• 제목/요약/키워드: viscosity increase

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모사된 GTL공정의 점성액체 매체에서 wake의 특성 (Characteristics of Wakes in a Viscous Liquid Medium of a Simulated GTL Process)

  • 임대호;장지화;강용;전기원
    • Korean Chemical Engineering Research
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    • 제49권5호
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    • pp.571-576
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    • 2011
  • 점성 액체를 사용한 모사된 GTL공정(직경 0.102 m ${\times}$ 높이 1.5 m)에서 기포에 의해 발생되는 wake의 특성을 고찰하였다. 기체의 유속(0.04 ~ 0.12 m/s)과 액상의 점도(0.001 ~ 0.050 $Pa{\cdot}s$)가 wake의 특성 즉 상승속도, 빈도수, 크기 그리고 체류량에 미치는 영향을 전기저항 탐침법에 의해 결정하였다. 상승하는 단일기포들뿐만 아니라 다중기포의 후면에 형성된 wake 상들도 탐침에 의해 측정된 전기 전도도 요동자료로부터 효과적으로 검침되었다. 유속이 조절되는 압축 여과공기와 CMC 수용액을 각각 분산기체상과 연속액상으로 사용하였다. 실험결과 wake 상의 상승속도와 크기는 기체의 유속 또는 액상의 점도가 증가함에 따라 증가하였다. wake 상의 체류량과 빈도수는 기체의 유속이 증가함에 따라 증가하였는데, 이는 기체유속의 증가에 따라 공정에 유입되는 기체의 양이 증가하기 때문이다. 그러나, 액상의 점도가 증가함에 따라 기포의 크기와 wake의 크기가 증가하기 때문에 wake의 상의 체류량과 빈도수 값은 wake 상의 액상의 점도가 증가함에 따라 감소하였다. Wake 상 체류량의 기체의 체류량에 대한 비율은 0.25~0.48의 범위였으며, 이 비율은 액체점도가 증가함에 따라 증가하였으나 기체의 유속이 증가함에 따라 감소하였다. 본 연구의 실험범위에서 wake 상의 특성들은 운전변수의 상관식으로 잘 나타낼 수 있었다.

세립토의 모래함량에 따른 유변학적 특성 분석 (Rheological Characteristics of Fine-Grained Soil with Sand Content)

  • 강효섭;김윤태
    • 대한토목학회논문집
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    • 제33권5호
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    • pp.1897-1905
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    • 2013
  • 항복응력, 점성과 같은 유변학적 특성은 토석류의 유변성을 결정하는 주요 매개변수이다. 본 연구에서는 다양한 액성지수와 모래함량을 가지는 세립토를 대상으로 유변측정 시험을 수행하였다. 이를 통해 전단응력-전단변형률속도 관계, 액성지수와 점성 및 항복응력 관계, 체적농도와 점성 및 항복응력 관계 등과 같은 다양한 분석을 통해 모래함량을 달리하는 흙에 대한 유변학적 특성을 파악하였다. 유변측정 시험 결과로부터 세립토의 유동곡선 특성은 전단변형률속도가 점차 커짐에 따라 곡선의 기울기가 감소하는 전형적인 전단담화(shear thinning)의 거동 형태를 나타냄을 알 수 있다. 동일한 모래함량을 갖는 시료에서 액성지수가 증가함에 따라 항복응력과 점성은 감소하는 경향을 보이며, 동일 액성지수 상태에서 모래함량이 커짐에 따라 항복응력과 점성 모두 증가하는 것으로 나타났다. 항복응력과 점성은 약간의 함수비 증가에도 크게 감소함을 알수 있다. 체적농도($C_v$)가 증가함에 따라 항복응력과 점성은 증가하는 경향을 나타낸다. 회귀분석을 통해 임의의 체적농도($C_v$)에 대한 항복응력과 점성의 계수 ${\alpha}_1$, ${\alpha}_2$, ${\beta}_1$, ${\beta}_2$를 산정하였다.

