• Title/Summary/Keyword: uptake capacity

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Removal, Recovery, and Process Development of Heavy Metal by Immobilized Biomass Methods (미생물 고정화법에 의한 중금속 제거, 회수 및 공정개발)

  • Ahn, Kab-Hwan;Shin, Yong-Kook;Suh, Kuen-Hack
    • Journal of Environmental Science International
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    • v.6 no.1
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    • pp.61-67
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    • 1997
  • Heavy metal adsorption by microbial cells is an alternative to conventional methods of heavy metal removal and recovery from metal-bearing wastewater The waste Sac-chuomyces cerevisiae is an inexpensive, relatively available source of biomass for heavy metal biosorption. Biosorption was investigated by free and immobilized-S. cerevisiae. The order of biosorption capacity was Pb>Cu>Cd with batch system. The biosorption parameters had been determined for Pb with free , cells according to the Freundlich and Langmuir model. It was found that the data fitted reasonably well to the Freundlich model. The selective uptake of immobilized-S. cerevisiae was observed when all the metal ions were dissolved in a mixed metals solution(Pb, Cu, Cr and Cd). The biosorption of mixed metals solution by immobilized-cell was studied in packed bed reactor. The Pb uptake was Investigated in particular, as it represents one of the most widely distributed heavy metals in water. We also tested the desorption of Pb from immobilized-cell by us- ing HCI, $H_2SO_4$ and EDTA.

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Effectiveness of Feather Waste for Orange II Removal from Aqueous Solutions (수용액 중 Orange II 흡착 제거를 위한 우모폐기물의 이용가능성)

  • Park, Soo-Yeun;Yoo, Ji-Yeon;Son, Hong-Joo
    • Journal of Environmental Science International
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    • v.27 no.9
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    • pp.743-751
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    • 2018
  • The objective of this study was to investigate the adsorption potential of chicken feathers for the removal of OrangeII (AO7) from aqueous solutions. Batch experiments were performed as a function of different experimental parameters such as initial pH, reaction time, feather dose, initial OrangeII concentration and temperature. The highest OrangeII uptake was observed at pH 1.0. Most of the OrangeII was adsorbed at 2 h and an adsorption equilibrium was reached at 6 h. As the amount of chicken feather was increased, the removal efficiency of OrangeII increased up to 99%, but its uptake decreased. By increasing the initial concentration and temperature, OrangeII uptake was increased. The experimental adsorption isotherm exhibited a better fit with the Langmuir isotherm than with the Freundlich isotherm, and maximum adsorption capacity from the Langmuir constant was determined to be 0.179244 mmol/g at $30^{\circ}C$. The adsorption energy obtained from the Dubinin-Radushkevich model was 7.9 kJ/mol at $20^{\circ}C$ and $30^{\circ}C$ which indicates the predominance of physical adsorption. Thermodynamic parameters such as ${\Delta}G^0$, ${\Delta}H^0$, and ${\Delta}S^0$ were -12.28 kJ/mol, 20.64 kJ/mol and 112.32 J/mol K at $30^{\circ}C$, respectively. This indicates that the process of OrangeII adsorption by chicken feathers was spontaneous and endothermic. Our results suggest that as a low-cost biomaterials, chicken feather is an attractive candidate for OrangeII removal from aqueous solutions.

Physicochemical Properties of Pigmented Rice (Suwon-415) (수원415호 유색미의 이화학적 특성)

  • Lee, You-Seok;Cho, Ji-Mi;Rhee, Chong-Ouk
    • Korean Journal of Food Science and Technology
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    • v.34 no.5
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    • pp.842-845
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    • 2002
  • Physicochemical properties and water uptake rate of pigmented rice were determined. The median and mean particle sizes of pigmented rice flour were 15.18 and $38.53\;{\mu}m$, whereas brown rice flour were 11.46 and $33.41\;{\mu}m$, respectively. Water-binding capacity, swelling power, and solubility of pigmented rice flour were higher than those of brown rice flour. X-ray diffraction patterns showed traditional A type of cereals. Moisture gain of pigmented rice kernels increased continuously up to 60 min at soaking temperature $(20{\sim}25^{\circ}C)$. Water uptake rate constants of pigmented rice during soaking at $20{\sim}25^{\circ}C$ also increased.

