• Title/Summary/Keyword: urethane composite

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Degradation Characteristics of Filament-Winding-Laminated Composites Under Accelerated Environmental Test (필라멘트 와인딩 복합적층재의 환경가속 노화시험 평가)

  • Kim, Duck-Jae;Yun, Young-Ju;Choi, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.3 s.258
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    • pp.295-303
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    • 2007
  • Degradation behaviors of filament-winded composites have been evaluated under the accelerated environmental test of high temperature, water immersion and thermal impact conditions. Two kinds of laminated composites coated by an urethane resin have been used: carbon-fiber reinforced epoxy(T700/Epon-826, CFRP) and glass-fiber reinforced phenolic (E-glass/phenolic, GFRP). For tensile strength of $0^{\circ}$ composites, CFRP showed little degradation while GFRP did high reduction by 25% under the influence of high temperature and water However for water-immersed $90^{\circ}$ composites tensile strength of both CFRP and GFRP showed high reduction. Bending strength and modulus of $90^{\circ}$ composites were largely reduced in water-immersion as well as high temperature environment. Urethane coating on the composite surface improved the bending properties by 20%, however hardly showed such improvement for water-immersed $90^{\circ}$ composites. In case of shear strength and modulus, both CFRP and GFRP showed high reduction by water-Immersion test but did a slight increase by high temperature and thermal impact conditions.

Synthesis of UV-Curable Modified (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate Acrylate (자외선 경화형 변성 (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate 아크릴레이트의 합성)

  • Lee, Jongmin;Yi, Hwanpyo;Lee, Sanggun;Park, Hyungnam;Choi, Kangsik;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.27 no.4
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    • pp.199-205
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    • 2017
  • In this study, (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate acrylate was synthesized by reacting (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate with acrylic acid to minimize hardening shrinkage and to improve heat resistance, which are known as disadvantages of photopolymers for 3D printing application. Urethane acrylate was synthesized by reacting 1,3,5-triazine-2,4,6-triamino alcohol, 2-hexylethyl acrylate, and isophorone diisocyanate in order to improve the mechanical properties without deteriorating the heat resistance. The physical properties before and after the synthesis of the acrylate and the mechanical properties when the urethane acrylate was applied were investigated. The reaction progress of the composite was examined by FTIR and $^{13}C$ NMR. The heat deflection temperature, flexural strength, and surface hardness of the molding were measured. The curing behavior by Photo-DSC ultraviolet irradiation was also examined.

A look at rooftop waterproofing methods that combine a circular adhesive insulated composite duplex exposure repellent with a airvent (원형 접착 절연형의 복합 복층형 노출 방수제와 탈기관을 결합한 옥상 방수 공법에 관한 고찰)

  • KIM, Yeong-Seok;JEON, Sang-Hoon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.236-237
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    • 2021
  • In the waterproofing of the rooftop of reinforced concrete buildings, it is difficult to solve perfectly according to the proficiency of waterproofing materials, methods, and mechanics. Therefore, this study applies a Tricot Fabric Mesh to the behavior of the bottom concrete. In addition, it responds to the behavior of the concrete cracking, and the waterproofing and protective layer has developed a method to provide convenience for rooftop floor use by adhesion between the base and the waterproof layer with the use of high viscosity urethane to effectively move the surface deformation and surface vapor and install a airvent device on the wall.

