• Korean Chemical Engineering Research
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• 제53권3호
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• pp.382-390
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• 2015

Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

• 폴리머
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• 제36권4호
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• pp.470-477
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• 2012

다양한 아민 그룹으로 개질된 다중벽 탄소나노튜브(이하 MWNT) 지지체를 기반으로 하여 페놀 화합물을 검출하기 위한 티로시나아제가 고정된 바이오센서를 개발하였다. 방사선 중합법을 이용하여 MWNT에 글리시딜메타크릴레이트를 중합한 후 중합 사슬의 아미노화 반응을 통해 MWNT에 다양한 아민 그룹을 도입시켰다. 이렇게 제조된 물질의 물리적, 화학적 특성은 SEM, XPS 그리고 TGA에 의해 평가되었다. 그리고 제조된 물질을 기반으로 제작된 티로시나아제가 고정화된 바이오센서의 전기화학적 특성도 평가하였다. 본 효소 바이오센서는 0.1-0.9 mM의 페놀을 검출할 수 있다. 결합효과, pH, 온도 그리고 다양한 페놀화합물에 대한 반응과 같은 여러 가지 변수에 대하여도 최적화하였고 상용 레드와인에서의 페놀화합물 검출도 연구하였다.

• 한국안전학회지
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• 제32권6호
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• pp.75-80
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• 2017

In this study, seismic performance of various types of valve supports in terms of flexural rigidity are evaluated by FEA using equivalent static load method. Flexural rigidity of the existing two types of valve supports can be effectively improved by simply adding one more bracket on the other side of support. New types of polygonal valve supports with a concept of fully stressed beam theory are suggested and it is verified that the new supports are rigid enough to withstand stronger earthquake which we should be prepared for.

• Structural Engineering and Mechanics
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• 제52권5호
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• pp.1033-1049
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• 2014

The free vibration of functionally graded material (FGM) beams on an elastic foundation and spring supports is investigated. Young's modulus, mass density and width of the beam are assumed to vary in thickness and axial directions respectively following the exponential law. The spring supports are also taken into account at both ends of the beam. An analytical formulation is suggested to obtain eigen solutions of the FGM beams. Numerical analyses, based on finite element method by using a beam finite element developed in this study, are performed in order to show the legitimacy of the analytical solutions. Some results for the natural frequencies of the FGM beams are given considering the effect of various structural parameters. It is also shown that the spring supports show the greatest effect on the natural frequencies of FGM beams.

• Nuclear Engineering and Technology
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• 제56권5호
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• pp.1627-1637
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• 2024

This research paper proposes a novel methodology for predicting the optimal location of friction supports to effectively mitigate vibrational energy in piping systems. The incorporation of friction forces in the dynamic characteristics of the system introduces inherent nonlinearity, making its analysis challenging. Typically, numerical solutions in the time domain are employed to circumvent the complexities associated with finding analytic solutions for nonlinear systems. However, time domain analysis (TDA) can be computationally intensive and demand significant computational resources due to the intricate calculations stemming from nonlinearity. To address this computational burden, this study presents an efficient approach based on linear analysis to predict the ideal position for installing friction supports as a replacement for fixed supports. Furthermore, we investigate the relationship between the installation positions of friction supports and their effectiveness in absorbing vibrations using the harmonic balanced method (HBM). Both methodologies are validated by comparing the obtained results with those obtained through time domain analysis (TDA) using the finite element method (FEM).

• Steel and Composite Structures
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• 제12권4호
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• pp.291-302
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• 2012

Frequently, steel silos are supported by discrete supports or columns to permit easy access beneath the barrel. In such cases, large loads are transferred to the limited number of supports, causing locally high axial compressive stress concentrations in the shell wall above the supports. If not dealt with properly, these increased stresses will lead to premature failure of the silo due to local instability in the regions above the supports. Local stiffening near the supports is a way to improve the buckling resistance, as material is added in the region of elevated stresses, levelling these out to values found in uniformly supported silos. The aim of a study on the properties of local stiffening will then be to increase the failure load, governed by an interaction of plastic collapse and elastic instability, to that of a discrete supported silo. However, during the course of such a study it was found that, although the failure remains local, the cylinder height is also a parameter that influences the failure mechanism, a fact that is not properly taken into account in current design practice and codes. This paper describes the mechanism behind the effect of the cylinder height on the failure load, which is related to pre-buckling deformations of the shell structure. All results and conclusions are based on geometrically and materially non-linear finite element analyses.

