• Journal of the Korean Ceramic Society
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• v.26 no.5
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• pp.705-711
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• 1989

The glass-ceramics was prepared with the scoria(CaO-MgO-Al2O3-SiO2 system) of the locally occurring volcanic ejecta containing 10-13w/o of (FeO＋Fe2O3) by melting at 140$0^{\circ}C$ for 4 hours and thermally treated for nucleation and crystallization. The sucrose was added to the scoria to adjust the Fe2+/Fe3+ ratio during the melting process. The addition of 1-2w/o of sucrose showed the glass-ceramics body with the finest particle developed and dispersed over the entire range. It is concluded that the impurity content of iron oxide and titanium oxide play the most-influencial effect on the crystallization. When 1-2w/o of sucrose was added to the scoria, the value of Fe2+/Fe3+ ratio was 0.93-1.32 and showed the best result of crystallization. The nucleation temperature and time were calculated by the measurements of exothermic peak temperatures of DTA for quenched and thermally treated glasses. The nucleation temperature of scoria glass without the addition of sucrose was estimated as 75$0^{\circ}C$, but the addition of sucrose by 2w/o showed the nucleation temperature 6$25^{\circ}C$. The nucleation time was calculated with the same DTA curves. The nucleation times estimated were about 150min. for both of glasses without and with sucrose added. Finally, the activation energies for crystallization were calculated with the DTA data. The calculated activation energies were 143 Kcal/mole for the glass without addition of sucrose and 90Kcal/mole, 87Kcal/mole, 85Kcal/mole and 71Kcal/mole for the glasses of 1w/o, 2w/o, 3w/o and 4w/o addition respectively.

• The Journal of the Petrological Society of Korea
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• v.17 no.2
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• pp.108-131
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• 2008

The Miocene andesite and basalt intruded into and/or extruded on the Cretaceous volcanic and granitic rocks over the area of Chenjabong and Sirubong in the vicinity of Jinhae, southern part of Kyongsang basin. The K-Ar ages of the younger volcanic rocks are from 16 Ma (Sirubong andesite) to 10 Ma (Cheonjabong basalt), which indicate the Miocene volcanism in the outer part of the Tertiary basin in the Korean peninsula. The volcanics are divided into Chenjabong andesite, Cheonjabong basaltic andesite, Sirubong andesite and Cheonjabong basalt. The Cheonjabong andesite is composed of phenocrysts of clinopyroxene and plagioclase ($An_{60{\sim}64}$) and groundmass with lath-like plagioclase ($An_{76{\sim}84}$) and glass. The Cheonjabong basaltic andesite is composed of plagioclase phenocryst ($An_{60{\sim}64}$) with plagioclase lath ($An_{65}$) and glass in groundmass. The Sirubong andesite is only consisted of plagiocalse lath ($An_{64{\sim}68}$) and glass with absence of phonocryst. The Cheonjabong basalt shows typical porphyritic texture with phenocrysts of olivine ($Fo_{69-84}$) and clinopyroxene. The groundmass of the Cheonjabong basalt is composed of microphenocrysts of olivine, clinopyroxene and plagioclase ($An_{66{\sim}71}$) and plagioclase laths ($An_{57{\sim}65}$) showing pillotaxitic and intergranular texture. The Cheonjabong andesite, Cheonjabong basaltic andesite, Sirubong andesite are belong to calc-alkialine but the Cheonjabong basalt is alkaline basalt. By tectonic discrimination diagrams the parental magmas of the volcanic rocks have occurred boundary.

• Journal of the Mineralogical Society of Korea
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• v.5 no.2
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• pp.61-71
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• 1992

Through the low-temperature(60-150${\circ}C$) hydrothermal treatment of perlite with the alkaline solution at various NaOH concentrations, the mode of volcanic glass alteration and resultant zeolite formation were investigated in a closed system. At a temperature of 80${\circ}C$ and alkalinities of pH range 8 to 12, corresponding to the natural environments of diagenetic zeolite formation, only weak dissolution of perlitic glass occurs without zeolite formation despite the residence time of 100 days. Activities of Si and Al increase progressively, as a consequence of increasing pH, whereas activity ratios of Si/Al decrease. Zeolites were synthesized from perlite in the alkaline solution at above 0.1M NaOH concentrations. Below the temperature of 100${\circ}C$ Na-P was mainly formed, whereas analcime was the dominant zeolite at the temperature range of 100-150${\circ}C$. During Na-P synthesis chabazite and Na-X were also formed as by-products in case of lower proportion of solution/sample(<10ml/g) and higher NaOH concentraion (>3M), respectively. The alteration modes of perlite in the zeolite synthesis reflect that the formation of synthetic zeolites occurs as an incongruent dissolution likely with the diagenetic formation of natural zeolites from volcanic glass. Considering much difference in reaction kinetics between natural and synthetic systems, however, the evaluated synthetic conditions in these experiments were not directly applicable to the natural diagenetic system.