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AN EXPERIMENTAL STUDY ON PHYSICAL PROPERTIES OF VARIOUS POSTERIOR RESTORATIVE COMPOSITE RESINS (수종(數種) 구치부(臼齒部) 충전용(充塡用) 복합(複合)레진의 물리적(物理的) 성질(性質)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Park, Sun-Jae;Park, Sang-Jin;Min, Byang-Soon;Choi, Ho-Young
    • Restorative Dentistry and Endodontics
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    • v.12 no.1
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    • pp.7-24
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    • 1986
  • The purpose of this study was to observe the compressive strength, compressive fatigue strength, surface hardness, water sorption and solubility of eight different posterior restorative composite resins. Eight composite resins were tested for their strength of the compressive and compressive fatigue with prepared two different types of specimens (I and T-type) using a Instron universal testing machine (model No. 1332). The hardness was measured with a Knoop hardness tester (MVH-2, Tokyo) for each cylindrical specimen, 7mm in diameter and 5mm thick. The water sorption and solubility were evaluated with the prepared composite resin disks, 20mm in diameter and 1mm thick. The results were as follows: 1. The compressive strength, compressive fatigue strength and hardness were noticed to be Increased by increasing the volume content of filler. 2. The compressive strength was appeared to be independent on the type of specimen, but the compressive fatigue strength was found to be greatly influenced by the type of specimens. 3. The composite resins having higher compressive strength had also higher compressive fatigue limits. 4. The compressive fatigue limits at $10^5$ stress cycles were about 50-80% of the compressive strength and were showen to be dependent on the materials and type of specimens. 5. The larger the filler particle size was, the lower was the water sorption. And the water sorption of BIS-GMA resin was higher than that of urethane resin. 6. The visible light-cured composite resin had a higher value of solubility than the chemically- cured composite resin. And the solubility tended to decrease by increasing the volume content of filler.

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Aerodynamic and Structural Design on Small Wind Turbine Blade Using High Performance Configuration and E-Glass/Epoxy-Urethane Foam Sandwich Composite Structure (고성능 형상 및 유리섬유/에폭시-우레탄 샌드위치 구조를 사용한 소형 풍력발전 블레이드의 공력 및 구조설계)

  • Chang-Duk Kong;Jo-Hyug Bang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.1
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    • pp.70-80
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    • 2004
  • This study proposes a development result for the 1-kW class small wind turbine system, which is applicable to relatively low wind speed regions like Korea and has the variable pitch control mechanism. In the aerodynamic design of the wind turbine blade, parametric studies were carried out to determine an optimum aerodynamic configuration which is not only more efficient at low wind speed but whose diameter is not much larger than similar class other blades. A light composite structure, which can endure effectively various loads, was newly designed. In order to evaluate the structural design of the composite blade, the structural analysis was peformed by the finite element method. Moreover both structural safety and stability were verified through the full- scale structural test.

Synthesis and Analysis of Multi-functional Urethane Acrylate Monomer, and its Application as Curing Agent for Poly(phenylene ether)-based Substrate Material (다관능 우레탄 아크릴레이트 단량체의 합성과 분석, 및 폴리페닐렌에테르 기판소재용 경화성분으로의 적용)

  • Kim, Dong-Kook;Park, Seong-Dae;Oh, Jin-Woo;Kyoung, Jin-Bum
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.413-419
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    • 2012
  • Multi-functional urethane acrylate monomers as the curing agent of poly(phenylene ether) (PPE) were synthesized and then the urethane bond formation was checked by FTIR spectrometry and NMR analysis. The synthesized monomers were mixed with PPE and fabricated to dielectric substrates. After forming PPE/monomer composite sheets by a film coater, several sheets were laminated to a test substrate in a vacuum laminator and then its properties depending on the type and the amount of monomers, such as dielectric constant, dielectric loss, and peel strength, were measured. Between the two different hydroxyl acrylates, when the monomer synthesized with 2-hydroxy-3-phenoxypropyl acrylate containing a phenyl group was used as a curing agent, a smaller dielectric loss was obtained and the dielectric constant and loss decreased with a decrease in the amount of the monomer. The peel strength values of the test substrates, however, did not show any specific difference between the cases of two synthesized monomers. As a result, it was obtained the polymer substrate for high frequency application having peel strength of about 10 N, low dielectric constant of 2.54, and low dielectric loss of 0.0027 at 1 GHz.

Study on the Thin-walled carbon nanotubes (TWNTs)/Amine epoxy additive composite via supercritical fluid process (초임계 공정을 이용한 Thin-walled carbon nanotubes (TWNTs)/아민계 에폭시 첨가제의 복합체 제조)

  • Kim, Yong-Ryeol;Jeong, Hyeon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.486-491
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    • 2014
  • We have been fabricated Thin-walled carbon nanotubes (TWNTs)/amine epoxy additives composite using Eco-friendly solvent system such as supercritical process and dry mixed process. TWNTs/amine epoxy additives composite has used as a curing agent for urethane based bisphenol A type epoxy resin. The thermo-mechanical property of the epoxy resin cured by TWNTs/amine epoxy additives composite is characterized by dynamic mechanical analysis(DMA) and dispersability of the nanotubes in the epoxy matrix is also confirmed by scanning electron microscope(SEM). As a results, the epoxy resin cured by TWNTs/amine epoxy additives composite with supercritical process shows enhanced dispersability of the TWNTs in the matrix and thermo-mechanical property when compare to dry mixed process.

