• Title/Summary/Keyword: urea formaldehyde resin

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Long Term Formaldehyde Emission Trend of Wood Panels Manufactured by F/U Molar Ratios in Urea Resin Adhesive (요소수지의 F/U 몰비별로 제조된 목질패널의 포름알데히드 장기 방출 경향)

  • Park, Heon
    • Journal of the Korea Furniture Society
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    • v.11 no.2
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    • pp.73-78
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    • 2000
  • This study was carried out to measure formaldehyde emission with the passing of two years from plywood, sliver-board and strand-board bonded with urea resins which were made of 6 f/U molar ratios. The urea resins were manufactured by six kinds of formaldehyde/urea molar ratio of 1.0, 1.2, 1.4, 1.6, 1.8 and 2.0. 1. The plywood with molar ratio of 1.0 satisfied the KS F3101 $F_2$ directly after manufacture. The plywood with molar ratio of 1.2 satisfied m 3 days. The plywood with molar ratio of 1.4 satisfied the $F_3$ in 3 days and the $F_2$ in 600 days. And the plywood with molar ratio of 1.8 and 2.0 satisfied the $F_3$ in 365 days, but didn't satisfy the $F_2$ in 730 days. 2. Sliver-board with molar ratio of 1.0 and 1.2 satisfied the KS F3104 $E_2$ right after manufacture. Sliver-board with molar ratio of 1.4 and 1.6 satisfied in 150 and 360 days, respectively. Sliver-board with molar ratio of 1.8 and 2.0 satisfied in 730 days. 3. Strand-board with molar ratio of 1.0 and 1.2 satisfied the KS F3104$ E_2$ directly after manufacture. Strand-board with molar ratio of 1.4 and 1.6 satisfied in 150 days. But Strand-board with molar ratio of 1.8 and 2.0 didn't satisfied in 730 days.

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Manufacture of Wood Veneer-Bamboo Zephyr Composite Board: II. Effect of Manufacturing Conditions on Properties of Composite Board (목재 단판-대나무 제퍼 복합보드 제조: II. 복합보드의 성능에 미치는 제조조건의 영향)

  • Roh, Jeang Kwan
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.108-117
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    • 2007
  • This research was performed to investigate the feasibility of bamboo as a raw material for the manufacture of plywood. Wood veneer-bamboo zephyr composite boards (WBCB) were manufactured using keruing (Dipterocarpus sp.) veneers and hachiku bamboo (Phyllostacbys nigra var. henonis Stapf) using various adhesives, and the effect of the method and amount of resin spread on the mechanical properties of the composites were investigated. The WBCB manufactured using polymeric isocyanate (PMDI) showed the best mechanical properties, followed by phenol-formaldehyde resin (PF), phenol-melamine-formaldehyde resin, urea-melamine-formaldehyde resin, and urea-formaldehyde resin. However, considering the operation feasibility as well as mechanical properties, PF resin proved to be the appropriate adhesive for the practical purpose. As the amount of resin spread increased, the mechanical properties of 5-ply WBCB with 12 mm thicknesses manufactured using PF resin tended to increase, and more failure occurred at the interface between veneer and bamboo zephyr than at the interface among bamboo zephyrs. This result suggests that penetration of resin into bamboo zephyr could be the important factor. In this research, the appropriate amount of resin amount was $320g/m^2$. 5-ply WBCBs were manufactured using various methods of resin spread but the effect of the methods on the mechanical properties showed no little difference, which meant that the method of resin spread could be chosen considering the manufacturing conditions and operation feasibility.

The Improvement of Physico-mechanical Properties of MDF with High Frequency Heating Technique

  • Youh, Shin-Jae;Jo, Byoung-Muk;Oh, Jung-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.4
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    • pp.83-93
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    • 2000
  • This study was carried out to improve the physico-mechanical properties of board products by applying the technique of high frequency heating, and find out the optimum conditions of high frequency heating, compared with the technique of hot platen heating. The possibility of isocyanate resin application to board production was also considered to solve the problem of free formaldehyde emission from urea resin which is generally used in wood industry. For this study, 30 mm thick MDP (medium density fiberboard) with isocyanate resin were manufactured by the techniques of hot platen heating, high frequency heating and the combination techniques of both heating methods, and compared in several point of views.

