• 제목/요약/키워드: vapors

검색결과 170건 처리시간 0.036초

공기중 유기용제 농도 측정에 있어서 수동식 시료채취기의 성능평가 및 한국산 수동식 시료채취기의 개발에 관한 연구 제 1 부 : 외국산 수동식 시료채취기의 성능 평가 (Evaluation of Commercially Available Passive Samplers and Development of New Passive Samplers Part 1: Evaluation of Commercially Available Passive Samplers)

  • 백남원;박미진;윤충식
    • 한국산업보건학회지
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    • 제6권1호
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    • pp.109-124
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    • 1996
  • This study was performed to evaluate the performance of three passive samplers made in U.S.A. Three passive samplers selected for this study included products made by 3M, Gilian, and SKC in U.S.A. Three organic solvents, such as toluene, trichloroethylene, and n-hexane which are used frequently in Korean industry were selected for the study. Conclusions obtained from this study are summarized as follows. 1. For toluene and trichloroethylene, the overall accuracy of the results from all of three products was within 25 %, which is the criteria recommended by the U.S. National Institute for Occupational Safety and Health (NIOSH). For n-hexane, the overall accuracy of the results from two products except 3M was exceeding 25 %. Thus 3M product showed the best accuracy among three products. 2. When passive samplers collected organic vapors were exposed to clean air for two hours, there were 12 - 16 % loss of organic vapors due to reverse diffusion in Gilian products. There was no significant loss in results from other two products. 3. Air velocity affected greatly on the performance of passive samplers which did not have permeation membrane. At high velocity, 100 cm/sec, accuracies of results from Gilian and SKC were 57 - 108 and 128 - 164 %, respectively. However, the results from 3M samplers, which contain permeation membrane, indicated accuracy below 25 %. 4. When passive samplers collected organic vapors for eight hours, the accuracy was reduced. Thus, it is recommended that passive samplers be used for less than four hours.

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다양한 위해성평가 방법에 따라 도출한 오염토양 선별기준의 차이에 관한 연구 (I): 매체 간 이동현상 해석에 따른 차이 (Analysis on the Risk-Based Screening Levels Determined by Various Risk Assessment Tools (I): Variability from Different Analyses of Cross-Media Transfer Rates)

  • 정재웅;류혜림;남경필
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제16권2호
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    • pp.12-29
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    • 2011
  • Risk-based screening levels (RBSLs) of some pollutants for residential adults were derived with risk assessment tools developed by United States Environmental Protection Agency (USEPA), American Society for Testing and Materials (ASTM), and Korea Ministry of Environment (KMOE) and compared each other. To make the comparison simple, ingestion of soil, dermal contact with soil, outdoor inhalation of vapors, indoor inhalation of vapors, and inhalation of soil particulates were chosen as exposure pathways. The results showed that the derived RBSLs varied for every exposure pathway. For direct exposure pathways (i.e., ingestion of soil and dermal contact with soil), the derived RBSLs varied mainly due to the different default values for exposure factors and toxicity data. When identical default values for the parameters were used, the same RBSLs could be derived regardless of the assessment tools used. For inhalation of vapors and inhalation of soil particulates, however, different analysis methods for cross-media transfer rates were used and different assumptions were established for each tool, identical RBSLs could not be obtained even if the same default values for exposure factors were used. Especially for inhalation of soil particulates pathway, screening level derived using KMOE approach (most conservative) was approximately 5000~10000 times lower than the screening level derived using ASTM approach (least conservative). Our results suggest that, when deriving RBSL using a specific tool, it is a prerequisite to technically review the analysis methods for cross-media transfer rates as well as to understand how the assessment tool derives the default values for exposure factors.