Yoghurt의 안정제 종류에 따른 물성 변화 (Changes of Rheological Properties of Yoghurt by Different Kinds Stabilizers)

  • 최순호;장운기;정종국;오동규;이부웅
    • 한국축산식품학회지
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    • 제18권1호
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    • pp.35-41
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    • 1998
  • The objective of this study was to examine the changes of physical properties by additions of different kinds of stabilizers milk proteins concentration, when stored at 4$^{\circ}C$ or 20$^{\circ}C$ for yoghurt. the results were summarized as follows: 1. Addition of 2% carboxyl methyl cellulose and carrageenan, gelation 0.4%, pectin and starch 0.6%, and carrageenan & pectin 0.8% in the manufacture of yoghurt increased the viscosity, water-holding capacity and protein hydration of yoghurt. 2. Addition of 3% skim milk powder, Ca-caseinate or Na-caseinate 0.6% increased the viscosity, water-holding capacity and protein hydration of yoghurt. 3. Twenty five percent of evaporation of milk promoted to build up the optimal structure of the micelles of yoghurt and improved viscosity, water-holding capacity and protein hydration of yoghurt. 4. Addition of stabilizers to yoghurt showed an increase of viscosity, water-holding capacity and protein hydration when compared with non-addition of stabilizers to yoghurt at 4$^{\circ}C$, 20$^{\circ}C$ storage for 12hrs, 96hrs followed by the decrease of it.

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표면사이징용 전분의 점도 특성이 라이너지의 표면사이징 효과에 미치는 영향 (Influence of the Viscosity of Surface Sizing Starch Solutions on Surface Sizing Effect of Linerboard)

  • 정영빈;이학래;윤혜정;정광호;류훈
    • 펄프종이기술
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    • 제44권5호
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    • pp.54-62
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    • 2012
  • The main role of surface sizing of linerboard is to improve surface and strength properties. Since surface sizing solution is applied on once dried web, substantial amount of drying energy is required. Saving of the drying energy associated with surface sizing can be made by increasing the solids content of the starch solution in size press. Therefore, it is highly desirable to develop low viscosity starches for surface sizing. A low viscosity oxidized starch was prepared and compared its effect of surface sizing with a conventional oxidised starch. Results showed increase in solids content of the starch solution decreased evaporation energy and drying time. Low viscosity starch penetrated deeper into paper and this improve various mechanical properties of linerboard.

Small and Large Deformation Rheological Behaviors of Commercial Hot Pepper-Soybean Pastes

  • Choi, Su-Jin;Kang, Kyoung-Mo;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • 제15권6호
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    • pp.871-876
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    • 2006
  • Rheological behavior of commercial hot pepper-soybean paste (HPSP) was evaluated in small amplitude oscillatory and steady shear tests. Storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) as a function of angular frequency (${\omega}$), and shear stress (${\sigma}$) as a function of shear rate (${\gamma}$) data were obtained for 5 commercial HPSP samples. HPSP samples at $25^{\circ}C$ exhibited a non-Newtonian, shear-thinning flow behavior with high yield stresses and their flow behaviors were described by power law, Casson, and Herschel-Bulkley models. Time-dependent flow properties were also described by the Weltman, Hahn, and Figoni & Shoemaker models. Apparent viscosity over the temperature range of $5-35^{\circ}C$ obeyed the Arrhenius temperature relationship with activation energies (Ea) ranging 18.3-20.1 kJ/mol. Magnitudes of G' and G" increased with an increase in ${\omega}$, while ${\eta}^*$ decreased. G' values were higher than G" over the most of the frequency range (0.63-63 rad/sec), showing that they were frequency dependent. Steady shear viscosity and complex viscosity of the commercial HPSP did not fit the Cox-Merz rule.

