• Bulletin of the Korean Chemical Society
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• 제19권12호
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• pp.1359-1363
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• 1998

The p-fluorobenzyl radical was generated from the p-fluorotoluene and vibronically excited in a corona excited supersonic expansion with inert buffer gases. The vibronic emission spectra of the jet cooled p-fluorobenzyl radical in the D1 → D0 transition have been observed in the visible region. The spectra exhibit several low frequency sequence bands in the vicinity of the every strong vibronic band. The characteristics of the sequence bands have been examined by varying the experimental conditions such as carrier gas and nozzle size to identify the origin of the transition in the spectra.

• 한국측량학회지
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• 제39권3호
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• pp.203-209
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• 2021

최근 위성센서 기술의 발전함에 따라 다양한 분광파장대의 고해상도 영상 취득이 가능해졌다. Worldview-3 위성센서는 높은 공간해상도를 지닌 panchromatic 영상과 함께 낮은 공간해상도를 지닌 VNIR (Visible Near InfraRed), SWIR (ShortWave InfraRed) 밴드들을 제공하고 있어, 국방, 환경, 측량 등 다양한 분야에서 활용이 가능하다. 본 연구에서는 Worldview-3 위성영상을 활용하여 광물탐지를 수행하였다. Worldview-3 위성영상의 VNIR, SWIR 밴드들을 효과적으로 활용하기 위해 융합기법을 적용을 통해 panchromatic 영상의 공간해상도로 융합하여 광물탐지에 이용하였다. 광물탐지에 SWIR 밴드들의 활용성을 확인하기 위해 VNIR 밴드들만을 활용한 광물탐지를 수행하여 비교평가하였다. 광물탐지 기법으로는 대표적인 유사도 기법인 SAM (Spectral Angle Mapper)을 적용하였으며, 분석 결과에 경험적 임계치를 적용하여 광물로 탐지되는 화소들을 선정하였다. 광물탐지의 정확도 평가를 위해 유사도 분석을 수행한 결과에 참조자료를 이용하여 정량적평가를 수행하였다. 정확도 평가 결과, SWIR 밴드들을 활용한 광물탐지 결과의 탐지율과 오탐지율이 각각 0.882, 0.011로 계산되었으며, VNIR 밴드들만을 활용한 결과는 각각 0.891, 0.037로 나타났다. SWIR 밴드를 추가적으로 활용한 경우의 탐지율이 VNIR 밴드만을 사용한 경우보다 다소 낮은 것으로 나타났지만, 오탐지율이 크게 감소한 것으로 나타나, 이를 통해 광물탐지에서의 SWIR 밴드들의 활용가능성을 확인할 수 있었다.

• 한국측량학회지
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• 제38권5호
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• pp.435-441
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• 2020

Sentinel-2A satellite imagery provides VNIR (Visible Near InfraRed) and SWIR (ShortWave InfraRed) wavelength bands, and it is known to be effective for land cover classification, cloud detection, and environmental monitoring. Greenhouse is one of the middle classification classes for land cover map provided by the Ministry of Environment of the Republic of Korea. Since greenhouse is a class that has a lot of changes due to natural disasters such as storm and flood damage, there is a limit to updating the greenhouse at a rapid cycle in the land cover map. In the present study, we utilized Sentinel-2A satellite images that provide both VNIR and SWIR bands for the detection of greenhouse. To utilize Sentinel-2A satellite images for the detection of greenhouse, we produced high-resolution SWIR bands applying to the fusion technique performed in two stages and carried out the detection of greenhouse using SVM (Support Vector Machine) supervised classification technique. In order to analyze the applicability of SWIR bands to greenhouse detection, comparative evaluation was performed using the detection results applying only VNIR bands. As a results of quantitative and qualitative evaluation, the result of detection by additionally applying SWIR bands was found to be superior to the result of applying only VNIR bands.

• 한국통신학회논문지
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• 제17권1호
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• pp.58-67
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• 1992

MgGa2Se4 및 MgGa2Se4 : Co2+단결정을 bridgman 방법으로 성장하여 광흡수와 광발광을 가시광 영역과 근적외선 영역에서 조사하였다. 광흡수 스펙트럼은 MgGa2Se4단결정의 Td Symmetry를 갖는 host lattice에 점유하여 바닥상태와 여기상태의 Co2+ ion 에너지 ㅣlevel간 전자전이에 의해서 760nm, 1640nm, 그리고 2500nm에서 3개의 흡수피크를 관측하였다. 광발광 스펙트럼에서 이 단결정은 가시광 발광ㄸ들을 관찰하였다.가시영역의 발광 band들은 에너지 준위도에서 제안된 바와 같이 자전자대의 우의 꼭대기 acceptor 준위에서 전도대 아래의 밑에 분포된 trap으로부터 끊임없이 전자전에 의한다고 볼수 있다. 한편, 이들은 적외선 발광 band가 deep level에서 acceptor level부터 전자전이에 기인한다고 고려할 수 있다. 광전이의 mechanism은 MgGa2Se4 결정의 에너지 diagram의 항으로 잘 설명되고 있다.

• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.763-767
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• 2013

We resolved the controversial assignments of the visible vibronic bands observed from corona discharge of 1,2,3-trimethylbenzene. The vibronic bands belonging to the jet-cooled 2,6-dimethylbenzyl radical were clearly identified from the spectrum observed from corona discharge of 2,6-dimethylbenzyl chloride. After subtracting the bands of the 2,6-isomer from the spectrum observed from corona discharge of 1,2,3-trimethylbenzene, the vibronic bands of the 2,3-isomer were also identified. By comparing data with the known vibrational data of 1,2,3-trimethylbenzene and the results of ab initio calculations, we determined the electronic energies of the $D_1{\rightarrow}D_0$ transitions and vibrational mode frequencies in the ground electronic states of the 2,3-and 2,6-dimethylbenzyl radicals.

• Bulletin of the Korean Chemical Society
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• 제16권3호
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• pp.281-284
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• 1995

The visible emission spectra of the o-xylyl radical in the gas phase have been obtained using a Fourier transform spectrometer coupled with a technique of supersonic expansion. The o-xylyl radical was generated in a jet by expansion with an inert buffer gas He from a high voltage dc discharge of the precursor o-xylene. The spectra were analyzed on the basis of the rotational contours of the vibronic bands as well as the known vibrational frequencies by a matrix isolation method.

• 한국자원식물학회지
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• 제23권4호
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• pp.386-392
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• 2010

녹차, 부분발효차, 발효차 및 후발효차 등 다양한 차 제품 분말을 NIRSystem를 이용하여 전 대역(400-2500 nm)에서 스펙트럼을 얻어 중회귀분석에 의해 색상 관련 특성 및 카테킨류 성분에 대한 검량식을 유도하였다. Hunter color scale에서 발효정도의 변이를 a/b로 98.7% 설명될 수 있어 a/b값으로 차제품의 발효정도를 추정할 수 있다. MPLS를 이용하여 작성된 검량식의 결과 L값의 검량식 작성시 결정계수는 0.997, a값의 결정계수는 1.00, b값의 결정계수는 0.996, a/b값의 결정계수는 0.999로 매우 높았다. MPLS를 이용하여 작성된 검량식의 결과 EGC, EC, EGCg, ECg 및 총 카테킨의 결정계수는 각각 0.919, 0.896, 0.978, 0.905 및 0.983으로 매우 높았다. 차 제품 분말의 색상관련 특성들(L, a, b, a/b) 및 카테친류 (EGCg, EGC, EC, ECg 및 총 카테킨) 의 검량식 정확도가 매우 높아서 NIRS의 가시광선 대역(400~700 nm)및 근적외선 대역(780~2500 nm)에서 동시에 두 특성의 성분을 1~2분 내로 측정이 가능하다.

• 대한화학회지
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• 제6권2호
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• pp.170-175
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• 1962

The ultraviolet and visable absorption spectra of trans, cis-azoxybenzene, substituted azoxybenzenes and their conjugate acids have been studied. The 320-350$m{\mu}$ main bands of free-base of azoxybenzenes are due to ${\pi}{\to}{\pi}^{\ast}$ transition. These bands of their conjugate acids shown bathochromic shift into visible range. The following emperical relationship between absorption maxima of the main bands was found. ${\lambda}_{max}={\lambda}^{\circ}_{max}+{\Delta}{\lambda}_x+{\Delta}{\lambda}_y$ This relationship in terms of wave number is also hold in good agreement. ${\nu}={\nu}_{\circ}-({\Delta}{\nu}_x+{\Delta}{\nu}_y)$

• Bulletin of the Korean Chemical Society
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• 제17권9호
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• pp.854-857
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• 1996

Absorption and luminescence spectra of Eu3+ (aquo) and the two different 1: 3 Eu3+: ligand systems in aqueous solutions are measured under mild acidic pH condition. The oxydiacetate (ODA) and dipicolinate (DPA) ligands, forming the similar geometric complexes, are used in this work. The three intensity parameters, Ωλ (λ=2, 4, and 6) are empirically determined by applying the Judd-Ofelt theorem to the oscillator strengths of the six absorption bands arising from the ground 7F0 state. Among the three intensity parameters, the Ω2 is found to response markedly to a miner change in the ligand environment via the 7F0→5D0 transition. In addition, the relative oscillator strengths of the four luminescence bands in the visible region, assigned to the 5D0→7FJ (J=1, 2, 3 and 4) transitions are obtained to investigate their sensitivity to the ligand environment. Among the four bands, the 610 nm band, attributed to the 5D0→7F2 transition, shows hypersensitivity in the luminescence.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1012-1012
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• 2001

The elegant early experiments of Herschel demonstrated that there is light after the visible spectrum in a region we call the near infrared (NIR). This was followed by the work which showed that the spectrum went further into what we call the mid infrared (MIR). The MIR has been used for many years as a qualitative and quantitative region to measure constituent values. The MIR region contains the fundamental vibrations which can be theoretically calculated from symmetry rules and harmonic oscillator equations. The NIR is not as straight forward because the region from 400-2500 nm does not contain any of the fundamental vibrations only combination bands and overtones. Over the past fifty years efforts to understand the NIR have largely been ignored while the quantitative aspects of the region have been utilized. This presentation will focus on the efforts to define terms for NIR, examine the calculation of combination bands and overtones and ways to interpret the spectra. The interpretation of the NIR has been aided greatly in recent years by the use of two dimensional spectroscopy which allows the correlation of bands in one spectral region with that of the NIR.