• Journal of International Area Studies (JIAS)
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• v.18 no.3
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• pp.145-168
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• 2014

Given the distance from Mt. Baekdu, volcanic ash will have the direct impact on South Korea in case Mt. Baekdu erupts. Ash fall deposits or particulate matters(PM10) in the air will cause damages in various sectors. In particular, the PM10 impact on the manufacturing sector when the ash disperses in Korea is needed to be assessed since South Korea's manufacturing sector accounts for more than 30% of GDP. Meanwhile the economic impacts of PM10, including Asian dust, have been researched in Korea as the events become frequent, and losses in the manufacturing have been also reported. This study is to identify vulnerable sectors to volcanic ash in the korean industry, and to assess economic losses in case of a Mt. Baekdu eruption scenario, based on the historical loss experience with particulate matters. Study results show that airline, precision such as electronics and semiconductors, distribution, shipbuilding, car, leisure, glass, dairy farming are vulnerable to volcanic ash, or PM10. The economic losses in both car and shipbuilding industry is estimated to 46.49 billion Korean won due to shutdown for 6 hours in case of a Mt. Baekdu eruption scenario.

• Advances in materials Research
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• v.4 no.3
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• pp.179-192
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• 2015

The study presents a preliminary investigation on the applicability of Shirasu (a pyroclastic flow deposit characterized by high percentage of volcanic glass) in geopolymer. Comparative study on compressive strength and internal pore structure has been done between geopolymers with alkali activated Shirasu and fly ash as aluminosilicates. Mortar mix proportions are selected based on variations in ratio of alkaline activators to aluminosilicate and also on silica to alkali hydroxide ratio. From the experimental study, Shirasu geopolymer exhibited fairly good compressive strength. Mix proportion based on silica to alkali hydroxide ratio is observed to have profound effect on strength development.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.40 no.3
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• pp.160-166
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• 2007

The coarse deposit with a lower mud content adjacent to the shelf of the southern East Sea is probably a "relict" sediment deposited in response to a lower stand of sea level during the Pleistocene. The sediment that developed on the slope and in the deep sea was river-borne primarily and was secondarily reworked or redistributed by the Tsushima Warm Current from the East China Sea. The clay mineralogy of the area suggests various sources of fine-grained sediment from adjacent rivers, the Korea Strait, volcanic material from Ulleung Island, and the Japan coast. Massive sand, bioturbated mud, homogeneous mud, and laminated mud were the dominant facies found in the core sediments from the study area. The massive sand was mainly volcanic ash from an eruption on Ulleung Island (9300 yr BP) and consisted of colorless pumiceous glass and a black scoriaceous type. The sedimentation rates on the slope, based on the Ulleung-Oki ash layer, were about 10cm/ky higher than in the basin. Other than the coarse-grain sediment, the mean size of the fine sediment dominating the bioturbated and homogeneous muds in the basin and the laminated mud on the slope was 6-10 phi. This indicates a difference in the major sedimentary process: hemipelagic sedimentation in the Ulleung Basin and mass flow deposition, such as turbidite, on the slope of the southern East Sea.