액체 점도에 따른 Y-jet 노즐 내부 유동 및 분무 특성의 변화 (Effect of liquid viscosity on internal flow and spray characteristics of Y-jet atomizers)

  • 송시홍;이상용
    • 대한기계학회논문집B
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    • 제20권12호
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    • pp.4053-4061
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    • 1996
  • Internal flow characteristics within Y-jet atomizers and the local drop size distribution and cross-sectional averaged drop size at the outside were investigated with the liquid and air injection pressures, mixing port length of atomizers, and the liquid properties taken as parameters. To examine the effect of the liquid viscosity, glycerin-water mixtures were used in this study. The liquid viscosity plays only a minor role in determining the internal flow pattern and the spatial distribution shape of drops, but the drop sizes themselves generally increase with increasing of the liquid viscosity. An empirical correlation for the liquid discharge coefficient at the liquid port was deduced from the experimental results; the liquid discharge coefficient strongly depends on the liquid flow area at the mixing point which is proportional to the local volumetric quality(.betha.$_{Y}$), and the volumetric quality was included in the correlation. Regardless of the value of the liquid viscosity, the compressible flow through the gas port was well represented by the polytropic expansion process(k=1.2), and the mixing point pressure could be simply correlated to the aspect ratio( $l_{m}$/ $d_{m}$) of the mixing port and the air/liquid mass flow rate ratio( $W_{g}$/ $W_{f}$) as reported in the previous study.udy.udy.y.

자색 고구마 분말 첨가 생면의 품질 특성 (Quality Characteristics of Wet Noodles Added with Purple Sweet Potato Powder)

  • 이재상;유승석
    • 동아시아식생활학회지
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    • 제22권4호
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    • pp.489-496
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    • 2012
  • This research investigated the quality characteristics and anthocyanin content of wet noodles according to the amount of freeze-dried purple sweet potato powder. For viscosity, initial pasting temperature tended to increase compared to the control group, whereas peak viscosity, peak viscosity time and final viscosity steadily decreased. As the amount of purple sweet potato powder increased, breakdown value of viscosity and set back value significantly decreased. For chromaticity, as the amount of purple sweet potato powder increased, L-value decreased gradually, whereas a-value gradually increased and b-value significantly decreased compared to the control group. Anthocyanin content significantly increased in the addidtive group (91.79) compared to the control group (70.20). Measurement of texture characteristics found that hardness was highest in the control group, but it decreased as the amount of purple sweet potato powder increased. Springiness, gumminess and chewiness were highest in the control group. In the sensory evaluation, color, odor, chewiness, and overall acceptance were high in the 6% addictive group. In this study, by investigating the anthocyanin contents, quality characteristics and sensory attributes of wet noodles with freeze-dried purple sweet potato powder, we found that the 6% additive group is the best. Our results provide basic information for the development of noodles with purple sweet potato powder.

증점제를 이용한 분리저감형 유동화 콘크리트의 개발 및 그 특성분석 (Development and Property Analysis of Segregation-Reducing Type Flowing Concrete Using the Viscosity Agent)

  • 한천구;강의영;오선교;반호용
    • 콘크리트학회논문집
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    • 제11권4호
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    • pp.95-105
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    • 1999
  • When superplasticizer is added to manufacture flowing concrete, the base concrete usually needs the adjustment to assure the sufficient fines contained to obtain flowable consistency without excessive bleeding or segregation. However, this may not only increase the cost, but also cause inconvenience in producing the base concrete. In this paper, the experiments are performed on normal base concrete to achieve a segregation-reducing flowing concrete by adding superplasticizer mixed with viscosity agents and AE admixtures. Three kinds of superplasticizer and two kinds of viscosity agent are selected. According to the results, with regard to the performance and cost of the admixtures, melamine type superplasticizer combined with the PEO viscosity agent and AE admixtures at the ratio 1:0.28:0.001 can acquire good quality and reduce the cost in producing the flowing concrete. With proper addition of combined superplasticizer, even though water to cement ratios of the base concrete are different, the segregation-reducing flowing concrete could be also achieved without reproportioning of the base concrete. However, it would be more desirable if the superplasticizer could be adjusted, before it is put into the practical use in order not to cause some other problems, such as rapid rate of slump loss and retarding of setting time.

