• Bulletin of the Korean Chemical Society
• /
• v.12 no.2
• /
• pp.224-227
• /
• 1991

The "frozen-out" $^{13}C-NMR$ spectrum of cyclooctanone conformer was detected at $-150^{\circ}$ and is reported for the first time. The stable conformation of cyclooctanone deduced by $^{13}C-NMR$ measurements was a unsymmetrical boat-chair conformation.

• Steel and Composite Structures
• /
• v.26 no.4
• /
• pp.453-461
• /
• 2018

In this paper, nonlinear vibrations of the unsymmetrical laminated composite beam (LCB) on a nonlinear elastic foundation are studied. The governing equation of the problem is derived by using Galerkin method. Two different end conditions are considered: the simple-simple and the clamped-clamped one. The Hamiltonian Approach (HA) method is adopted and applied for solving of the equation of motion. The advantage of the suggested method is that it does not need any linearization of the problem and the obtained approximate solution has a high accuracy. The method is used for frequency calculation. The frequency of the nonlinear system is compared with the frequency of the linear system. The influence of the parameters of the foundation nonlinearity on the frequency of vibration is considered. The differential equation of vibration is solved also numerically. The analytical and numerical results are compared and is concluded that the difference is negligible. In the paper the new method for error estimation of the analytical solution in comparison to the exact one is developed. The method is based on comparison of the calculation energy and the exact energy of the system. For certain numerical data the accuracy of the approximate frequency of vibration is determined by applying of the suggested method of error estimation. Finally, it has been indicated that the proposed Hamiltonian Approach gives enough accurate result.

• Multiscale and Multiphysics Mechanics
• /
• v.1 no.2
• /
• pp.143-156
• /
• 2016

Reinforced concrete (RC) structures require advanced analysis techniques for better estimation of their seismic responses, especially in the case of exhibiting complex three-dimensional coupling of torsional and flexural behaviors. This study focuses on validating a numerical approach for evaluating the seismic response of a three-dimensional unsymmetrical RC structure through the participation in the SMART 2013 international benchmark program. The benchmark program provides material properties, detailed drawings of the RC structure, and input ground motions for the seismic response evaluation. In this study, nonlinear constitutive models of concrete and rebar were formed and local tests were conducted to verify the constitutive models in finite element analysis. Elastic calibration of the finite element model of the SMART 2013 RC structure was performed by comparing numerical and experimental results in modal and linear time history analyses. Using the calibrated model, nonlinear earthquake analysis and seismic fragility analysis were performed to estimate the behavior and vulnerability of the RC structure with various ground motions.

• Journal of the Korean Chemical Society
• /
• v.55 no.6
• /
• pp.940-951
• /
• 2011

Reaction of 1-methylpyrimidine-(1H,3H,5H)-2,4,6-trione (1-MBA 1) as an unsymmetrical barbituric acid with cyanogen bromide and various aldehydes in the presence of triethylamine and/or pyridine afforded diastereomeric mixtures of new class of heterocyclic stable 5-aryl-1,1'-dimethyl- and 5-aryl-3,1'-dimethyl-1H,1'H-spiro[furo[2,3-d]pyrimidine-6,5'-pyrimidine]2,2',4,4',6'(3H,3'H,5H)-pentaones which are dimeric forms of 1-methyl barbiturate at the range of $0^{\circ}C$ to room temperature. In the reaction of some aldehydes with 1-MBA and BrCN were afforded a mixture of diastereomers. Another two aldehydes such as 4-cyano- and 2-hydroxybenzaldehydes gave exclusively two diastereomers in which binded to the salt of triethylammonium hydrobromide by intermolecular H-bond in ratio of 1:1. 4-Hydroxybenzaldehyde and 2-pyridinecarbaldehyde gave exclusively one diastereomer under the same condition. Aldehydes possessing strong electron-donor were produced exclusively two geometric isomers of Knoevenagel adduct (E- and Z-isomers). The structures of compounds were deduced by $^1H$ NMR, $^{13}C$ NMR and FT-IR spectroscopy. Mechanism of the formation is discussed.

• Journal of Electrical Engineering and Technology
• /
• v.7 no.2
• /
• pp.184-192
• /
• 2012

The torque and unbalanced magnetic forces in permanent magnet machines are resultants of the tangential, axial and normal magnetic forces, respectively. Those are in general influenced by pole-teeth-winding configuration. A study of the torque and unbalanced magnetic forces of a small flux concentrating permanent magnet transverse flux machine (FCPM-TFM) in segmented compact structure is presented in this paper. By using FLUX3D software from Cedrat, Maxwell stress tensor has been solved. Finite element (FE-) magneto static study followed by transient analysis has been conducted to investigate the influence of unsymmetrical winding pattern, in respect to the rotor, on the performance of the FCPM-TFM. Calculating the magnetic field components in the air gap has required an introduction of a 2D grid in the middle of the air gap, whereby good estimations of the forces are obtained. In this machine, the axial magnetic forces reveal relatively higher amplitudes compared to the normal forces. Practical results of a prototype motor are demonstrated through the analysis.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
• /
• 2003.11a
• /
• pp.279-281
• /
• 2003

We analysed the operating properties of resistive type superconducting fault current limiters (SFCLs) based on YBCO thin films with a single line-to-ground fault. When a single line-to-ground fault occurred, the short circuit current of a fault phase increased up to about 6 times of transport currents immediately after the fault instant and was effectively limited to the designed current level within 2 ms by the resistance development of the SFCL. The fault currents of the sound phases almost did not change because of their direct grounding system. The unsymmetrical rates of a fault phase were distributed from 6.4 to 1.4. It was found that the unsymmetrical rates of currents were noticeably improved within one cycle after the fault instant. We calculated the zero phase currents for a single line-to-ground fault using the symmetrical component analysis. The positive sequence resistance was reduced remarkably right after the fault but eventually approached the balanced positive resistance component prior to the system fault. This means that the system reaches almost the three-phase symmetrical state in about 60 ㎳ after the fault. The ground currents were almost 3 times of the zero phase mts since most of the fault currents flowed through the grounding line.

• Proceedings of the KIEE Conference
• /
• 1992.07b
• /
• pp.1100-1103
• /
• 1992

Two different resonance inverters used as fluorescent lamp ballast are based on the self oscillation at the series resonance of the circuit components. Each circuit is simulated on a computer in order to explain its function and the variation of the circuit variables for each of the circuit elements. Experimental results have bean carried out on the unsymmetrical scheme to indicate the voltage and current of the fluorescent lamp operation at the high frequency.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.12 no.1
• /
• pp.133-143
• /
• 1994

A new photochromic spiroxazine dye having a pyridinium s-triazine moiety has been prepared. It shows a reversible photochemical color change from colorless to reddish-purple in ethanol solution. In ethanol solution the half life time of the open form was 150sec, which was shortened by raising temperature. Silica-immobilized spiroxazine(6). Fine power of silica-immobilized spiroxazine was changed intensely blue from colorless by U.V. light or sunlight.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.12
• /
• pp.3658-3660
• /
• 2014

• YAKHAK HOEJI
• /
• v.34 no.4
• /
• pp.244-251
• /
• 1990

N-Monoalkylations of ditertiary diamines succeed best in nitromethane or ethanol at low temperature. Unsymmetrical 1,2-diaminoethane, 1,3-diaminopropane and piperazine compounds react selectively under these conditions at the sterically less hindered nitrogen atom.