• Journal of the Korean Ceramic Society
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• v.28 no.2
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• pp.160-166
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• 1991

Microstructure and phase changes during the sintering of ZnO varistors were studied in ZnO-Bi2O3-CoO-Sb2O3 and ZnO-Bi2O3-CoO-Sb2O3-Cr2O3 systems using acanning electron microscopy (SEM) with an energy dispersive X-ray analysis (EDAX), X-ray diffraction (XRD) and differential thermal analysis (DTA). The spinel phase and the Bi2O3 phase were formed by the decomposition of the pyrochlore phase during heating. The spinel particles (2-4$\mu\textrm{m}$), which were formed both along ther grain boundaries and within the ZnO grain, were always found near the pyrochlore phase. Intergranular phases (Bi2O3 and pyrochlore) were precipitated from the liquid phase during cooling. The Bi2O3 phases were located at the triple (or multiple) point of the ZnO grains. Cr2O3 played a role in decreasing the formation temperature of the spinel phase and Bi2O3 phase during sintering, and inhibited the grain growth.

• Journal of the Korean Ceramic Society
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• v.28 no.2
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• pp.101-108
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• 1991

0.2 mo1% La doped BaTiO3 samples were prepared by a wet chemical process (Pechini process) and electrical conductivity were measured from annealing temperatures(800-110$0^{\circ}C$) to room temperature continuously. 2 probe I-V characteristics showed that Pt electrodes were non-ohmic below about 80$0^{\circ}C$ for Ladoped sample. I-V curves showed varistor behavior and breakdown voltages showed PTC-like behavior. AC complex impedance of 0.2 La and 0.05 Mn mo1% doped BaTiO3 samples with three different electrodes (electroless Ni, Pt, Ag electrodes) were measured with temperature variation. Complex impedance plots showed that the samples with electroless Ni electrodes have negligible electrode resistance. Samples with Ag or Pt paste electrodes showed large electrode resistance. PTC effect, which is defined as the ratio of maximum resistance to minimum resistance, was found to be less than 10 for 0.2 mo1% La doped dense sample however greater than 105 with codoping of 0.05 mo1% Mn and 0.2 mol% La.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.747-750
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• 2003

The microstructure and nonlinear properties of ZPCMR-based varistors were investigated with various additives. The density of varistors were gradually decreased for the same R in order of NiO, MgO, and $Cr_2O_3$, respectively. The ZPCR-based varistors were not affected by NiO and MgO additives in nonlinear properties, whereas greatly affected by $Cr_2O_3$. Among the ZPCCR-based varistors, ZPCCD varistor exhibited the highest nonlinear properties, in which the nonlinear exponent is in the range of $40.5{\sim}67.4$ and the leakage current is in the range of $1.2{\sim}2.7{\mu}A$.

• Transactions on Electrical and Electronic Materials
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• v.11 no.5
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• pp.216-221
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• 2010

The microstructure, electrical properties, and DC-accelerated aging behavior of the Zn-Pr-Co-Cr-Y-Er (ZPCC-YE) varistors were investigated for different amounts of erbium oxide ($Er_2O_3$). The microstructure consisted of zinc oxide grain and an intergranular layer ($Pr_6O_{11}$, $Y_2O_3$, and $Er_2O_3$-rich phase) as a secondary phase. The increase of $Er_2O_3$ amount decreased the average grain size and increased the sintered density. As the $Er_2O_3$ amount increased, the breakdown field increased from 5094 V/cm to 6966 V/cm and the nonlinear coefficient increased from 27.8 to 45.1. The ZPCC-YE varistors added with 0.5 to 1.0 mol% $Er_2O_3$ are appropriate for high voltage, with high nonlinearity and stability against DC-accelerated aging stress.