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Reduction of Formaldehyde Emission from Particleboardsby Bio-Scavengers

  • Eom, Young-Geun;Kim, Jong-Sung;Kim, Sumin;Kim, Jin-A;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.5
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    • pp.29-41
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    • 2006
  • This study was to investigate the effect of adding additive as tannin, rice husk and charcoal, for reducing the formaldehyde emission level, on the adhesion properties of urea-formaldehyde (UF) resin for particleboard. We controlled the hot-pressing time, temperature and pressure to determine the bonding strength and formaldehyde emission. Blends of various UF resin/additives (tannin, rice husk and charcoal) compositions were prepared. To determine and compare the effect of additives (tannin, rice husk and charcoal) content, 0, 5, 10 and 15%, by weight of UF resin, were used. $NH_4Cl$ as hardener added. To determine the level of formaldehyde emission, we used the desiccator, perforator and 20 L-small chamber method. The formaldehyde emission level decreased with increased additions of additive (except rice husk). Also, increased hot-pressing time decreased formaldehyde emission level. At a charcoal replacement ratio of only 15%, the formaldehyde emission level is under F ✩ ✩ ✩ ✩ grade (emit < $0.3mg/{\ell}$). Curing of the high tannin additive content in this adhesive system indicated that the bonding strength increased. But, in the case of rice husk and charcoal, the bonding strength was much lower due to the inorganic substance. Furthermore, rice husk was poor in bonding strength as well as formaldehyde emission than tannin and charcoal.

Performance Evaluation of Particleboard from Wastewood (폐목재로 제조된 파티클보드의 성능평가)

  • Oh, Yong-Sung;Cha, Jae-Kyung;Kwak, Jun-Hyuk
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.4
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    • pp.23-26
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    • 2002
  • The generation of wastewood is currently about 40% level of the amount of domestic wood use. When the rate of wood self-supply is considered, the recycling of wastewood in wood panel products industry should be encouraged. This study was evaluated the performance of particleboard (PB) made from wastewood. PBs were manufactured with the synthesized urea-formaldehyde resin at 5 minutes hot-press time, and at 162℃ press temperature with 6 percent resin solids level on an ovendry wastewood particle weight basis. The PBs were tested by the procedure of ASTM D 1037. Test results exceeded the minimum strength requirement according to KS F 3104 Particleboard type 8.0. The PB's performance showed that wastewood is suitable raw material for PB.

Mechanical and Physical Properties of Roof Tile Prepared from Sugar Cane Fiber

  • Wong on, Jessada;Surin, Prayoon;Apawet, Chaiyaprek;Eidhed, Krittee;montra, Sunate;Aumkongthum, Kaichai;Thumsorn, Supaphorn
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.86-89
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    • 2015
  • Sugar cane, renewable fiber resources, were used for roof tile production. Urea formaldehyde, phenol formaldehyde and isocyanate resin were used as binders in this study. Roof tile specimens with 400 mm wide, 400 mm long and 5 mm thick were prepared by compression molding. Physical and mechanical properties of the specimens were analyzed by water absorption, thickness swelling, thermal conductivity, density, modulus of rupture and modulus of elasticity. From the results, water absorption at 1 and 24 hours was 19-47 % and 38-57 %, respectively. Thickness swell at 24 hours was 15-29%. Thermal conductivity was 0.016, 0.017 and 0.019 W/m.K when using isocyanate, urea formaldehyde and phenol formaldehyde, respectively. Density of the specimens was 770-860 kg/m3. Modulus of rapture was 255-280 MPa. Modulus of elasticity was 5.1-7.6 GPa. Physical and mechanical properties of the specimens indicated that they would be applied for roof tile and construction.

