• Title/Summary/Keyword: uniform CA

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Studies on the Conversion of Hexatomic Sulfur to Octatomic Sulfur in the Manufacture of the Precipitated Sulfur (II) (침강 유황 제조에 있어서의 Hexatomic Sulfur의 Octatomic Sulfur로의 변환에 관한 연구(II))

  • 라운룡;강화수
    • YAKHAK HOEJI
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    • v.27 no.3
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    • pp.229-234
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    • 1983
  • In the manufacture of precipitated sulfur calcium pentasulfide ($CaS_{5}$, train product) and calcium thiosulfate ($CaS_{2}O_{3}$, by-product) are decomposed simultaneously by hydrochloricacid into coarse (not being uniform) particle-size products. To improve this drawback, calcium thiosulfate was prepared directly without making calcium pentasulfide and obtained $S_{6}$ by the acid-decomposition. In the conversion of hexatomic sulfur to octatomic sulfur, the polymerization and the depolymerization were observed by using purification method. The conversion of $S_{6}$ to $S_{8}$ is proceeded by two steps. The first step reaction is affected by impurities (especially $SO_{2}$ and $H_{2}S$), Hexatomic sulfur is inert to triethylamine for the time being by purification, and thereafter a slow conversion to polymeric and then to octatomic sulfur occurs. Instead of calcium pentasulfide, the acid decomposition of calcium thiosulfate has several advantages; uniformity of particle-size of product, increase of yield, and simplicity of procedure.

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Presoaking with $GA_3$ Improves Germination of Zoysiagrass (Zoysia japonica Steud.) Seed on Poor Germination Conditions (발아불량 환경조건에서의 $GA_3$ 침지처리에 의한 들잔디의 종자발아촉진)

  • 구자형;윤병한
    • Asian Journal of Turfgrass Science
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    • v.13 no.1
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    • pp.21-28
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    • 1999
  • The seeds of Zoysiagrass (Zoysia japonica Steud.) were soaked with GA3 50 ppm and primed with CaCl2 at -1.0 MPa for 4days at 23$^{\circ}C$ to identify presoaking and priming regimes that may improve germination in saline condition and with PEG 8000 at high temperature. Presoaked, primed, and untreated seeds were then germinated at 30 and $35^{\circ}C$. NaCl salinity stress consistently decreased the rate of germination of zoysiagrass seed. GA3 or CaCl2 alleviated the inhibitory effect of salinity on germination. However, total percent germination (G) and T50 of untreated control seeds significantly decreased and prolonged at $30^{\circ}C$ and $35^{\circ}C$ as NaCl salinity stress increased. Presoaked seeds with GA3 50 ppm for 4 days at $23^{\circ}C$ had significantly higher germination and lower T50 than untreated or primed with CaCl2 at -1.0 MPa for 4days at $23^{\circ}C$m and overcame the inhibitory effect of germination derived from PEG 8000. In addition, presoaked seed had higher, faster, and more uniform germination than untreated seeds after sowing in growing media in greenhouse.

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Characteristics of Bi(Pb)-Sr-Ca-Cu-O Superconductor Wire Fabricated using the Billet Insertion Method (Billet 장입 방식을 이용 제조한 Bi(Pb)-Sr-Ca-Cu-O 초전도 선재의 특성)

  • 장건익;유재근;홍계원
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.471-477
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    • 1996
  • During Bi(Pb)-Sr-Ca-Cu-O superconductor wire fabrication the effect of the initial packing density on the final characteristics of superconductor wire was systematically studied. To increase the powder packing density with uniform distribution of superconducting core a billet insertion method processed by CIP was applied instead of the commonly used vibration and ramming method of powder insertion into silver sheath. Compared with the vibration and ramming method the billent insertion technique processed by CIP cause the 30% incre-specimen with 130${\mu}{\textrm}{m}$(core thickness : 45 ${\mu}{\textrm}{m}$)and 5.24 mm width processed at 84$0^{\circ}C$for 200hrs. shows specimen with 130${\mu}{\textrm}{m}$ (core thickness ; 45${\mu}{\textrm}{m}$)and 5.24 mm width processed at 84$0^{\circ}C$ for 200 hrs. shows maximum 34A for Ic and 16, 700 A/cm2 for Ic measured at 77K and 0T. Also the sample rolled 3 times shows maximum 7, 2A for Ic and 11, 000 A/cm2 for 77K and 0T. Based on X-ray experimental results the formation of Bi-2223 and texture were significantly well developed at the interface between the superconducting core and silver sheath as compared with those of the interior area of superconducting core.

