• Title/Summary/Keyword: viscosity increase

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Dilutant flow characteristics model of coarse particle suspensions with uniform size distribution

  • Ookawara, Shinichi;Ogawa, Kohei
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.35-41
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    • 2003
  • It is expected that particle size distribution of any portion obtained through screening, is of more uniform than that of the original mixture, typically following such as log-normal, Rosin-Rammler distributions and so on. In this study, therefore, a new relation between parameters of the uniform distribution and flow characteristics of the coarse particle suspensions is derived based on the continuous polydisperse model (Ookawara and Ogawa, 2002b), which is derived from the discrete polydisperse model (Ookawara and Ogawa,2002a). The derived model equation predicts a linear increase of viscosity with shear rate, viz., dilutant flow characteristics. Further, the increase of viscosity is expected to be proportional to the square of volume fraction of particles, and to show the linear dependency on density and average diameter of particles. It is also shown that the uniform distribution model includes additional term that expresses the effect of distribution width. For verification of the model, the experimental results of Clarke (1967) are cited as well as in our previous work for the monodisperse model (Ookawara and Ogawa,2000) since most parameters were varied independently in his work. It is suggested that the newly introduced term expands the applicable range compared with the monodisperse model.

Rheological behavior and wall slip of dilute and semidilute CPyCl/NaSal surfactant solutions

  • Kibum Sung;Han, Min-Soo;Kim, Chongyoup
    • Korea-Australia Rheology Journal
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    • v.15 no.3
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    • pp.151-156
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    • 2003
  • In this research, experimental studies were performed to examine the rheological behavior of equimolar solutions of cetylpyridinium chloride (CPyCl) and sodium salicylate (NaSal) solutions with concentration. The surfactant solutions were prepared by dissolving 2 mM/2 mM - 80 mM/80 mM of surfactant/counterion in double-distilled water. It has been observed that the zero shear viscosity shows abrupt changes at two critical values of C^*$ and C^{**}$. These changes are caused by the switching of relaxation mechanism with concentration of CPyCl/NaSal solutions at those concentrations. The wall slip velocities of dilute and semidilute CPyCl/NaSal solutions show a dramatic increase with shear rate where the shear viscosity exhibits shear thickening behavior for dilute solutions and shear thinning behavior for semi-dilute solutions, respectively. Considering that the dramatic increase in wall slip velocity should be related to the formation of shear-induced structure (SIS) in the surfactant solution, the shear thickening behavior of semi-dilute solutions is caused by elastic instability unlike the case of dilute solutions.

Effect of Guar Gum on Rheological Properties of Acorn Flour Dispersions

  • Yoo, Byoung-Seung;Shon, Kwang-Joon;Chang, Young-Sang
    • Food Science and Biotechnology
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    • v.14 no.2
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    • pp.233-237
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    • 2005
  • Rheological properties of acorn flour-guar gum mixtures (4% w/w) at different guar gum concentrations (0, 0.2, 0.4, 0.6, and 0.8% w/w) were evaluated in steady and dynamic shear. The acorn flour-guar gum mixtures at $25^{\circ}C$ showed high shear-thinning flow behavior (n= 0.20-0.27). Consistency index (K), apparent viscosity (${\eta}_{a,100}$), and Casson yield stress (${\sigma}_{oc}$) increased with the increase in guar gum concentration. Within the temperature range of $25-70^{\circ}C$, the {\eta}_{a,100}$ of mixtures obeyed the Arrhenius relationship with high determination coefficient ($R^2=\;0.974-0.994$). Activation energy values (5.37-6.77 kJ/mole) of acorn flour dispersions in the mixtures with guar gum (0.2-0.8%) were much lower than that (12.5 kJ/mole) of acorn flour dispersion (0% guar gum). Storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) increased with the increase in guar gum concentration. Dynamic rheological data of 1n (G', G") versus ln frequency (w) of guar gum-acorn flour mixtures had positive slopes with G' greater than G" over most of the frequency range, indicating that they exhibited weak gel-like behavior.