The characteristics of long- and short- chain PFCA and PFSA adsorption on granular activated carbon and surface-modified granular activated carbon (입상 활성탄 및 표면 개질 활성탄의 장·단사슬 PFCA와 PFSA 흡착 특성)

  • Jeongwoo Shin;Sangki Choi;Heejong Son;Byungryul An
    • Journal of Korean Society of Water and Wastewater
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    • v.38 no.4
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    • pp.199-208
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    • 2024
  • In this paper, the adsorption removal characteristic for 10 species of perfluoroalkyl and polyfluoroalkyl substances (PFAS) was investigated using GAC and modified GAC (GAC-Cu). After modification with Cu(II), the amount of copper was to 1.93 and 4.73 mg/g for GAC and GAC-Cu, respectively. The total amount of 10 species of PFAS per specific area was obtained to 0.548 and 0.612 ng/m2 for GAC and GAC-Cu, respectively. A series of batch test confirmed lower efficiency was observed with a smaller number of carbon chain length and the removal efficiency of PFCA (perfluoroalkyl carboxylic acids) was lower than that of PFSA (perfluoroalkyl sulfonic acids) with the same carbon chain length. Regarding the pH effect, the adsorption capacity was decreased with increase of pH due to the increase of electrostatic repulsion. According to pseudo first and second order (PFO and PSO) kinetic models, while the values of equilibrium uptake and time did not show significant difference, a difference in uptake was observed between 24-48h. Furthermore, based on correlation analysis, Log Kow and uptake have a high correlation with molecular weight (M.W.) and initial concentration, respectively. These results show that long-chain PFAS have higher removal efficiency due to their increased hydrophobicity.

The Analysis of Instantaneous $CO_2$ Uptake and Evapotranspiration of Herbaceous Plants for Artificial Roof Greening (옥상녹화용 초본식물의 순간 $CO_2$ 흡수 및 증발산량 분석)

  • Ahn, Geun-Young;Han, Seung-Won;Lee, Eun-Heui
    • Korean Journal of Environment and Ecology
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    • v.25 no.1
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    • pp.91-101
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    • 2011
  • The purpose of this study is to demonstrate the positive effects of artificial ground greening on the reduction of carbon dioxide ($CO_2$) which can help improve ecological functions in cities and mitigation of climate change, through quantifying $CO_2$ uptake and evapotranspiration by the process of photosynthesis of some plants. Experiment of $CO_2$ uptake and evapotranspiration was conducted by measurement of $CO_2$ exchange rate using the infrared gas analyzer, for 7 month, growing season from May to November 2009, 2 times a month. The result was as follows; The $CO_2$ uptake quantity per $cm^2$ of Chrysanthemum zawadskii was the highest rate at $21.47{\times}10^{-6}g/cm^2/s$ and Poa pratensis was $16.20g{\times}10^{-6}g/cm^2/s$. The stronger was light of intensity, the higher were $CO_2$ uptake rate of most plants. In quantity of evapotranspiration, Poa pratensis was the highest rate at $8.75{\times}10^{-5}g/cm^2/s$ and Aquilegia buergariana was $8.66{\times}10^{-5}g/cm^2/s$. From this study, it is confirmed that artificial ground greening has capacity of absorption $CO_2$ and effects on improving urban microclimate.

Physiological Adaptation of Nitrate Uptake by Phytoplankton Under Simulated Upwelling Conditions (모의 용승조건하에서 식물 플랑크톤 질산염 흡수기작의 생리적 적응)

  • YANG Sung Ryull
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.782-793
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    • 1997
  • To study the physiological adaptation (shift-up) of phytoplankton under the simulated upwelling conditions, nitrate uptake capacity of Dunaliella tertiolecta batch culture was measured in the laboratory using the stable isotope $^{15}N-KNO_3$. Contrary to the expected, there was no significant relationship between the maximum $V_{NO3}$ (nitrogen specific nitrate uptake rate) and the initial nitrate concentration. However, there was a strong relationship between the maximum $\rho_{NO3}$ (nitrate transport rate) and the initial nitrate concentration of $<25\;{\mu}M$, which was also influenced by the physiological status of the culture. The increase in $V_{NO3}$ was mainly due to the increase in PON (particulate organic nitrogen) concentration and partly due to the increase in $V_{NO3}$. When the phytoplankton population was severely shifted-down, the physiological adaptation of nitrate uptake was significantly inhibited at high initial nitrate concentrations. The timing of the maximum $V_{NO3}$ or $\rho_{NO3}$ was related to the initial nitrate concentration. At higher initial nitrate concentrations, maxima in $V_{NO3}$ and $\rho_{NO3}$ occurred 1 or 2 days later than at lower nitrate concentrations. This relationship was the opposite to the prediction from the shift-up model of Zimmerman et al. (1987), The shift-up process is apparently controlled by an internal time sequence and the initial nitrate concentration, but the magnitude of $V_{NO3}$ was affected little by changes in nitrate concentration.

