• Journal of the Korean Wood Science and Technology
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• v.1 no.2
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• pp.11-15
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• 1973

This study was carried out to utilize sweet potato, and jerusalem artichoke flour as an extender of urea formaldehyde resin for plywood manufacture. The results obtained are summarized as follows: 1) In dry and wet test of plywood, sweet potato flour extended in urea formaldehyde resin was shown better strength than those of wheat flour. 2) Sweet potato flour was shown good results up to 200 percent extension in the dry test, and there was not shown significant difference between 100 percent and 150 percent extension in the wet test. 3) In the case of 100 percent extension, potato flour was shown best dry shear strength(400 psi) and sweet potato flour was shown best wet shear strength (212 psi).

• Journal of the Korean Society of Clothing and Textiles
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• v.5 no.1
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• pp.23-26
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• 1981

In this paper, the extraction mechanism of free formaldehyde in the urea formaldehyde resin finished cotton fabric is discussed. An empirical equation for formaldehyde release has been formulated. $$F=3.7\times10^{-3}\;H\;T^{2.2326}+440$$ in which, F: the amount of free formaldehyde extracted ($\mu$g/g) H: extraction time (min) T: extraction temperature ($^{\circ}C$)

• Journal of the Korean Wood Science and Technology
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• v.26 no.4
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• pp.50-55
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• 1998

This study was carried out to develop low density board made of rice hull which needs proper use. Urea formaldehyde adhesive(UF) was used. The raw materials were the mixtures of the rice hulls from IllFum, DongGin, ChuChong, etc. The physical and mechanical properties of rice hull insulation board were examined. The results are as follows : For the thickness of 15mm of the low density rice hull board bonded with UF resin, proper manufacturing conditions were $171^{\circ}C$ of hot pressing temperature with thickness bar for optimum density, 12 percent of resin solid contents of rice hull ovendry weight, and 20 minutes of hot pressing time. These conditions meet Korean standards(KS 3201-1982) in relation to free formaldehyde emission, bending strength, water absorption and heat resistance.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1128-1135
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• 2019

In this study, different types of polyether amines and H₁₂MDI were used to synthesize water dispersed urea resins, which can be applied to coating material on the concrete slabs for bicycle road using the ordinary application equipments. The concentrations of several polyether amines with different molecular weights and the number of amine functionality were varied to set up the optimal condition for water dispersed urea resin preparation with both an excellent tensile strength and an elongation. In addition, the effect of DMPA[2,2-Bis(hydroxymethyl)propanoic acid] concentration on the storage stability of the water dispersed urea resin was also investigated. The formation of urea bonds from isocyanate and polyether amines was confirmed through FT-IR ATR spectroscopy. From the mechanical properties of urea resins, PU-4 and PU-6, which were prepared with both diamines and triamine of different molecular weights and number of functionality, showed the tensile strength of 10.5 N/㎟ and 12.7 N/㎟, respectively and the elongation of 1165 % and 969%, respectively. Among the water dispersed urea resin synthesized with different contents of DMPA, PU-6 showed the highest mechanical properties, a tensile strength of 14.2 N/㎟ and an elongation of 993%. In addition, the water dispersion state of this PU-6 was the most stable even after 8 weeks.

• Journal of the Korean Wood Science and Technology
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• v.45 no.4
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• pp.409-418
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• 2017

This work attempted to manufacture glued-laminated timber (Glulam) bonded with melamine-urea-formaldehyde (MUF) resin adhesives at various melamine contents from 20% to 50% under high frequency (HF) heating for a very short time. Two preparation methods were employed to prepare MUF resin adhesives with different melamine contents: one-batch method of synthesizing MUF resins in a single batch, and two-batch method of mixing urea-formaldehyde (UF) resin with melamine-formaldehyde (MF) resin that had been synthesized separately. As the melamine content increased, the gelation time and peak temperature of MUF resins decreased. The adhesion performance of plywood showed that the one-batch MUF resin adhesive with 50% melamine content only satisfied the standard requirement of water resistance. Thus, the one-batch MUF resin adhesive with 50% melamine content was applied for bonding wood lamina from four softwood species such as Japanese larch, Korean red pine, Korean pine and Japanese cedar to manufacture Glulam under HF heating. All Glulam samples bonded with the one-batch MUF resin adhesives with 50% melamine content except those from Korean Red Pine satisfied the requirement in water soaking or boiling water delamination test as an exterior grade Glulam. The presence of rosin in Korean Red Pine was believed to be responsible for its poor adhesion. These results showed that the one-batch MUF resin adhesives with 50% melamine content provided acceptable water resistance with exterior grade Glulam manufactured under HF heating.

