• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2002년도 금형가공 심포지엄
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• pp.125-131
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• 2002

Surface defects in injection molded parts are due to the unsteady flow of polymer melt which are related to the geometries of cavity and gate, the operational conditions of injection and the rheological properties of polymer. In this study we have examined jetting phenomena in injection molding process for three kinds of PCs which have different molecular weight and structure, PBT and PC/ABS alloy with several injection speeds. We have used various cavity shapes that are tensile, flexural and impact test specimens with various gate and cavity thicknesses. Through this study we have observed that the formation of surface defect associated with jetting during filling stage in injection molding is strongly related to die swell. This means that the jetting is strongly affected by the elastic property rather than the viscous property in viscoelastic characteristics of molten polymer. Large die swell would eliminate jetting however, the retardation of die swell would stimulate jetting. In the point of mold design, reducing the thickness ratio of cavity to gate can reduce or eliminate jetting and associated surface defects regardless of magnitude of elastic property. It also enlarges process window that can produce steady flow of polymer melt in injection molding.

• 한국정밀공학회지
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• 제23권7호
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• pp.152-158
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• 2006

The objective of this work is to develop the knee joint model for representing various pendulum motions and quantifying the spasticity. Knee joint model included the extension and flexion muscles. The joint moment consists of both the active moment from the stretch reflex and the passive moment from the viscoelastic joint properties. The stretch reflex was modeled as nonlinear feedback of muscle length and the muscle lengthening velocity, which is Physiologically-feasible. Moreover, we modeled the spastic reflex as having dynamic threshold to account far the various pendulum trajectories of spastic patients. We determined the model parameters of three patients who showed different pendulum trajectories through minimization of error between experimental and simulated trajectories. The simulated joint trajectories closely matched with the experimental ones, which show the proposed model can predict pendulum motions of patients with different spastic severities. The predicted muscle force from spastic reflex appeared more frequently in the severe spastic patient, which indicates the dynamic threshold relaxes slowly in this patient as is manifested by the variation coefficient of dynamic threshold. The proposed method provides prediction of muscle force and intuitive and objective evaluation of spasticity and it is expected to be useful in quantitative assessment of spasticity.

• 한국도로학회논문집
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• 제15권4호
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• pp.117-125
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• 2013

PURPOSES : The purpose of this study is to evaluate of field application and laboratory performance of warm-mix asphalt (WMA) according to the dosage rate of organic-based WMA additive. METHODS: Three asphalt mixtures, i.e., hot mix asphalt (HMA), WMA with the dosage rate of 1.5%, WMA with the dosage rate of 1.0%, were sampled from the asphalt plant when the field trial project were constructed. With these mixtures, the laboratory testings were performed to evaluate the linear viscoelastic characteristics and the resistance to moisture, rutting and fatigue damage. RESULTS : From the laboratory test results, it was found that the WMA with the reduced dosage rate of additive would be comparable to HMA and WMA with the original dosage rate in terms of the dynamic modulus, tensile strength ratio, rutting resistance. However, the fatigue reisistance of WMA with the reduced dosage rate was slightly worse but it should be noted that the fatigue performance is necessarily predicted by combining the material properties and pavement structure. CONCLUSIONS: Through the field construction and laboratory testings, the dosage rate of organic-based WMA additive could be reduced from 1.5% to 1.0% without the significant decrease of compactability and laboratory performance. The long-term performance of the constructed pavement will be periodically monitored to support the findings from this study.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3163-3172
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• 2010