• 한국안전학회지
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• 제30권2호
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• pp.48-55
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• 2015

The number of collapse accidents relevant to form support since 2003 is 30 on the basis of statistical data from Ministry of Employment and Labor,. Total number of casualty was 138 (47 for deaths and 91 for injuries). The accident severity rate was high because the 4.6 casualties per one accident were occurred averagely although the incident rate was relatively low. Especially, one of form support members, the pipe supports have not been equipped adequately so that the accidents could have happened. In this regard, this study performed buckling test related to the effect of horizontal connection and slope in the single pipe which is one of typical pipe supports. The buckling load, which was estimated from the single pipe with the horizontal connectors theoretically and experimentally, was increased as more than 2 times compared to the buckling load obtained from the pipe supports without the connector. The buckling load was reduced as more than 26%, 34% slope of the single pipe comparing with 5% and 10% slope, respectively. Thus, the purpose of this study is to provide the guideline for installation and the maintenance of the pipe supports legally and institutionally to prevent the collapse accidents of the pipe supports.

• Structural Engineering and Mechanics
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• 제52권5호
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• pp.997-1017
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• 2014

According to the structure characteristics of the non-uniform beam bridge, a practical model for calculating the vibration equation of the non-uniform beam bridge is given and the application scope of the model includes not only the beam bridge structure but also the non-uniform beam with added masses and elastic supports. Based on the Bernoulli-Euler beam theory, extending the application of the modal perturbation method and establishment of a semi-analytical method for solving the vibration equation of the non-uniform beam with added masses and elastic supports based is able to be made. In the modal subspace of the uniform beam with the elastic supports, the variable coefficient differential equation that describes the dynamic behavior of the non-uniform beam is converted to nonlinear algebraic equations. Extending the application of the modal perturbation method is suitable for solving the vibration equation of the simply supported and continuous non-uniform beam with its arbitrary added masses and elastic supports. The examples, that are analyzed, demonstrate the high precision and fast convergence speed of the method. Further study of the timesaving method for the dynamic characteristics of symmetrical beam and the symmetry of mode shape should be developed. Eventually, the effects of elastic supports and added masses on dynamic characteristics of the three-span non-uniform beam bridge are reported.

• 한국안전학회지
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• 제29권2호
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• pp.53-61
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• 2014

This study evaluated wind loads considering a local basic wind velocity and construction periods to define the level of applied wind loads for system supports. Structural responses of system supports were examined and compared to those of system supports with the level of wind loads following various standards and specifications for permanent and temporary structures. And, the maximum combined stress ratios were estimated to evaluate the structural safety of a considered system support. From results, it was found that the wind load level should be applied in accordance with construction periods when estimating the safety of system supports. Looking into the response by change of the basic wind velocity according to local regions, it is no need to consider wind loads in regions with the basic wind velocity of 30 m/s. However, it was analyzed that wind loads should be considered in the regions with the basic wind velocity of 40 m/s or above. In addition, wind loads should be considered in designing system supports located at the region with the basic wind velocity of 35 m/s starting from construction period of 1.5 years. The standard specification for temporary work was analyzed as an incorrect standard in evaluating wind loads, since it underestimated the response of system supports in accordance with the local basic wind velocity and construction periods.

• 유통과학연구
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• 제15권9호
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• pp.37-52
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• 2017

Purpose - This study explores the influence of franchisors' supports on franchisees financial performance, overall satisfaction and intention to remain. Research design, data, and methodology - Given the exploratory design of the investigation, purposive sampling technique was used to select twenty-six (26) franchisees as key informants for this study. In-depth face-to-face interviews were conducted leading to generation of rich qualitative data on the phenomenon of support services in the Nigeria franchise system. Results - Results indicate that at both the initial and growing stages, training and management service supports have marked influence on franchisees business outcomes. However, findings revealed that at the initial stage, the impact of training is greatest but this impact subsequently declines as franchisees master the nuances of the business. Management services on the other hand maintains a constant relevance through all stages of franchisees business. Conclusions - Three key conclusions were drawn from the findings of this study. First, the quality of initial and ongoing supports have consequences for the long-term health of franchisees and franchisors' businesses. Second, poor management of franchisees' expectations and perception of supports could damage franchise partnerships. Third, franchisees form their expectation of supports largely from the nature of initial supports provided by the franchisors.