrogen and air with fuel stoichiometry of two were used. Pressure transition during combustion process was recovered. The ratio of maximum pressure to initial pressure responded favorably with the change of height of combustor and the initial pressure, the maximum pressure was also increased. The flame propagation was observed only when a specific condition was satisfied. From the experiment the condition that guarantees stable propagation of flame was tabulated. The tabulated results includes criteria of quenching according to combustor height, combustor diameter, species of fuel and initial pressure.

Study on the Temperature Characteristic of Pressurization System Using Cryogenic Helium Gas (극저온 헬륨가스 가압시스템에 대한 온도특성 연구(I))

  • Chung Yonggahp;Kim Yoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.3
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    • pp.66-73
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    • 2005
  • The pressurization system in a liquid rocket propulsion system provides a controlled gas pressure in the ullage space of the vehicle propellant tanks. It is advantage to employ a hot gas heat exchanger in the pressurization system to increase the specific volume of the pressurant and thereby reduce over-all system weight. A significant improvement in pressurization-system performance can be achieved, particularly in a cryogenic system, where the gas supply is stored inside the cryogenic propellant tank. In this study liquid nitrogen was used instead of liquid oxygen as a simulant. The temperature characteristic of cryogenic pressurant is very important to develop some components in pressurization system. Numerical modeling and test data were studied using SINDA/FLUINT Program and PTF(Propellant-feeding Test facility).

Computational Study on Spirocyclic Compounds as Energetic Materials (I)

  • Seok, Won K.
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.989-993
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    • 2014
  • The molecular structures of 2,6-diaza-1,3,5,7-tetraoxaspiro[3,3]heptane (1) and its dinitro derivative, 2,6-dinitro-2,6-diaza-1,3,5,7-tetraoxaspiro[3,3]heptane (2), were fully optimized without symmetry constraints at $HF/6-31G^*$ level of theory. A bisected conformation with respect to the ring is preferred with a $C_2$ symmetric structure. The density of each molecule in the crystalline state was estimated to 1.12 and 2.36 $g/cm^3$ using PM3/VSTO-3G calculations from the molecular volume. The heat of formation was calculated for two compounds at the CBS-4M level of theory. The detonation parameters were computed using the EXPLO5 software: D = 6282 m/s, $P_{C-J}$ = 127 kbar for compound 1, D = 7871 m/s, $P_{C-J}$ = 307 kbar for compound 2, and D = 6975 m/s, $P_{C-J}$ = 170 kbar for 60% compound 2 with 40% TNT. Specific impulse of compound 1 in aluminized formulation when used as monopropellants was very similar to that of the conventional ammonium perchlorate in the same formulation of aluminum.

Basic Model for Propellant Tank Ullage Calculation (추진제탱크 얼리지 해석을 위한 기본모델)

  • Kwon, Oh-Sung;Cho, Nam-Kyung;Cho, In-Hyun
    • Aerospace Engineering and Technology
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    • v.9 no.1
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    • pp.125-132
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    • 2010
  • Estimation of pressurant mass flowrate and its total mass required to maintain propellant tank pressure during propellant outflow is very important for design of pressurization control system and pressurant storage tank. Especially, more pressurant mass is required to maintain pressure in cryogenic propellant tank, because of reduced specific volume of pressurant due to heat transfer between pressurant and tank wall. So, basic model for propellant tank ullage calculation was proposed to estimate ullage and tank wall temperature distribution, required pressurant mass, and energy distribution of pressurant in ullage. Both test and theoretical analysis have been conducted, but only theoretical modeling method was addressed in this paper.