• Journal of the Mineralogical Society of Korea
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• v.18 no.4 s.46
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• pp.277-288
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• 2005

Perlite, a hydrated volcanic glass, occurs mainly as a bed-like body, and is distributed intermittently along the unconformity surface between the Beomgockri Group and its lower formations, viz. Janggi Group. The perlite is intimately associated with surrounding pumiceous welded tuff and rhyodacites in space and time. Compared to the typical perlite, the perlite is rather silica-poor and impure, and thus, includes lots of phenocrysts and rock fragments. Nearly the perlite is compositionally rather close to a pitchstone than a perlite in water contents. Petrographic comparison between perlite and associated volcanic to volcaniclastic rocks indicates that pumiceous welded tuff and rhyodacite seem to be Protolith of the Perlite. A Zr/$TiO_{2}$-Nb/Y diagram and field occurrence of perlite and their protolithic rocks also conforms the above interpretation. Kn addition, remnant vesicles in perlite strongly reflect that the precursor of perlitic glass appeared to be pumice fragment as well as volcanic glass. The perlite was diagenetically formed by way of a pervasive water-rock interaction at the deposition of the Manghaesan Formation in lacustrine environment. During perlitization, $SiO_{2}$ and alkali tend to be consistently depleted. Preexisting system of the Beomgockri Group based on the perlite formation should be corrected, because the perlite was formed diagenetically without lateral persistence in its occurrence.

• Journal of the Mineralogical Society of Korea
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• v.25 no.2
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• pp.63-76
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• 2012

Tachylite, black basaltic glass formed by the rapid cooling of molten basalt, locally occurs at the Basaltic Agglomerate Formation (BAF), the lowest formation of Ulleung Island. The purposes of this study are to characterize the occurrence and mineralogy of tachylite and to elucidate its formation condition, with emphasis on its fracture pattern, which can serve as implications for the early volcanic activity of Ulleung Island. To this end, we investigated the occurrence pattern of tachylite in the field and carried out mineralogical analyses using optical microscope, XRD, EPMA, and SEM. Tachylite occurs at the chilled margin of basic dikes which are distributed in Naesujeon, Dodong and Jeodong seasides, Turtle Rock, and Yaerimwon, whose widths vary from several cm to 10 cm. It is evident that the outer surface of tachylite is dense and smooth, whereas the inner surface, if fractured, is characterized by conchoidal fracture. The matrix of tachylite consists of amorphous, glass and some fine-grained phenocrysts present in tachylite include biotite, anorthoclase, sanidine, plagioclase, hornblende, and Fe-Ti oxides. The fracture patterns characteristic of tachylite are subrounded, oval, or less commonly polygonal, bounded by joints to form globule or lump. Taking into account texture and mineralogy, tachylite is interpreted to have undergone little subsequent alteration at low temperature via hydration or hydrolysis that could form clay minerals after it was formed. Because tachylite with peculiar fractures occurs as dikes in a close association with BAF, its presence is considered as reliable evidence that when tachylite formed, the most part of BAF was still under subaqueous conditions, or at least saturated with seawater.

• Journal of the Mineralogical Society of Korea
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• v.23 no.1
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• pp.39-50
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• 2010

Zeolites were formed by the alteration of volcanic glass in the volcaniclastics including tuff cone/rings and subsurface Seoguipo Formation, Jeju Island. Phillipsite and analcime were identified by X-ray diffraction and electron microprobe analysis. Si/(Si+Al) atom ratios of analcime and phillipsite were similar to that of parent basaltic glass. In comparison with the simple chemistry of analcime, phillipsite showed a range of cavity cation compositions. Na is the major cavity cations of phillipsite in the Dangsanbong and Yongmeori tuffs bearing analcime, while K and Ca in core samples of Seoguipo Formation. Microtextural analysis by scanning electron microscope showed a general sequence that early phillipsite encrustification of pores was followed by later analcime infilling. Zeolites are abundant in the older tuff cone/rings but nearly absent in the younger ones.

• Journal of the Mineralogical Society of Korea
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• v.16 no.2
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• pp.181-189
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• 2003

Diverse microtextures and secondary minerals formed by chemical weathering were observed in the glacial debris of King George Island. Weathering rind was observed in the block of basaltic andesite tuff due to dissolution of calcite producing voids. Eolian volcanic glass altered to mixtrure of allophane-like materials and iron oxyhydroxides at grain edges with relative concentration of Al. Fe, and Ti. Biotite in granodiorite area was transfarmed to vermiculite and interstratified biotite-vermiculite or very rarely to kaolinite and gibbsite. Pyrite in the hydrothermal alteration zone was repalced by iron oxides, resulting in sulfuric acid which locally accelerated alteration of chlorite to expandable clay minerals. Weathering of plagiociase and K-feldspar was negligible. Although glacial debris of the Barton Peninsula has undergone weak chemical weathering with formation of some secondary minerals, massive formation of smectite, abundant in nearby marine sediments, didn't occur.