Poling Field Effect on Absorption and Luminescence of Disperse Red-19 and TiO2 Composites

  • Kim, Byoung-Ju;Hwang, Un-Jei;Jo, Dong-Hyun;Lim, Sae-Han;Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • v.3 no.1
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    • pp.5-9
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    • 2015
  • Absorption and luminescence characteristics of disperse red-19 (DR-19) and $TiO_2$ composite have been investigated with various poling electric field strengths. Two step synthetic processes were employed to employ the DR-19 to the $TiO_2$ sol-gel. Firstly, urethane bond formation between DR-19 (-OH) and 3-isocyanatopropyl triethoxysilane (ICPTES, -N=C=O) performed (ICPDR) prior incorporation to the $TiO_2$ sol-gel. Secondary, the hydrolysis of the ethoxy group from the ICPTES and condensation reaction between silanol groups from ICPTES and $TiO_2$ sol-gel were performed. The ICPDR and $TiO_2$ sol-gel ($DRTiO_2$) were mixed and stirred for several days. The composite was coated to the ITO coated glass substrate. Corona poling were performed before drying the composite with various electric field strengths. The absorption intensity decreased with the increase of the poling field strength, which resulted in the increase of poling efficiency. The photoluminescence also decreased as the poling field strength increased. There is long luminescence tail for the poled $DRTiO_2$ film compared with unpoled $DRTiO_2$ film. The luminescence long tail indicates that the self-trapped excitons and polarons were generated when the $DRTiO_2$ film was poled with electric field.

Numerical Analysis of Impact Force Transfer Characteristics of Court Sport Shoes to Surface Condition (지면조건에 따른 코트 스포츠화 착지 충격력의 전달특성 수치해석)

  • 류성헌;최주형;김성호;부진후;조진래
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.12
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    • pp.1974-1981
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    • 2004
  • This paper is concerned with the numerical investigation of the transfer characteristics of the landing impact force exerted on court sport shoes to the sport surface condition. The reaction force occurred by the impact between court sport shoes and sport surface is absorbed by shoes to some extent, but the remaining impact force is to transfer the human body from the sole of a foot. We consider four surface conditions, asphalt, urethane, clay and wood court surfaces. For the dynamic response analysis, we construct a coupled leg-shoes FEM model and create the multi-layered composite surface model. The numerical simulations are performed by an explicit nonlinear finite element method. Through the numerical experiments, we examine the transfer characteristics of the landing impact force to the surface condition.

Effective Equivalent Finite Element Model for Impact Limiter of Nuclear Spent Fuel Shipping Cask made of Sandwich Composites Panels (사용후 핵연료 수송용기 샌드위치 복합재 충격완충체의 유효등가 유한요소 모델 제시)

  • Kang, Seung-Gu;Im, Jae-Moon;Shin, Kwang-Bok;Choi, Woo-Suk
    • Composites Research
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    • v.28 no.2
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    • pp.58-64
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    • 2015
  • The purpose of this paper is to suggest the effective equivalent finite element model for the impact limiter of a nuclear spent fuel shipping cask made of sandwich composite panels. The sandwich composite panels were composed of a metallic facesheet and a core material made of urethane foam, balsa wood and red wood, respectively. The effective equivalent finite element model for the impact limiter was proposed by comparing the results of low-velocity impact test of sandwich panels. An explicit finite element analysis based on LS-DYNA 3D was done in this study. The results showed that the solid elements were recommended to model the facesheet and core of sandwich panels for impact limiter compared to combination modeling method, in which the layered shell element for facesheet and solid element for core material are used. In particular, the solid element for balsa and red wood core materials should be modeled by the element elimination approach.