Changes in Physical and Mechanical Properties of Freon-Adsorbed and Heat - Treated Leaf Tobacco (Freon Gas흡착 및 열처리에 의한 담배조직의 물리적, 역학적 특성변화연구)

  • Kim, Ki-Hwan;Yoo, Kwang-Kun;Joo, Young-Serg
    • Journal of the Korean Society of Tobacco Science
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    • v.6 no.1
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    • pp.39-49
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    • 1984
  • In the tobacco industry, it is important to study the change of mechanical property occurring the expansion process. The purpose of this study is to attain basic data for development of a tobacco expansion method. 1 . Freon gas was adsorbed to tobacco under various conditions of temperature, relative humidity and pressure, and then the amount of freon gas adsorbed was analyzed by GC. Freon adsorption rate of Burley 21 was more than that of By104 at the same condition and about 17 $\pm$ 1% moisture content produced better adsorption rate. 2. Freon adsorbed sample were heated to about $150^{circ}C\;to\;230^{\circ}C$ in a drying oven and recycle duct form about 2 to 30 seconds, and then the change of mechanical property were measured. Heated leaf was damaged when the tissue was pressed by the force of above $0.5x10^8dyn/cm^2$. The optimum condition of no damage of the sample was below the temperature of 15$0^{\circ}C$ and heating time of 10 seconds. It was more economically advantages to treated sample in a recycle duct than to be in a drying oven. By this process, the specific volume of the heated sample was increased from 80 to 110 percent in comparison to that of untreated sample.

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Development of New Ni-based Cast Superalloy with Low Density and High Temperature Capability for Turbine Wheel in Automotive Turbocharger (자동차 터보충전기 터빈휠용 경량 고내열 주조 Ni기 초합금의 개발)

  • Yutaro Oki;Yoshinori Sumi;Yoshihiko Koyanagi
    • Journal of Korea Foundry Society
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    • v.42 no.6
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    • pp.392-397
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    • 2022
  • In order to compliant the stringent exhaust emission regulations, higher fuel efficiency and cleaner exhaust gas in combustion engines have been required. To improve combustion efficiency, an exhaust gas temperature is increasing, therefore higher temperature resistance is required for components in exhaust system, especially turbine wheel in turbocharger. IN100 looks quite attractive candidate as it has high temperature properties with low density, however it has low castability due to poor ductility at high temperature. In this study, the balance of Al and Ti composition was optimized from the base alloy IN100 to improve the high temperature ductility by expanding the γ single phase region below the solidification temperature, while obtaining the high temperature strength by maintaining the volume fraction of γ' phase equivalent to IN100 around 1000℃. Furthermore, the high temperature creep rupture life increased by adding a small amount of Ta. The alloy developed in this study has high castability, low density and high specific strength at high temperature.

A Comparative Study on Diesel Engine Performance with Higher Alcohol-diesel Blends (고탄소알코올/경유 혼합유를 이용한 디젤엔진 성능 특성 비교 )

  • JAESUNG KWON;JEONGHYEON YANG;BEOMSOO KIM
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.767-772
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    • 2023
  • In this study, combustion experiments were conducted at various engine speeds under full-load conditions using a single-cylinder diesel engine by blending butanol, pentanol, and octanol with diesel at a volume ratio of 10%. Experimental results revealed that higher alcohol-diesel blends resulted in lower brake torque and brake power than pure diesel due to the lower calorific value and the cooling effect during evaporation. An evident improvement in the brake thermal efficiency of the blended fuels was observed at engine speeds below 2,000 rpm, with the butanol blend exhibiting the highest thermal efficiency overall. Furthermore, the brake-specific fuel consumption of the higher alcohol-diesel blends was lower than that of pure diesel at speeds below 2,200 rpm. When using blended fuels, the exhaust gas temperature decreased under lean mixture conditions due to heat loss to the air and the cooling effect from fuel evaporation.

Preparation of Glass-Ceramics in $Li_2O-Al_2O_3-TiO_2-SiO_2$ System by Sol-Gel Technique : (II) Crystallization of $Li_2O-Al_2O_3-TiO_2-SiO_2$ Monolithic Gel Prepared by Sol-Gel Method (Sol-Gel 법에 의한 $Li_2O-Al_2O_3-TiO_2-SiO_2$ 계 다공성 결정화 유리의 제조 : (II) Sol-Gel 법에 의해 제조된 $Li_2O-Al_2O_3-TiO_2-SiO_2$ 계 괴상겔의 결정화)