In this work, a novel method to synthesis of an acrylic superabsorbent hydrogel was reported. In the two stage hydrogel synthesis, first copolymerization reaction of acrylonitrile (AN) and acrylamide (AM) monomers using ammonium persulfate (APS) as a free radical initiator was performed. In the second stage, the resulted copolymer was hydrolyzed to produce carboxamide and carboxylate groups followed by in situ crosslinking of the polyacrylonitrile chains. The results from FTIR spectroscopy and the dark red-yellow color change show that the copolymerization, alkaline hydrolysis and crosslinking reactions have been do take place. Scanning electron microscopy (SEM) verifies that the synthesized hydrogels have a porous structure. The results of Brunauer-Emmett-Teller (BET) analysis showed that the average pore diameter of the synthesized hydrogel was 13.9 nm. The synthetic parameters affecting on swelling capacity of the hydrogel, such as AM/AN weight ratio and hydrolysis time and temperature, were systematically optimized to achieve maximum swelling capacity (330 g/g). The swollen gel strength of the synthesized hydrogels was evaluated via viscoelastic measurements. The results indicated that superabsorbent polymers with high water absorbency were accompanied by low gel strength. The swelling of superabsorbent hydrogels was also measured in various solutions with pH values ranging from 1 to 13. Also, the pH reversibility and on-off switching behavior makes the hydrogel as a good candidate for controlled delivery of bioactive agents. Finally, the swelling of synthesized hydrogels with various particle sizes obey second order kinetics.

• Composites Research
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• 제12권2호
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• pp.1-9
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• 1999

외부 회로가 연결된 압전 재료는 외부 회로의 영향으로 진동수에 영향을 받는 강성(stiffness)과 손실 계수(loss factor)를 가지게 된다. 일반적으로 외부 회로는 두 종류로 구별이 된다. 저항만으로 구성된 경우와 저항과 인덕터(inductor)로 구성된 경우이다. 저항만으로 구성된 경우를 RES(resistive shunting)라 하는데, 이 경우는 압전 재료의 물성이 점탄성 물질과 비슷하게 진동수에 영향을 받는다. 그러나 점탄성 물질에 비해서 더 큰 강성을 지니고, 온도에 영향을 덜 받는다. 저항과 인덕터로 구성된 경우를 RSP(resonant circuit shunting)라 하는데, PMD(proof mass damper)와 비슷한 방법으로 구조물의 공진을 최적으로 조절할 수 있다. 본 논문에서는 이러한 외부 회로와 연결된 압전 재료를 이용하여 복합재 보의 진동을 수동적으로 제어하는 실험을 수행하여 그 결과를 제시하였다.

• 한국염색가공학회지
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• 제15권3호
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• pp.132-139
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• 2003

PTT[Poly(trimethylene terephthalate)] fibers was annealed by passing on the plate heater to illuminate the effects of annealing on the alkaline hydrolysis behavior properties with varying the treatment temperature for 0.5 second. The L010 and crystallinity were increased with increases in temperature. With the increases of the temperature, the dynamic viscoelastic behaviors were analyzed to be reduction in $T_{max}(tan\;\delta)$. The weight loss in alkaline solution was two times more rapid for the PTT annealed at $200^\circ{C}$ than the control samples. The kinetics of hydrolysis was confirmed that the hydrolysis of the PTT fibers in the alkaline solution was started from the surface of the fibers and selective to the amorphous region in continuation, on the basis of the results of the increase in crystallinity and the decrease in dye uptake at the initial stage of the hydrolysis.

• Korea-Australia Rheology Journal
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• 제17권4호
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• pp.181-190
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• 2005

Rheological characterisation of flocculated kaolinite pulps has been undertaken to elucidate particle interactions underpinning the dewatering behaviour induced by flocculation with polyethylene oxide (PEO), anionic polyacrylamide (PAM A) and their blends. Shear yield stress $(\tau_y)$ analysis indicated that polymer mediated particle interactions were markedly amplified upon shear of PEG based pulps. In contrast, PAM A based pulps showed a significant decrease in yield values upon shear. Steady stress measurements analysed using a modified Ellis model indicated subtle differences between the respective linear viscoelastic plateaus of the pulps. Furthermore, modified shear thinning behaviour was evident in PEG based pulps. Estimation of elastic and viscous moduli (G', G') was made using dynamic stress analysis for comparison with values determined from vane measurements. Despite a noticeable difference in the magnitude of G' between the two methods, similar trends indicating sheared PEG-based pulps to be more elastic than PAM based pulps, were observed. Floc microstructural observations obtained in support of rheological properties indicate that PEG flocculant induces significantly more compact particle aggregation within the clay pulps under shear consistent with the yield stress data, in contrast to PAM A, or indeed unsheared PEG based pulps. Consequentially, sheared PEG based pulps show significantly improved dewatering behaviour. The implications of the results, potential benefits and drawbacks of flocculation with PEG and PAM A are discussed with respect to improvements in current dewatering processes used in the minerals industry.

