• Title/Summary/Keyword: viscosity model

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Material and rheological properties of (glycidoxypropyl) trimethoxysilane modified colloidal silica coatings

  • Kang Hyun Uk;Park Jung Kook;Kim Sung Hyun
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.175-182
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    • 2004
  • Colloidal coating solution was prepared to enhance the hydrophilic property of the film surface. Water and ethanol were used as the dispersion media and (glycidoxypropyl) trimethoxysilane (GPS) as a binder in the colloidal silica coatings. Ethylene diamine was added to the colloidal silica solution as the curing agent. The colloidal silica solution was regarded as a hard-sphere suspension model with low volume fraction of the silica particles. Rheological properties of the silica suspensions modified with GPS have been investigated as a function of pH and concentration. The acidic solution showed high viscosity change by fast hydrolysis reaction and adsorption of the organic binders on the surface of silica particles. However, the hydrolysis was slow at the basic condition and the binders combined with themselves by condensation. The viscosity change was smallest at pH 7. The viscosity increased with the curing time after adding ethylenediamine, and the increase of viscosity at low pH was higher than that at high pH. The hydrophilic properties of the coating film were investigated by the contact angle of water and film surface. The smallest contact angle was shown under the strong acidic condition of pH 2.

Dynamic Simulation of Solid Particle Considering Change by Viscosity in Rheology Material (반응고 재료에서 점성을 고려한 고상입자의 거동예측을 위한 수치모사 해석)

  • Kwon, K.Y.;Kang, C.G.
    • Transactions of Materials Processing
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    • v.18 no.1
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    • pp.26-38
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    • 2009
  • It was reported that the semi-solid forming process has many advantages over the conventional forming process, such as a long die life, good mechanical properties and energy savings. It is very important, however, to control liquid segregation to gain mechanical property improvement of materials. During forming process, rheology material has complex characteristics, thixotropic behavior. Also, difference of velocity between solid and liquid in the semi-solid state material makes a liquid segregation and specific stress variation. Therefore, it is difficult for a numerical simulation of the rheology process to be performed. General plastic or fluid dynamic analysis is not suitable for the behavior of rheology material. The behavior and stress of solid particle in the rheology material during forging process is affected by viscosity, temperature and solid fraction. In this study, compression experiments of aluminum alloy were performed under each other tool shape which is rectangle shape(square array), rectangle shape(hexagonal array), and free shape tool. In addition, the dynamics behavior compare with Okano equation to power law model which is viscosity equation.

Viscosity and Dynamic Rheological Properties of Job's-tears as a Function of Moisture Content (수분함량에 따른 율무가루의 점도변화 및 동적물성 특성에 관한 연구)

  • Yoon, Won-Byung;Kim, Byung-Yong;Shin, Dong-Hoon
    • Korean Journal of Food Science and Technology
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    • v.29 no.5
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    • pp.932-938
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    • 1997
  • Changes in viscosity and dynamic theological properties of Job's-tears were measured by Bohlin dynamic tester as a function of moisture, and measurement was performed within a linear viscoelastic range. The result of the shear stress vs shear rate of Job's-tears at different moisture contents $(50{\sim}75%)$ was applied to mathematical models and Herschel-Bulkley model showed the highest correlation coefficient. Lower moisture content (55%) produced higher yield stress and consistency index, but lower flow behavior index, whereas higher moisture content showed reverse effects. Job's-tears with $50{\sim}70%$ moisture contents showed a higher storage modulus (G') than loss modulus (G') at all frequencies, showing a higher concentrated polymer characteristics. However, higher moisture content (>75%) showed crossover point between G' and G', and frequency dependency. As the moisture content was increased, the amount of viscoelastic properties such as G', G', complex viscosity decreased during heating, and initial temperature and miximum value of viscoelastic properties shifted to higher temperatures, representing the moisture-dependence of Job's-tears upon theological properties.

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The effect of Al2O3 on the isokom temperatures in soda-lime glass (소다석회유리에서 Al2O3가 isokom 온도에 미치는 영향)

  • Kang, Seung Min;Kim, Chang-sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.3
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    • pp.103-106
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    • 2022
  • The effect of Al2O3 on isokom temperatures in soda-lime glass is estimated by comparing calculated isokom temperatures using viscosity model proposed by Lakatos. Substitution of SiO2 with Al2O3 by 0.5 mol% raises the isokom temperatures by 3.1, 3.3, 3.6 and 7.2℃ at the viscosity of log η = 12.3, 10, 6.6 and 1 (Pa·s), respectively. Meanwhile, replacing 0.5 mol% of CaO with Al2O3 raises the isokom temperatures by 1.6, 2.3, 4.1 and 17.7℃ at the viscosity of log η = 12.3, 10, 6.6 and 1 (Pa·s), respectively.