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In situ Microfluidic Method for the Generation of Uniform PEG Microfiber (PEG 마이크로 섬유 제조를 위한 마이크로플루이딕 제조방법)

  • Choi, Chang-Hyung;Jung, Jae-Hoon;Lee, Chang-Soo
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.470-474
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    • 2010
  • In this study, we presents a simple microfluidic approach for generating uniform Poly(ethylene glycol)(PEG) microfiber. Elongated flow pattern of monomer induced by sheath flow of immiscible oil as continuous phase is generated in Y-shape junction and in situ polymerization by UV exposure. For uniform microfiber, we investigate the optimized flow condition and draw phase diagram as function of Ca and Qd. At the region for stable elongated flow pattern, the microfiber generated in microfluidic chip is very uniform and highly reproducible. Importantly, the thickness of microfibers can be easily controlled by flow rate of continuous and disperse phase. We also demonstrate the feasibility for biological application as encapsulating FITC-BSA in PEG microfiber.

The epigenetic phenotypes in transgenic Nicotiana benthamiana for CaMV 35S-GFP are mediated by spontaneous transgene silencing

  • Sohn, Seong-Han;Choi, Min-Sue;Kim, Kook-Hyung;Lomonossoff, George
    • Plant Biotechnology Reports
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    • v.5 no.3
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    • pp.273-281
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    • 2011
  • Diverse epigenetic phenotypes are frequently found during research on transgenic plants. To understand the factors underlying such diversity, hundreds of independent 35S-GFP transgenic N. benthamiana plants were analyzed. The diverse GFP-expression phenotypes of the transgenic plants were classified into three major types based on the GFP expression patterns and their response to 35S-GFP agroinfiltration: steady-green, silenced and non-uniform phenotype. The non-uniform phenotype was further sub-divided into five minor phenotypes: variegated, red-dropped, on-silencing, partitioned and misty, according to the distribution of GFP expression on the leaves. Many of transgenic plants continuously generated diverse phenotypes over several generations despite the transgene identity. Such epigenetic GFP phenotyping was found to be the result of spontaneous transgene silencing mediated by either or both of post-transcriptional gene silencing (PTGS) and transcriptional gene silencing (TGS). This finding was verified by the detection of 21- and 24-nt small interfering RNA (siRNA) molecules, and DNA methylation in the transgenic plants that showed repeated epigenetic variation. Agroinfiltration demonstrated that irregular distribution of GFP on a leaf was the result of erratic transgene silencing, and the technique also proved to be a rapid and effective method for selecting fully silenced plants within 3 days. Furthermore, two novel phenotypes described are potential materials for in-depth investigations into the genes and mechanisms responsible for spontaneous transgene silencing.

Synthesis and Characteristic Evaluation of Downward Conversion Phosphor for Improving Solar Cell Performance (태양전지 성능향상을 위한 하향변환 형광체의 합성 및 특성평가)

  • Jae-Ho Kim;Ga-Ram Kim;Jin-To Choi;Soo-Jong Kim
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.5
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    • pp.523-528
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    • 2023
  • The applicability as a material to improve solar cell performance was reviewed by synthesizing a phosphor that emits red wavelengths by a liquid synthesis method using a metal salt aqueous solution and a polymer medium as a starting material. An aqueous solution was prepared using nitrate of metals such as Ca, Zn, Al, and Eu, and a precursor impregnated with starch, a natural polymer, was sintered to synthesize CaZnAlO:Eu phosphor powder. The surface structure and composition analysis of the synthesized CaZnAlO:Eu phosphor powder were analyzed by scanning electron microscope(SEM) and energy-dispersed X-ray spectroscopy(EDS). The crystal structure of CaZnAlO:Eu phosphor particles was analyzed by an X-ray diffraction analyzer (XRD). As a result of measuring the photoluminescence(PL) characteristics of the phosphor, it was confirmed that a red phosphor with a light emitting wavelength of 650-780nm was successfully synthesized. According to SEM and EDS analysis, the synthesized Ca14Zn6Al9.93O35:Eu3+0.07 phosphor powder has a uniform particle size, and Eu ions used as an activator are present. The synthesized CZA:Eu3+ phosphor can be used as a material that can increase the light absorption efficiency of the solar cell by converting ultraviolet or visible light down conversion into a wavelength in the near-infrared region.