• 소음진동
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• 제9권2호
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• pp.324-330
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• 1999

With the increase of track density, high rotational speed and the compatibility for various media such as CD-ROM, CD-R/RW, DVD-ROM/RAM/RW etc. in optical disk drive, the effective anti-vibration design is so crucial for robust operaton. Especailly when the drive is self-excited by unbalanced disk, internal sled base vibration and its external transmission to the case bring about so severe problem. Generally these two consideration points the practical anti-vibration design process to control thses two conflictive properties using finite element analysis. As an example of the design process, Duro 25 and 40 visco-elastic rubber mount was selected and analyzed. The stiffness obtained from FEM rubber model was well matched with the experiments. Also it was confirmed that the internal and external vibration induced from unbalanced disk have good agreement with experimental results. The proposed design process is adopted to the slim-type optical disk drive.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2004년도 추계학술대회논문집
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• pp.349-353
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• 2004

A study on optimal placement of constrained layer damping treatment for vibration control of automotive panels is presented. The effectiveness of damping treatment depends upon design parameters such as choice of damping materials, locations and size of the treatment. This paper proposes a CAE (Computer Aided Engineering) methodology based on finite element analysis to optimize damping treatment. From the equivalent modeling technique, it is found that the best damping performance occurs as the viscoelstic patch is placed by means of the modal strain energy method of bare structural panels to identify flexible regions, which in turn facilitates optimizations of damping treatment with respect to location and size. Different configurations of partially applied damping layer treatment have been analyzed for their effectiveness in realizing maximum system damping with minimum mass of the applied damping material. Moreover, simulated frequency response function of the automotive roof with and without damping treatments are compared, which show the benefits of applying damping treatment. Finally, the optimized damping treatment configuration is validated by comparing the locations and the size of the treatment with that of an experimental modal test conducted on roof compartment.

• 한국식품과학회지
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• 제32권6호
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• pp.1313-1318
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• 2000

총고형분 함량$(TS:\;50{\sim}57%)$을 달리하여 숙성시킨 고추장의 유동특성, 정적 및 동적점탄특성을 관찰하였다. 고추장의 TS가 증가함에 따라서 점조도 지수(K)와 겉보기 점도$({\eta}_{a.5})$는 증가하였으며 유동성 지수(n)는 1보다 훨씬 낮은 0.24-0.31의 범위를 나타내어 고추장은 shear-thinning 성질을 보여주었다. 고추장의 항복응력 측정에서는 고추장의 TS가 증가함에 따라 Casson 항복응력$({\sigma}_{oc})$은 증가하는 경향을 나타내었으며, 또한 고추장의 액상 매개체인 serum 점도$({\eta}_{se})$는 고추장의 TS와 매우 좋은 상관관계$(R^2=0.97)$를 나타내었다. 고추장의 동적점탄성 실험에서는 주파수$({\omega})$가 증가함에 따라 저장탄성률(G#)와 손실탄성률(G@)은 증가하였으며 양(+) 기울기로 G#수치가 G@수치보다 높게 나타났다. 이는 고추장이 약한 겔과 같은 구조적 특성을 갖고 있으며 또한 shear-thinning 거동을 가지고 있음을 나타낸다. 정적점탄성 실험에서 고추장의 총고형분 함량에 따라서 순간탄성 변형$(J_0)$과 지연탄성변형$(J_1)$은 총고형분 함량이 증가함에 따라서 감소하였으며 점도$({\eta}_N)$와 지연시간 $({\tau}_1)$은 증가하였다. 따라서 고추장은 농도가 증가함에 따라 보다 탄력적이며 안정된 구조를 형성하고 있음을 알 수 있었다.