수첨석유수지 개질에 의한 폴리프로필렌 필름의 특성 연구 (A Study on the Filmic Properties of Polypropylenen by Modification of Hydrogenated Hydrocarbon Resin)

  • 천봉근;성익경;이정준
    • 접착 및 계면
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    • 제14권4호
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    • pp.192-196
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    • 2013
  • 본 연구에서는 polypropylene (PP)을 기본 고분자로 하여, 석유수지(hydrocarbon resin, HCR) 종류와 함량을 달리하여PP/HCR 블랜드의 열량 거동을 분석하였고, 이를 이용하여 bi-axially oriented polypropylene (BOPP) 필름을 제조한 후 필름의 기계적 물성, 광학적 특성, 가스 및 수증기에 대한 투과도 그리고 수축률을 비교 평가하였다. 이 연구에서 HCR로는 수첨 dicyclopentadiene (DCPD) 수지와 수첨 C9 수지가 사용되었다. Homo-PP 대비 PP/HCR 블랜드는 stiffness의 증가 등 필름의 기계적 물성 증가, 필름의 haze 감소 등의 광학적 특성 향상, 가스 및 수증기에 대한 투과도 감소 그리고 필름의 수축률이 증가되었으며, HCR로 사용된 수첨DCPD수지와 수첨 C9수지는 기계적 물성 및 광학적 물성에서는 유사한 기여도를 보이지만, 가스 및 수증기에 대한 투과도와 필름의 수축률에 있어서는 차이를 보였다.

폐기물 소각시 생성되는 유해 중금속물질의 증발.응축현상에 대한 연구 (Vaporization and condensation of metallic species in hazardous waste incineration)

  • 송유석;황정호
    • 대한기계학회논문집B
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    • 제20권6호
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    • pp.1983-1993
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    • 1996
  • For selected (pure and compound) metallic species effects of saturation ratio, temperature, particle size and number density on condensation mechanisms are first reviewed. The tendencies for vaporization and condensation differ between metallic species because of the significant differences in their saturation pressures. Then particle pressure of a metal vapor species at incineration temperature is calculated by simplifying waste as a compound of methane, chlorine and small amounts of metals and assuming a thermodynamic equilibrium state. Next the condition is assessed for which supersaturation of combustion gases by the species above the critical level for homogeneous condensation may occur, when the gases contain a large number of pre-existing particles such as entrained ashes. Regardless of the presence of chlorine in the waste, the homogeneous condensation of PbO vapors may occur, depending on number density of the pre-existing particles. However, when chlorine exists in the waste, the homogeneous condensation of PbCl$_2$vapors does not occur, which is similar to the case of Cd and Hg vapors. Thus these highly volatile species, PbCl$_2$, Cd, and Hg, may emit to atmosphere as vapor phase. In general, for reducing the emission of hazardous metallic species into the atmosphere, the number density of pre-existing particles has to be increased. For fixed particle number density, the temperature drop rate must be kept in low if the temperature at which a condensable vapor species emits from a incineration system is fixed, while the temperature drop rate must be kept in high if the residence time for which a condensable species stays in the system is fixed.

유증기를 구성하는 주요 10종류 성분의 온도에 따른 흡·탈착특성 비교 (Comparisons of Adsorption-Desorption Characteristics of Major 10 Kinds Components Consisting of Gasoline Vapor)

  • 이송우;나영수;이민규
    • 한국환경과학회지
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    • 제23권9호
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    • pp.1593-1600
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    • 2014
  • Adsorption and desorption characteristics of the representative 10 kinds components consisting of gasoline vapor on activated carbon were investigated at the temperature range of $-30^{\circ}C{\sim}25^{\circ}C$. The breakthrough curves of each vapors obtained by the Thomas model were well described the breakthrough experimental results of this study. The breakthrough times of each vapors were correlated with the molecular weight, density, and vapor pressure. The breakthrough times had greater correlation with boiling point than molecular weight and density. The slope of the breakthrough curve was a proportional relationship with the rate constant (k) of Thomas model expression. The higher the slope of the breakthrough curve, the rate constant was larger. The biggest slope vapor had the smallest adsorption capacity ($q_e$). Adsorption and desorption characteristics of mixed vapor similar to the gasoline vapor were studied at room temperature ($25^{\circ}C$). The mixed vapor consisting of 9 components; group A (pentane, hexene, hexane), group B (benzene, toluene), group C (octane, ethylbenzene, xylene, nonane) was examined. Group A was not nearly adsorbed because of substitution by group C, and the desorption capacity of group A was smaller than group C. The adsorbed substances were confirmed to be Group C.