  • 조훈성;양중식
    • Journal of the Korean Ceramic Society
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    • v.32 no.4
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    • pp.507-515
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    • 1995
  • The monolithic dry gels of the Li2O-Al2O3-TiO2-SiO2 system were prepared by the sol-gel technique using metal alkoxides as starting materials to obtain monolithic glass-ceramics at low temperature without melting. Activation energy for the crystal growth of the gel with 6.05% TiO2, nucleating ageng, for the preparation of Li2O-Al2O3-TiO2-SiO2 system glass-ceramic was 101.14kcal/mol. As a result of the analysis of DTA & XRD, it was confirmed that the crytallization of Li2O-Al2O3-TiO2-SiO2 system glass-ceramic was the most efficient when 6.05% TiO2, nucleating agent, was added. $\beta$-eucryptite solid solution crystals and $\beta$-spodumene solid solution crystals were detected in the sample heat treated above 85$0^{\circ}C$. The sintered gel heat treated at 85$0^{\circ}C$ had the specific surface area of 185$m^2$/g, the pore volume of 0.19cc/g and the average pore radius of 20.8$\AA$. This shows that the sintered gel is also comparatively porous material. In temperature range of 25~85$0^{\circ}C$ thermal expansion coefficient of the specimen which was crystallized for 10hrs at 85$0^{\circ}C$ was 6.7$\times$10-7/$^{\circ}C$, which indicated that the crystallized specimen was turned out to be the glass-ceramic with low thermal expansion.

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Natural Gas Sorption Using Activated-Carbon with Surface Treatment (활성탄의 표면처리에 의한 천연가스 흡장)

  • Yun, Seok-Min;Kim, Ju-Wan;Im, Ji-Sun;Kim, Shin-Dong;Hong, Ji-Sook;Suh, Jeong-Kwon;Lee, Young-Seak
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.4
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    • pp.434-439
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    • 2006
  • In this study, activated carbon(ACs) have been modified by nitric acid and heat-treatment. The surface and structure properties of ACs were determined by BET surface area, FT-IR pH and acid/base value. The changes in pore structure and surface properties of these modified ACs were correlated with natural gas adsorption which measured by volumetric apparatus at $0^{\circ}C$ and $25^{\circ}C$. The pore textural properties of activated carbon was also characterized by nitrogen adsorption at 77 K. Specific surface area and micropore volume of them were calculated by Langmuir equation and Horvath-Kawazoe method, and chemical properties of surface were measured by FT-IR and titration of acid and base solutions. Pore texture of activated carbons after treatments were not significantly changed. Total acidity increased and basicity of samples decreased. however the basicity increased with heat treatment. The methane adsorption of ACs become different depending on the acid/base value of samples.

Effects of Alloying Elements(C, Si) and Hot-Rolling on Damping Capacity and Mechanical Properties of Fe-17%Mn Alloys (Fe-17%Mn 합금의 진동감쇠능과 기계적 성질에 미치는 합금원소(C, Si) 및 열간압연의 영향)

  • Kim, J.C.;Han, D.W.;Back, J.H.;Kim, T.H.;Baik, S.H.;Lee, Y.K.
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.2
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    • pp.99-104
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    • 2005
  • In this study, the effects of C and Si on damping capacity and mechanical properties of as-cast and as-rolled Fe-17%Mn alloys were investigated as a basic study for the purpose of the commercialization of the alloy. The $M_s$ temperature of ${\gamma}{\rightarrow}{\varepsilon}$ martensitic transformation in Fe-17%Mn alloy was decreased with increasing C and Si contents, resulting in the less volume fraction of ${\varepsilon}$ martensite. The damping capacity was also decreased with increasing alloying content because of less ${\varepsilon}$ amount and the reduction in mobility of the damping sources such as the stacking fault boundaries and ${\gamma}/{\varepsilon}$ interfaces due to the pinning effect by alloying elements. The mechanical properties of as-rolled alloys were superior to those of as-cast alloys probably because of finer ${\gamma}$ grains, larger amount of ${\varepsilon}$ martensite, and chemical homogeneity.