Densification Behavior of C/C Composite Derived from Coal Tar Pitch with Small Amount of Iodine Addition (석탄계 피치에 요오드를 소량 첨가하여 제조한 탄소복합재의 치밀화 거동)

  • Cho, Kwang-Youn;Riu, Doh-Hyung;Shin, Dong-Geun;Joo, Heyok-Jong;Koo, Hyung-Hoi;Park, In-Seo
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.643-647
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    • 2009
  • We investigated the viscosity behavior and the carbon yield of coal tar pitch (CTP) treated with iodine. The viscosity of iodine treated pitch showed that the fluidity of iodine treated CTP did not increase within the iodine addition of 1.4%. DTG analysis showed that cross linking was accelerated at the temperature range from $400\;to\;500{^{\circ}C}$ with iodine treatment, which is due to the accelerated dehydrogenative reaction by iodine. The iodine treatment was mainly effective for β-resin content increase of CTP. The carbon yield of CTP increased from 40 to 60% by the iodine non-treated CTP.

Microstructure and Characteristic of Rheocast Al-6.2wt%Si Alloy (Al-6.2wt%Si합금의 리오캐스트 조직과 특성)

  • Lee, Jung-Il;Park, Ji-Ho;Lee, Ho-In;Kim, Moon-Il
    • Journal of Korea Foundry Society
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    • v.14 no.5
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    • pp.438-446
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    • 1994
  • The effect of various thermomechanical treatments on the structure and rheological behaviour of Al-6.2wt%Si alloy in its solidification range were investigated using a Searle type high temperature viscometer. During continuous cooling, the viscosity increases gradually with increasing fraction of solidified alloy, until a critical fraction of solidified alloy is reached above which the viscosity sharply increases. The viscosity of the slurry, at a given volume fraction wolid, decreased with increasing shear rate. The size and morphology of primary solid particles during stirring is influenced strongly by shear rates, cooling rates, volume fraction and stirring time of solid. Morphological changes during stirring as a function of solid volume fractions, shear rate and processing time were also reported. In this study, the size of primary solid particles in these alloys consistently increases and the it`s aspect ratio decrease with the increase in fraction solid and decrease in shear rate. Crystal morphology changes from rosette type to spheroid type with the increase in shear rate and solid fraction.

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Experimental Study on Mixing Stability and Macroscopic Spray Characteristics of Diesel-gasoline Blended Fuels (디젤-가솔린 혼합연료의 혼합안정성 및 거시적인 분무 특성에 관한 실험적 연구)

  • Park, Sewon;Park, Su Han;Park, Sungwook;Chon, Mun Soo;Lee, Chang Sik
    • Journal of ILASS-Korea
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    • v.17 no.3
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    • pp.121-127
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    • 2012
  • The study is to investigate the mixing stability, fuel properties, and macroscopic spray characteristics of diesel-gasoline blended fuels in a common-rail injection system of a diesel engine. The test fuels were mixed diesel with gasoline fuel, which were based volume fraction of gasoline from 0 to 100% in 20% intervals. In order to analyze the blended effect of gasoline to diesel fuel, the properties of test fuels such as density, viscosity, and surface tension were measured. In addition, the spray behavior characteristics were studied by investigating the spray tip penetration and spray angle using a spray images through a spray visualization system. It was revealed that the density, kinematic viscosity and surface tension of diesel-gasoline blending fuels were decreased with the increase of gasoline fuel. The injection quantity of test fuels were almost similar level at short energizing duration condition. On the other hand, the increase of energizing duration shows the decrease of injection quantity compared to short energizing duration. The test blending fuels have similar growth in Spray tip penetration and Spray cone angle.