Fractography of the Wood Materials Ruptured by Shear Stress (구조용 목질재료의 전단파괴기구 해명을 위한 파면해석적 연구)

  • ;Juichi Tsutsumi
    • Journal of the Korea Furniture Society
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    • v.10 no.1
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    • pp.23-32
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    • 1999
  • The ultrastructural characteristics of shear fracture surfaces of laminated wood prepared from major four Korea wood specimens were examined. Commercial urea and urethan resin were used as adhesives for laminated woods of both homospecies and heterospecies. The morphology of fracture surface was observed using an optical microscopy and scanning electron microscopy. Three anatomical failure types were recognized : intercell failure, intrawall failure and transwall failure. In dry specimen, failure occurred mainly in woods. Laminated woods of softwoods showed mostly intrawall failure and transwall failure of tracheids, and them of hardwoods indicated mainly intrawall failure and interwall failure. Laminated woods prepared with urethan resin showed coarse fracture surface, on the other hand, those prepared with an urea formaldehyde resin had clean surface. In wet specimen, failure occurred dominantly in glue line. Intrawall failure and flags were characterized in laminated wood prepared with urethan resin. In heterospecies laminated woods, failure was occurred mainly in softwood. Consequently, fracture morphology of laminated wood may be influenced by adhesives, moisture content, species and anatomical characteristics.

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Effect of Panel Density and Resin Content on Properties of Medium Density Fiberboard

  • Hong, Min-Kug;Lubis, Muhammad Adly Rahandi;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.4
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    • pp.444-455
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    • 2017
  • This study was conducted to evaluate the effect of panel density and resin content on properties of medium density fiberboard (MDF) to obtain some insights on MDF properties as a function of panel density and resin content. MDF panels with different panel densities such as 650, 700, 750 and $800kg/m^3$ were manufactured by adjusting the amount of wood fibers in the mat forming. MDF panels were also fabricated by spraying 8, 10, 12, and 14% of urea-formaldehyde (UF) resins onto wood fibers in a drum-type mechanical blender to fabricate MDF panels with a target density of $650kg/m^3$. As the panel density and resin content increased, the internal bonding (IB) strength of MDF panel consistently increased. Modulus of rupture (MOR), modulus of elasticity (MOE) and screw withdrawal resistance (SWR) had a similar trend to the IB strength. In physical properties, thickness swelling (TS) and water absorption (WA) decreased with an increase in both panel density and resin content. In addition, the formaldehyde emission (FE) which increased as the panel density and resin content became greater. In overall, the panel density of MDF had more significant effect than the resin content in all properties of MDF panels, indicating that it was better to adjust the panel density rather than the resin content for MDF manufacture.

The Formaldehyde/VOCs Emission of Particleboard with Cross-linked Vinyl Resin (변성 비닐계 접착제를 이용한 파티클보드의 포름알데히드/VOCs 방산특성)

  • Kim, Ki-Wook;Lee, Se Na;Baek, Bong-San;Lee, Byong-Ho;Kim, Hyun-Joong;Choi, Younmee;Jang, Seong Wook
    • Journal of Adhesion and Interface
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    • v.9 no.1
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    • pp.28-34
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    • 2008
  • This study was used particleboard with urea-formaldehyde resin and cross linking vinyl resin. Manufactured particleboard had high cross linking vinyl resin content that internal bonding strength was low value but flexural strength was increased. For emission test of particleboard using VOC Analyzer, it was confirmed that more cross linking vinyl resin had reduced 4 volatile organic compounds (Toluene, Ethylbenzen, Xylene, Styrene) but also TVOC (Total VOC), 5 VOCs (Benzene, Toluene, Ethylbenzen, Xylene, Styrene) and formaldehyde emissions from manufactured particleboard were also lower emission factor than particleboard with only urea formaldehyde resin.

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