Polymer coating for controlled release of biostimulants from Biostimulant balls (생물활성촉진제의 용출율 제어를 위한 폴리머 코팅)

  • Song, Young-Chae;Woo, Jung-Hui;Senthilkumar, Palaninaicker
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2013.10a
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    • pp.46-47
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    • 2013
  • We prepared biostimulant balls using sea sediment mixed with biostimulants viz acetate, nitrate and sulfate. The Biostimulant balls were coated with Cellulose Acetate (CA) and Polysulfone (PS) to control the release of the biostimulants. SEM images showed that CA coating was porous and irregular in the inside and very uniform and tight like beehive while PS coating was the same in the inside and outside and not porous. Biostimulants release was found to be high in sea water compared to distilled water. The release of nitrate was higher compared to sulfate. In turbulent environment the release of bionutrients was 50% higher than static environment.

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Changes in Microstructure and Mechanical Properties due to Heat Treatment of Mg-1.0Al-1.0Zn-0.2Mn-0.5Ca Alloy Sheet Manufactured via Normal Casting and Twin Roll Casting Process (일반주조 및 쌍롤주조 공정으로 제조된 Mg-1.0Al-1.0Zn-0.2Mn-0.5Ca 합금 판재의 열처리에 따른 미세조직 및 기계적 특성 변화)

  • Dong Hwan Eom;No Jin Park
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.6
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    • pp.359-366
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    • 2023
  • Changes in microstructure and mechanical properties of Mg-1.0Al-1.0Zn-0.2Mn-0.5Ca (AZMX1100) alloy sheet manufactured by normal casting and twin roll casting process, were studied according to process and heat treatment. Non-uniform microstructure was observed in the initial sheet produced through both processes, and in particular, tilted dendrites and shifted central segregation were observed in the twin roll casting sheet. It was homogenized through hot rolling and heat treatment, and heat treated at 350℃ and 400℃ to compare the effect of heat treatment temperature. Both sheets were homogenized by the hot rolling process, and the grain size increased as the heat treatment temperature and time increased. It was confirmed that the grain size, deviation, and distribution of the second phase were finer and more homogenized in the TRC sheet. Accordingly, mechanical properties such as hardness, formability, and tensile strength also showed better values. However, unlike other previously reported AZMX alloy systems, it showed low formability (Erichsen value), which was judged by the influence of Al2Ca present in the microstructure.

Improvement of MAC Protocol to Reduce the Delay Latency in Real-Time Wireless Sensor Networks (실시간 무선 센서 네트워크에서 전송 지연 감소를 위한 MAC 개선 방안)

  • Jang, Ho;Jeong, Won-Suk;Lee, Ki-Dong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.34 no.8A
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    • pp.600-609
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    • 2009
  • The traditional carrier sense multiple access (CSMA) protocol like IEEE 802.11 Distributed Coordination Function (DCF) does not handle the constraints adequately, leading to degraded delay latency and throughput as the network scales are enlarged. We present more efficient method of a medium access for real-time wireless sensor networks. Proposed MAC protocol is like the randomized CSMA protocol, but unlike previous legacy protocols, it does not use a time-varying contention window from which a node randomly picks a transmission slot. To reduce the latency for the delivery of event reports, we carefully decide to select a fixed-size contention window with non-uniform probability distribution of transmitting in each slot. We show that the proposed method can offer up to severaansimes latency reduction compared to legacy of IEEE 802.11 as the size of the sensor network scales up to 256 nodes using widely using network simulation package,caS-2. We finally show that proposed MAC scheme comes close to meet bounds on the best latency being achieved by a decentralized CSMA-based MAC protocol for real-time wireless sensor networks which is sensitive to delay latency.

An improvement of Medium Access Control Protocol in Ubiquitous Sensor Networks (유비쿼터스 센서 네트워크의 매체 접근 제어 기법에 대한 개선 방안)

  • Jang, Ho;Lee, Myung-Sub;Jeon, Woo-Sang
    • The KIPS Transactions:PartC
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    • v.16C no.3
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    • pp.373-382
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    • 2009
  • we present more efficient method of a medium access for real-time ubiquitous sensor networks. Proposed MAC protocol is like the randomized CSMA/CA protocol, but unlike previous legacy protocols, it does not use a time-varying contention window from which a node randomly picks a transmission slot. To reduce the latency for the delivery of event reports from sensor nodes, we carefully decide to select a fixed-size contention window with non-uniform probability distribution of transmitting in each slot. We show that the proposed method can offer up to several times latency reduction compared to legacy of IEEE 802.11 as the size of the sensor network scales up to 256 nodes using a widely-used network simulation package, NS-2. We finally show that proposed MAC scheme comes close to meet bounds on the best latency being achieved by a decentralized CSMA-based MAC protocol for real-time ubiquitous sensor networks which is sensitive to latency.