Friction Model for Sheet Metal Forming Analysis(Part 2 :Mathematical Model) (박판성형 해석용 마찰 모델(2부:수학적 모델))

  • 금영탁;이봉현
    • Transactions of Materials Processing
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    • v.13 no.5
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    • pp.461-465
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    • 2004
  • Based on the experimental observation, the mathematical friction model, which is an essential information for analyzing the forming process of sheet metal, is developed considering lubricant viscosity, surface roughness and hardness, punch comer radius, and punch speed. By comparing the punch load found by FEM with a proposed friction model with experimental measurement when the coated and uncoated steel sheets are formed in 2-D geometry in dry and lubricant conditions, the validity and accuracy of the developed friction model are demonstrated.

Preparation and evaluation of ethylcellulose microcapsules of indomethacin

  • Lee, Haeng-Ja;Shim, Chang-Koo;Shim, Chang-Koo
    • Archives of Pharmacal Research
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    • v.7 no.1
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    • pp.33-40
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    • 1984
  • In domethacin was microencapsulated with ethylcellulose using a modified spherical agglomeration process, aiming at a sustained release proparation without side effects on the stomach. The surface morphology of the microcapsules was examined using scanning electron microscopy. The microcapsules were porous and spherical, and their porosity increased with increasing the viscosity of ethylcellulose. In vitro dissolution process followed Higuchi's diffusion model for first 3 hr. Release rate of the drug from microcapsules decreased as the viscosity of ethylcellulose was decreased. The release rate also decreased with increasing the microcapsule size. The microcapsules induced less gastric ulcer in rats than raw drug.

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A Study on the Color Reproduction of Halftone Image by used Factor N and Process Ink Characteristics (Factor N와 잉크특성을 고려한 망점화상의 색재현예측에 관한 연구)

  • 김성근
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.13-27
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    • 1994
  • Litho printing ink vehicles based on rosin modified phenolic are faster drying, have better durability, are harder and glosser and have greater resistance to water than ones based on ester gums. Ink-Water balance and rheological properties are important in litho printing process. These physical properties is concerned with molecular weight of Resin to use vehicle. So this paper was studied about the effects of changing molecular weight of Rosin modified phenolic on surface tension, viscosity, pseudoplasticity and printablility of Litho Inks. The results were as follows. 1) The surface tension of model inks depended on the molecular weight of the resin : Dispersion componnent of ink increase but non dispersion component decrease as molecular weight of Resin increase. 2) Water pick-up of litho ink is more fast balance, using low molecular weight of Resin. 3) Viscosity, Yield value and Newtonian value of model inks increase as molecular weight of Resin increase. 4) The litho ink prepared with the modified phenolic of which molecular weight is about 20000 showed the highest printing density and gloss.

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The Effect of Changing Molecular Weight of Rosin Modified Phenol Resin on Physical Properties of Litho Printing Inks (Rosin변성 phenol수지의 분자량 변화에 따른 평판인쇄 잉크의 물성변화에 관한 연구)

  • SungBinKim
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.145-157
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    • 1994
  • Litho printing ink vehicles based on rosin modified phenolic are faster drying, have better durability, are harder and glosser and have greater resistance to water than ones based on ester gums. Ink-Water balance and rheological properties are important in litho printing process. These physical properties is concerned with molecular weight of Resin to use vehicle. So this paper was studied about the effects of changing molecular weight of Rosin modified phenolic on surface tension, viscosity, pseudoplasticity and printability of Litho Inks. The results were as follows. 1) The surface tension of model inks depended on the molecular \veight of the resin : Dispersion componnent of ink increase but non dispersion component decrease as molecular weight of Resin increase. 2) Water pick-up of litho ink is more fast balance, using low molecular weight of Resin. 3) Viscosity, Yield value and Newtonian value of model inks increase as molecular weight of Resin increase. 4) The litho ink prepared with the modified phenolic of which molecular weight is about 20000 showed the highest printing density and gloss.

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