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Effect of Chlorella on Metallothionein Synthesis and Binding Capacity of Cadmium in Cadmium Poisoned Rat Liver and Kidney

  • Hwang Yoo-Kyeong;Choi Hyun-Jin;Nan Meng;Yoo Jai-Du;Kim Yong-Ho
    • Biomedical Science Letters
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    • v.12 no.1
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    • pp.23-27
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    • 2006
  • The rate of metallothionein synthesis on cadmium-poisoned rats reflects the level of toxicity, and also it reduces the toxicity which is caused by the uptake of cadmium. Chlorella supplementation in the diets of the cadmium-poisoned rats decreased the concentration of cadmium in blood and urine compared with the control group. Although the liver and kidneys of rats are major target organs of cadmium and coherence of metallothionein and cadmium, no previous study has determined the correlation between the rate of metallothionein synthesis in the liver and kidneys of rats and dietary supplementation of chlorella with cadmium uptake. This study analyzed total metallothionein level on the tissue of the liver and kidneys, the concentration of cadmium bound to the metallothionein, and the total concentration of cadmium on the tissue of the liver and kidneys after dietary supplementation with 1%, 5%, and 10% dried chlorella and 40 ppm of cadmium to 46 male SD rats (mean weight: $150\pm20\;g$) for 4 weeks. According to the data analysis of the total rate of metallothionein synthesis in the liver and kidneys, the group of SD rats on the supplementation with 1% chlorella and 40 ppm of cadmium showed a rate of $93.2\pm8.9\;ng/g$, a significant decrease of 58.8% compared to that of the control group of SD rats on the supplementation with cadmium only, which showed a rate of $227.3\pm32.5 ng/g$ (P=0.0001). In contrast, no significant difference was observed through the changing of chlorella concentrations between 5% and 10% chlorella supplementation with cadmium. The group supplemented with 1% or greater chlorella levels represented a greater decrease in the total cadmium concentration of the kidney and liver tissues, the amount of total metallothionein synthesis, the amount of metallothionein with binding to cadmium, and the concentration of free cadmium without binding to metallothionein. Consequently, the supplementation of 1% and 5% chlorella was effective in reducing the synthesis of metallothionein for cadmium uptake, but increased the rate of binding of cadmium to metallothionein.

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Anion Transport or Nucleotide Binding by Ucp2 Is Indispensable for Ucp2-Mediated Efferocytosis

  • Lee, Suho;Moon, Hyunji;Kim, Gayoung;Cho, Jeong Hoon;Lee, Dae-Hee;Ye, Michael B.;Park, Daeho
    • Molecules and Cells
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    • v.38 no.7
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    • pp.657-662
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    • 2015
  • Rapid and efficient engulfment of apoptotic cells is an essential property of phagocytes for removal of the large number of apoptotic cells generated in multicellular organisms. To achieve this, phagocytes need to be able to continuously uptake apoptotic cells. It was recently reported that uncoupling protein 2 (Ucp2) promotes engulfment of apoptotic cells by increasing the phagocytic capacity, thereby allowing cells to continuously ingest apoptotic cells. However, the functions of Ucp2, beyond its possible role in dissipating the mitochondrial membrane potential, that contribute to elevation of the phagocytic capacity have not been determined. Here, we report that the anion transfer or nucleotide binding activity of Ucp2, as well as its dissipation of the mitochondrial membrane potential, is necessary for Ucp2-mediated engulfment of apoptotic cells. To study these properties, we generated Ucp2 mutations that affected three different functions of Ucp2, namely, dissipation of the mitochondrial membrane potential, transfer of anions, and binding of purine nucleotides. Mutations of Ucp2 that affected the proton leak did not enhance the engulfment of apoptotic cells. Although anion transfer and nucleotide binding mutations did not affect the mitochondrial membrane potential, they exerted a dominant-negative effect on Ucp2-mediated engulfment. Furthermore, none of our Ucp2 mutations increased the phagocytic capacity. We conclude that dissipation of the proton gradient by Ucp2 is not the only determinant of the phagocytic capacity and that anion transfer or nucleotide binding by Ucp2 is also essential for Ucp2-mediated engulfment of apoptotic cells.

Studies on Nutrio-physiology of Low Productive Rice Plants (수도저위생산력(水稻低位生産力)의 원인구명(原因究明)에 관(關)한 영양생리적연구(營養生理的硏究))