• Journal of the Korean Institute of Telematics and Electronics
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• v.26 no.8
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• pp.1211-1216
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• 1989

To enhance the breakdown properties of low voltage-oriented ZnO varistor, sample were fabricated with additive oxides and sintering conditions. Addition of TiO2 lowered breakdown voltage` nonlinear resistances were lowered about 10V/mm and nonlinear exponents were not lowered with respect to it with the basic composition. To the samples added TiO2, V2ko5, and Cr2O3, microstructures were observed by SEM, moreover Ti was detected at grainboundaries and within the grain by EDS. Addition of Si-oxides and Sb2O3 increased nonlinear exponent and also increased nonlinear resistance, by addition of TiO2 to these samples at the sintering conditions of 1250\ulcorner and 1 hour we could fabricate low voltage-oriented ZnO varistors with nonlinear exponent of 30 or more and with real breakdown voltage of 30V/mm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.04b
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• pp.175-178
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• 2004

The microstructure, electrical, and clamping voltage characteristics of ZPCCD-based varistors were investigated at sintering time of 2 and 3 h. The average grain size and density of varistor were increased from 15.2 to 19.0 and from 5.5 to 5.6 $g/cm^3$ with sintering time, respectively. The nonlinear exponent was 65.4 for 2 h and 37.4 for 3 h, and leakage current was 0.54 ${\mu}A$ for 2 h and 0.67 ${\mu}A$ for 3 h. The dissipation factor was 0.0397 for 2 h and 0.0457 for 3 h. The clamping voltage ratio at surge current($8/20{\mu}s$) of 10~300 A was increased in the range of 1.56~2.17.

• Proceedings of the KIEE Conference
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• 2004.11d
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• pp.40-42
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• 2004

Electronic equipments made from electrical circuits with small-sized semiconductor are very weak against lightning surge. So, electronic equipments is protected by SPD(surge protective devices) such as Zno varistor. The SPD protect electronic circuit in electronic equipments and AC power lines from the lightning surge. Therefore to achieve effective method of surge protection, there are needs for correlation between lightning surge protective effect and installation method of surge protective device. Therefore this paper describes as a result of experiments for correlation between lightning surge protective effect and installation method of surge protective device.

• Journal of the Korean Society of Safety
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• v.12 no.1
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• pp.29-36
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• 1997

Precision electronic equipments for outdoor use are composed of sophisticated microcircuits that are extremely vulnerable to lightning-caused voltage spike. This transient voltage spike may cause upset, latent failure or Interference on electronic equipments. In order to develop efficient lightning protection measures on AC power lines of a road traffic controller as a electronic equipment for outdoor use, experimental surge immunity tests were conducted according to IEC standard 801-5. The combination of gas tube arrester and metal-oxide varistor was installed at the input of AC power lines and the silicon avalanche suppressor installed at the output of DC power supply for the lightning protection measures.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.06a
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• pp.1035-1040
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• 2005

This paper deals with the design rule and performance results of the surge protective devices (SPDs) for low-voltage mains on shipboard. The proposed SPDs consists of a metal oxide varistors (MOV) and a L-C filter to improve noise-elimination performance. Three kinds of SPDs are fabricated and tested by using a combination surge generator which produce the standard impulse current of 8/20${\mu}s$ 2.1kA. As a results, the proposed SPDs with series L-C filter have more excellent transient blocking and noise reduction performance than the conventional ones.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.472-475
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• 2001

The electrical properties and stability of ZPCCY-based varistors composing of $ZnO-Pr_{6}O_{11}-CoO-Cr_{2}O_{3}-Y_{2}O_{3}$ ceramics were investigated with sintering time. As sintering time is increased, the nonlinear exponent decreased in the range of 51.19~26.70. Among varistors having above 30 in nonlinear exponent, for the varistor sintered for 1h, the nonlinearity was superior to the stability comparatively and, in the case of 2h, the stability was superior to the nonlinearity relatively. Consequently, it is estimated that the varistors sintered for 1~2h will be applied to various fields by trade-off between nonlinearity and stability.