Rheological and Magnetic Properties of Plastic Ferrite Magnets (플라스틱 페라이트 자석의 레올로지와 자기특성)

  • 이석희;최준환;문탁진;정원용
    • Journal of the Korean Magnetics Society
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    • v.8 no.3
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    • pp.150-155
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    • 1998
  • The purpose of this study is to investigate the variations of rheological and magnetic properties with powder loading in plastic anisotropic ferrite magnets. The measured relative viscosities with powder loading were compared with the calculated ones. The variation of relative viscosities with powder loading was in good agreement with that of particle alignment. Remanent flux density and maximum energy product increased linearly with the increase of powder loading, and then showed maximum values. The decrease of magnetic properties at high powder loading was caused by rapid decrease of particle alignment due to the drastic increase of mixture viscosity. The powder loading for maximum magnetic properties is dependent on magnetic field during injection molding and melt viscosity of binder, so the binder with low melt viscosity is necessary to fabricate the magnet with high properties.

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Leakage Characteristics of LPG injector with Low Viscosity LPG Fuel (저점도 LPG연료 인젝터의 누설특성에 관한 연구)

  • Kim, C.U.;Park, C.W.;Oh, S.M.;Kang, K.Y.
    • Journal of ILASS-Korea
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    • v.10 no.4
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    • pp.8-15
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    • 2005
  • The use of clean gaseous fuels for the purpose of high efficiency and low emission in automotive engines has tendency to increase in order to meet the reinforcing emission regulations and to efficiently utilize limited natural resources. Automotive companies developed and commercialized a LPG liquid injection system, which is mounted on LPLi(Liquid Phase LPG Injection) engines and vehicles based on this research trend. This research examines the biggest problem in LPLi engine, that is, the leakage characteristics of low viscosity LPG fuel according to the injector design variables. This study is also aimed to improve the performance of fuel-leakage in LPLi engine through the addition of a lubrication improver in HFRR(High Frequency Reciprocating Rig) facility. The needle displacement and the spring displacement of an LPLi injector are found to be already optimized. The possibility of a maximum of 70% leakage reduction compared to a conventional case, is verified when 1000ppm of a lubrication improvement material is added and 40% increase of a injector spring constant (K) is applied.

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Measurement of Breakup Length of Viscous Liquid Jet in Stagnant Air (정지공기중 점성유체 분류의 분열길이 측정)

  • Rhim, Jung-Hyun;Ryu, Keun-Young;Lim, Sung-Bin;No, Soo-Young
    • Journal of ILASS-Korea
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    • v.3 no.4
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    • pp.1-7
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    • 1998
  • The measurement of breakup length of viscous liquid jet in stagnant air was conducted by a 3CCD digital video camera. The nozzle diameters of 4, 6, 8mm with L/d=50 were selected and the dynamic viscosity of viscous liquid made of glycerine and water was in the range of $1.061\times10^{-6}m^2/s$ to $4.935\times10^{-5}m^2/s$. The critical velocity is decreased and the breakup length is increased with the increase of nozzle diameter at the same dynamic viscosity of liquid. At the same nozzle diameter, the breakup length and the critical velocity are both increased with the increase of dynamic viscosity of liquid. It is found in the theoretical analysis that the initial disturbance level is the main cause of occurrance of critical Reynolds number in the stability curve. The comparison of experimental critical Reynolds number and the empirical correlation by Tanasawa and Toyota reveals the relatively good agreement.

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Functional Properties of the Microcrystalline Collagen Manufactured from Raw Pigskins (생돈피에서 제조된 미세결정성 콜라겐의 기능적 성질)

  • Lee, Moo-Ha;Kim, Yang-Ha
    • Korean Journal of Food Science and Technology
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    • v.19 no.5
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    • pp.409-413
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    • 1987
  • Microcrystalline collagen was manufactured from raw pigskins and its functional properties were measured. It showed a thixotropic behavior. The maximum viscosity was obtained at pH 3.5 and the viscosity increased with the increase of concentration in a nonlinear manner. The increase in temperature decreadsed the viscosity while the effect of temperature was greater at pH below 4.5. Foaming capacity was similar to that of gelatin but superior to that of egg white at 1%. The foam stability was inferior to that of egg white. Emulsifying capacity was lower than that of pork. Values from physical and chemical analysis were somewhat different from those of medical-grade microcrystalline collagen made from bovine cerium collagen.

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