• Journal of the Korea Institute of Building Construction
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• v.2 no.1
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• pp.139-146
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• 2002

This study deals with the characterizing and the application like as insulation materials in the joint part in concrete surface layer and waterproofing sheet especially for roof slabs. Using steel materials and butil-rubber tape to band waterproofing sheet and concrete surface together before this waterproofing system will be applied. It can be expected to both the curability and the watertightness by coating poly-urethane 2 or 3 times with sheet surface. Therefore this waterproofing system can be possible to protect water without the damage when vapor is going out from concrete and without air pockets because of the difference temperature inside and out. This system particularly consists of air bents and elastic waterproofing sheet considering the physical damage while water can cause purely physical damage. This system is one of the most efficient ways of waterproofing system without air pocket.

• Fibers and Polymers
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• v.3 no.3
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• pp.97-102
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• 2002

A series of waterbome poly(urethane-urea) anionomers were prepared from isophorone diisocyanate (IPDI), polycaprolactone diol (PCL), dimethylol propionic acid (DMPA), ethylene diamine (EDA), and triethylamine (TEA), NaOH, or Cu($(COOCH_3)_2$) as neutralizing agent. This study was performed to decide the effect of neutralizing agent type on the particle size viscosity, hydrogen bonding index, adhesive strength, antistaticity, antibacterial and mechanical properties. The particle size of the dispersions decreased in the following order: TEA based samples (T-sample), NaOH based samples (N-sample), and Cu($(COOCH_3)_2$) based sample (C-sample). The viscosity of the dispersions increased in the order of C-sample, N-sample, and T-sample. Metal salt based film samples Of and C-sample) had much higher antistaticity than TEA based sample. By infrared spectroscopy, it was found that the hydrogen bonding index (or fraction) of samples decreased in the order of T-sam-pie, N-sample, and C-sample. The adhesive strength and tensile modulus/strength decreased in the order of T-sample, N-sam-pie, and C-sample. The C-sample had strong antibacterial halo, however, T- and N-samples did not

• Macromolecular Research
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• v.14 no.3
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• pp.300-305
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• 2006

The chemical structure of a semi-aromatic polyimide-I, which was prepared by the chemical imidization of cyclopentanetetracarboxylic dianhydride and 2,2-bis(4-aminophenyl)hexafluoropropane, was characterized by $^{13}C-NMR$ spectroscopy. The chemically imidized polyimide-I was used for the preparation of a photosensitive polyimide (PSPI) through the addition of benzophenone and benzophenone oxime hexamethylene diurethane (BOHD), a photobase generator containing oxime-urethane groups. The polyimide-I film containing benzophenone and BOHD was not soluble in 2.38 wt% tetrabutylammonium hydroxide solution in $H_2O$. However, it became soluble following irradiation with 310 nm UV light. A positive tone image with a resolution of $5{\mu}m$ was obtained with this PSPI, having sensitivity($D_c$) of $1.2J/cm^2$ and contrast(${\gamma}_p$) of 1.08. Thus, a polyimide, which is not intrinsically photosensitive, can become photosensitive through the addition of a photobase generator containing oxime-urethane groups as a photosensitive compound.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05a
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• pp.127-130
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• 2011

The duplex waterproofing construction method has been investigated to improve various problems (how to fix the sheet, breaking, air/water pocket, and cracks caused by different materials) of the existing rooftop exposed waterproofing construction method. By using fiber sheet, Net PE fabric, and thixotropy urethane with high viscosity, the waterproofing construction method is to glue the ground and waterproof course by circular dot. The method is also to construct the waterproof course with high hardness by using waterproof membrane coatings in upper hybrid system. By gluing the ground and the waterproof course by circular dot, the study is expected to be useful to minimize the simultaneous breaking in the waterproof course as tensile stress is buffer in case of the ground crackling. Also, since the waterproofing construction method is good at moving and emitting vapor from the ground, it is considered to be effective to minimize any damages caused by air/water pocket and get loose of the waterproof course.

• Elastomers and Composites
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• v.35 no.3
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• pp.227-235
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• 2000

This study focused on the recycling technology and application of waste polyurethane scrap($5{\sim}7mm$) and waste urethane form from the footware scrap. Firstly we suggest the waste polyurethane can be used as a component of medium for hydroponic rose culture. Secondly, recycled thermoplastic polyurethane(RTPU) was produced and blended it with high impact polystyrene(HIPS). And also, in order to extend application of recycling field, the former was produced with adding the amine foaming agent to RTPU/HIPS alloy. The main purpose of this study is to diverse of the recycling of the waste polyurethane.