• Journal of the Korean Wood Science and Technology
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• v.33 no.2 s.130
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• pp.29-39
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• 2005

Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

• Journal of the Korean Wood Science and Technology
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• v.28 no.4
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• pp.83-93
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• 2000

This study was carried out to improve the physico-mechanical properties of board products by applying the technique of high frequency heating, and find out the optimum conditions of high frequency heating, compared with the technique of hot platen heating. The possibility of isocyanate resin application to board production was also considered to solve the problem of free formaldehyde emission from urea resin which is generally used in wood industry. For this study, 30 mm thick MDP (medium density fiberboard) with isocyanate resin were manufactured by the techniques of hot platen heating, high frequency heating and the combination techniques of both heating methods, and compared in several point of views.

• Journal of Adhesion and Interface
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• v.13 no.2
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• pp.85-88
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• 2012

In this paper, the curing reaction of UF resins was investigated by a real time FT-IR method. The curing temperature range of the UF resin was $25{\sim}200^{\circ}C$. It was found that the reactions of UF resin at different temperatures resultedin resins with different cross-linked structures. A real time FT-IR spectroscopy can be considered as a good routine analytical tool for following the progress of UF resin curing.

• Journal of the Korean Wood Science and Technology
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• v.27 no.2
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• pp.23-30
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• 1999

This study was carried out to develop the Korean paper(Hanji) sludge-wood fiber composite boards utilizing the relinquished sludges occurring from the making process of Korean classic paper Hanji. The bark of paper mulberry(Broussonetia kazinoki Sieb.) has been used as a raw material since past hundreds and thousands years. Korean paper(Hanji) sludge was divided into two kinds, the one was the white sludge from the first stage and the other was the black sludge occurring from the final stage of Korean paper(Hanji) making. Four levels of the mixed ratio of each white or black sludge to wood fiber(10:90, 20:80, 30:70 and 40:60), three levels of the resin adhesives(PMDI, urea and phenol resin) and three levels of the density(0.60, 0.75 and 0.90) were designed to investigate the physical properties of Korean paper(Hanji) sludge-wood fiber composite boards. From the results and discussion, it could be concluded as follows : 1. In the white sludge-wood fiber composite board, the thickness swelling was not affected by the specific gravity and sludge additive of composite boards, but among the resin adhesives PMDI resin showed the best dimensional stability. Water absorption was superior in urea resin, secondly PMDI resin and very poor in phenol resin. 2. In the black sludge-wood fiber composite board, thickness swelling was superior in PMDI resin but very poor in phenol resin. In water absorption, PMDI and urea resin showed good results, regardless of specific gravity or sludge additive, but phenol resin showed poor results. 3. From the results and discussion of physical properties it is suggested that the white sludge-wood fiber composite boards bonded with PMDI or black sludge-wood fiber composite boards bonded with urea resin were made possibly with similar or better properties. compared with general fiberboard until the addition of 20% sludge into wood fiber.

• Journal of Korean Society of Forest Science
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• v.24 no.1
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• pp.45-52
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• 1974

This study was carried out to examine the subsitution possibility into water soluble amino resins instead of phenolic resin as a sizing material for the strength increase on the wet forming hardboard. The properties of hardboard, manufactured with amino-resins based urea, melamine, formaline, and methanol which were low priced domestic products, were examined in comparison with those of hardboard treated with phenolic resin. In this study by the results and discussions, it may be summarized as follows: 1. Amino-resins are able to be substituted for the phenolic resin as a good sizing material for strength increase in the manufacture of wet forming hardboard. Under the considerations of economic advantages and properties of hardboard, modified urea-melamine resin was given a best results. 2. The specific gravities of hardboard that were treated with phenolic resin was equal to that treated with modified amino type resin, and in case of urea-melamine resin, the specific gravity value were lowest among them. 3. The results of moisture contents were satisfied the standard which calls for 13 percent or below. There were no differences in moisture contents between hardboards, treated with melamine resin and modified urea-melamine resin but phenolic resin. The moisture contents of hardboard treated with phenolic resin was shown the lowest. 4. The water absorption of hardboard treated with phenolic resin was greater than those treated with amino resins, and to satisfy the standard of water resistance, the treatment of 2 percent paraffin wax emulsion was needed in this case. There were no differences in water absorptions between hardboards, treated with melamine resin and modified urea-melamine resin. To satisfy the standard of water resistance in this case the treatment of 1 percent paraffin wax emulsion was shown good results. 5. The differences among the flexural strength in using tested three adhesives were significant. The flexural strength were shown the signification by order of melamine resin, modified urea-melamine resin, and phenolic resin. In all cases to satisfy the standard of flexural strength, the treatment of 3 percent sizing materials for strength increase was needed.