Effect of NCO/OH ratio and binder content with micro-AP on HTPB/AP/Al-based propellants mechanical properties

  • Zulfam Adnan;Nurul Musfirah Mazlan
    • Advances in materials Research
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    • 제13권2호
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    • pp.129-140
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    • 2024
  • This study evaluates the ratio of Toluene di-isocyanate (TDI) functional group isocyanate (NCO) to the binder functional hydroxyl group (OH) in HTPB/AP/Al-based propellants on their mechanical properties, flow rate, and viscosity to determine the limitations of NCO/OH in the composition of solid propellants. The propellants consisted of hydroxyl-terminated polybutadiene (HTPB) polyurethane (PU), aluminum (Al) and tri-modal ammonium perchlorate (AP). The tri-modal AP consisted of 30% of coarse AP, 30% of medium AP, and 8% of fine AP. The ratio of NCO/OH varies from 0.73 to 0.85, with two binder percentages of 10.5% and 12%. An increase in NCO/OH ratio with 10.5% binder provided 20%, 95%, and 8 to 9% increments in UTS, modulus, and hardness, respectively. However, the propellant elongation, density, and flow rate decreased by 170%, 0.2%, and 11-12%, respectively. Viscosity increased 20% based on initial hour reading. The 12% binder provides 27%, 47%, and 5~6% an increment of UTS, modulus and hardness respectively. However, the propellant elongation, density, and flow rate decreased by 47%, 0.17% and 27%, respectively. The viscosity increased 30% based on initial hour reading. This study suggests the NCO/OH value of 0.77 and 10.5~11% binder content in propellant based on the mechanical properties, flow rate, and viscosity for better processing and pot life.

고성능 습식 숏크리트의 레올로지에 관한 기초연구 (A Study on Rheology Properties of High Performance Wet-mix Shotcrete)

  • 최성용;윤경구;김진웅;김용빈
    • 한국방재학회 논문집
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    • 제10권4호
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    • pp.25-32
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    • 2010
  • 최근 고강도 및 고내구성에 대한 인식이 높아지면서 고성능 숏크리트에 대한 연구가 일부 진행되기도 하였으나, 국외 선진국에 비하면 아직 초보 단계에 그치고 있다. 즉 강도와 내구성 평가만 일부 이루어졌고, 시공성을 대변하는 펌핑성능(Pumpability)과 뿜칠성능(Shootability)에 대한 평가가 전혀 이루어지지 않았다. 따라서 본 논문의 목표는 국내 습식 숏크리트의 고성능화에서 고시공성에 대한 연구로, 이를 위해 실리카 흄(0.0, 4.5, 9%), AE제(0.0, 0.005%)를 주요 변수로 하여 시공성 평가를 위해서 레오미터를 사용한 레올로지를 측정하였을 뿐만 아니라, 펌프압, 리바운드율, 붙임두께 등을 측정하여 비교고찰 하였다. AE제와 고성능 감수제가 레올로지 특성에 미치는 영향을 고찰한 결과 AE제는 흐름저항(Flow Resistance, G)과 토크점성(Torque Viscosity, H)이 모두 일정하게 감소되었고, 실리카 흄은 흐름저항(G)은 증가 토크점성(H)은 감소한 결과가 나타났다. 펌핑성능과 레올로지 관계에서 토크점도(H)가 증가함에 따라 필요 펌핑 압송력이 상승하는 결과를 얻었고, 뿜칠성능과 레올로지 관계에서는 흐름저항(G)가 증가할수록 최대 붙임두께는 증대 리바운드율은 감소하는 경향을 얻었다.