• Journal of the Semiconductor & Display Technology
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• v.16 no.3
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• pp.87-92
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• 2017

Poly(urethane acrylate) siloxane oligomers with Interpenetrating polymer networked nanoparticles were prepared to synthesize hard coating solution by reaction with isophorone diisocyanate(IPDI) of 1, 2, 3, 4 phr. The structures and molecular weights of the synthesized solutions were characterized by IR spectroscopy and gel permeation chromatography, respectively. In the cross-cut test for the adhesion, all the solutions showed good adhesion of 5B regardless of the content of IPDI and film thickness. The addition of 1 phr IPDI resulted in the best pencil hardness. The IPDI combined siloxane hard coating solution showed more flexibility than the siloxane solution. These results will yield the improvement in the siloxane solution using for plastic display plate.

• Transactions of Materials Processing
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• v.33 no.1
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• pp.5-11
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• 2024

The development of a next-generation hydrogen compressor, a key component in the expansion of hydrogen charging infrastructure, is in progress. In order to improve compression efficiency and durability, it is important to optimize the precision forming and shearing processes of the diaphragm, which is the bellows unit cell, as well as the optimization of diaphragm shape itself. In this study, we aim to show that die and process design technology that can synchronize the inner and outer shearing points of the diaphragm for the precision forming of product can be constructed based on a numerical simulation. First, the damage model that can predict the fracture points will be determined using the shear load and shear zone measurements obtained by performing a blanking test of AISI-633 stainless steel. Next, we will explain the overall procedure based on numerical analysis model how to determine the shearing points according to the deformation pattern of urethane die for various shearing die design.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.25-26
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• 2023

The internal core material and external color of a sandwich panel have a significant impact on the performance of the sandwich panel. For use on roofs and walls, the internal core material and external color must be considered. Therefore, the surface and back side temperatures were measured for each exterior color and inner core material type. For the internal core materials, urethane foam and Expanded Poly Styrene(EPS), which are core materials mainly used in sandwich panels, were selected. As colors, black and ivory were selected according to brightness, and a total of five colors were selected: red, blue, and green, which are the three primary colors of light. As a result, there were differences in surface and temperature depending on the external color and type of internal core material. Regardless of the color, the temperature was measured lower for panels with urethane foam than for panels with an internal core of EPS. This is believed to have been influenced by the difference in thermal conductivity of urethane foam being 0.023W/(m·K) and that of EPS being 0.032W/(m·K). In addition, panels with a black exterior color were found to have higher surface and back temperatures than panels of other colors, and ivory-colored panels had lower back temperatures regardless of the core material. This is proportional to the brightness and light-absorbing characteristics.

• Conservation Science in Museum
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• v.17
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• pp.85-100
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• 2016

The Bukji-ri Stone Pensive Bodhisattva of Bonghwa in the collection of Kyungpook National University Museum was transported to the National Museum of Korea for display in a special exhibition('Masterpieces of Early Buddhist Sculpture 100 BCE - 700 CE') and therefore underwent conservation ahead of the exhibition's start date. The stone sculpture had visibly encrusted surface dirt, granular disintegration and fissures upon arrival. Notably, a crack running obliquely across its lower half rendered the object unable to support its own weight without a pedestal, so one was created in order to maintain the sculpture in an upright position while on exhibition. The sculpture was further examined using a polarizing microscope and a stereoscopic microscope. SEM-EDS resulted in petrographic analysis of the stone's mineral composition and identification of its surface contaminants. Polarizing light microscopy confirmed biotite granite as the main mineral component of the object. Several urethane resins cast in round cross-sections were inserted into the newly made pedestal and stability tests were perform to measure the frictional force of the resins. An additional test was performed to compare urethane resin and epoxy resin, with results showing urethane to have a higher coefficient of friction. Utilizing a pedestal with urethane resin effectively ensured the stability of the Bukji-ri Stone Pensive Bodhisattva of Bonghwa during the aforementioned exhibition.

• Economic and Environmental Geology
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• v.53 no.3
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• pp.287-296
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• 2020

Mine Reclamation Project is being carried out with the aim of ensuring a sustainable green living and helping to develop eco-friendly mines by analyzing, removing and preventing the harmful factors. Mines developed during the japanese colonial period and mining boom period are still not repaired throughout the country, and from these scattered risks, public safety is worth pursuing as a top priority. The project that is close to public safety in the mine recalmation project is an emergency treatment, and the most widely used method is a filling method similar to the ground subsidence prevention. If dangerous mine cavity or tunnels are located in the mountains, charging with existing materials may not be possible, or unreasonable cases may occur, and new methods of technological development are required. Emergency actions should be carried out safely and efficiently to prevent the loss of precious people's lives on the hiking paths adjacent to dangerous mining sites. In these field conditions, urethane foam materials may be an alternative. In this study, the applicability of urethane foam materials in mining was reviewed through overseas cases. It was also tested on the appropriate depth of top soil for the protection of urethane foam materials through forest fire simulation test. The test result show that approximately 15cm of soil covering (recommended 20cm over) was suitable for maintaining the function of foam materials from forest fires.