  • Park, Jun-Kyu
    • Applied Biological Chemistry
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    • v.17 no.1
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    • pp.1-30
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    • 1974
  • Present study was undertaken to elucidate the relationship between uptake of nutrients and photosynthetic activities, and the translocation of several mineral nutrients in rice plants which were grown under different cultural conditions, utilizing radioactive tracer technique. Particular emphasis was placed on the analysis of patterns of nutrient uptake, the relationship between nutritional conditions and yield components. For this, rice plants grown on either low or high yielding fields at different growth stage were subjected to this study. The results are summarized as follows; 1. Varietal difference was observed in the uptake of potassium and phosphorus. Kusabue and Jinheung had good capacity but Paldal had rather poor capacity for the uptake of the both nutrients. 2. For rice plants, a high positive correlation was found between the oxidation of alpha plaus-naphthylamine by root and uptake of phosphorus. 3. Carbon assimilation rate repended on rice varieties. It was high in Noindo, Gutaenajuok #3 Suweon #82 and Jinheung but low in Taegujo, Kwanok, Yugu #132 etc. 4. Heavy application of nitrogen increased carbon assimilation in rice plants but this also depressed translocation of certain carbohydrates to ears. 5. Carbon assimilation wan greatly hampered in rice plants deficient in magnesium, phosphorus or potassium. 6. Total dry matter after ear formation stage, was much higher in rice plants grown in high yielding fields than those grown in low yielding fields. 7. Leaf area index(LAI) reached maximum at heading stage and decreased thereafter in high yielding fields. But in low yielding fields, it reached maximum before heading and sharply decreased thereafter due to early senescence of lower leaves. 8. In general, light transmission ratio (LTR) of leaves was higher in the early growth stage and lower in later stages. Higher ratio of LTR to leaf area index, was found in the rice grown in high yielding fields than those in low yielding fields. 9. Net photosynthetic activity decreased with the increase in leaf area index but was higher in high yielding fields than in low yielding fields. 10. After the ear formation stage, nitrogen, potassium and silicon as weil as $K_2O/N$ in straw were higher in high yielding fields than those in low yielding fields. 11. Nitrogen, phosphorus, potassium and magnesium taken up by rice plants in low yielding fields before heading stage were readily translocated to ears than those in high yielding fields. This suggests greater redistribution of nutrients in straw occurs due to lower uptake, in later growth stages, by rice plants grown in low yielding fields and hence results in early senescence due to nutrient deprivation. 12. In the high yielding fields nitrogen uptake by rice was slow but continuous throughout the life of the plants resulting in a large uptake even after heading. But, in low yielding fields the uptake was fast before heading and slow after heading. 13. A high positive correlation was found between the contents of nitrogen and potassium in the straw at heading stage and grain yield. Positive correlation was also found to hold between the contents of potassium, silicon, $K_2O/N$, $SiO_2/N$ in the straw at harvesting stage, and grain yield. 14. Carbon assimilation was greately hampered in rice plants deficient in magensium, phosphorus or potassium. 15. Uptake of nitrogen, phosphorus, potassium, silicon and manganese by rice was considerably higher in high yielding fields and reached maximum at ear formation stage. 16. In rice, a high positive correlation was discovered between total uptake of nitrogen, phosphorus, potassium, calcium, magnesium, silicon, manganese at harvesting stage and grain yield. 17. In rice, a high positive correlation was found between the total uptake of nitrogen, phosphorus, potassium, calcium, magnesium, silicon at harvesting stage, and number of spikelets per $3.3\;m^2$. In addition, a correlation was found between the total uptake of nitrogen and potassium and number of panicles per hill.

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The Effect of Disintegrants on the Properties of Salicylamide Tablets (수종의 붕해제가 살리실아미드정제의 제제특성에 미치는 영향)

  • Hwang, Sung-Joo;Rhee, Gye-Ju;Jee, Ung-Kil;Kwak, Hyo-Sung;Kim, Chong-Kook
    • Journal of Pharmaceutical Investigation
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    • v.22 no.1
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    • pp.41-48
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    • 1992
  • Six common tablet disintegrants (corn starch, Avicel PH102, calcium carboxymethylcellulose, Primojel, Kollidon CL and Ac-Di-Sol) were used at the concentration of 0, 2, 4 and 6% (w/w) in salicylamide tablets made with wet granulation method. Certain physical parameters of the disintegrants (moisture sorption, hydration capacity and bulk density) were determined to evaluate their relative efficiency. The disintegration time and dissolution rate of the tablets were correlated well with the ranks of initial rate of moisture sorption for each disintegrant as follows; Ac-Di-Sol, Kollidon CL, primojel, calcium CMC, corn starch and Avicel PH102. The initial rate of moisture sorption was important for the disintegration capacity as well as hydration capacity. The effect of storage at different temperatures and relative humidity upon the tablets containing various disintegrants was evaluated in terms of tablet hardness and disintegration time. Storage at high temperature reduced the hardness substantially and retarded the disintegration of the all tablets studied. Especially, the hardness of tablets containing Kollidon CL was significantly reduced. Although the tablet hardness was decreased and the disintegration time was increased under a moderate humid condition, both of them were decreased under the severely high humid condition of 80 or 90% RH, which was due to the breakrupture of tablet matrix bonds by the excessive uptake of moisture. Therefore, the stability caused by moisture sorption should be considered, when disintegrants having high moisture sorption such as Kollidon CL, Ac-Di-Sol and Primojel were employed in the tablets containing water-labile or hygroscopic drugs.

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